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公开(公告)号：JP2009108057A
公开(公告)日：2009-05-21
申请号：JP2008268534
申请日：2008-10-17
Inventor： TERASAKI HIROYUKI , FUJIO AKIRA , FUKUHARA KAZUHISA , KITAHARA YOSHIHISA
IPC: C07C227/08 , A61K8/44 , A61Q5/00 , A61Q5/02 , A61Q5/12 , C07C229/12
Abstract: PROBLEM TO BE SOLVED: To provide a method for simply producing a betaine ester-containing mixture imparting good flexibility, smoothness and oily feeling to the hair.
SOLUTION: The method for producing the mixture includes reacting a monohalogenated carboxylic ester with a tertiary amine in a solvent of a secondary alcohol of formula (1) [wherein, R
6 is R
8 -O-(AO)
n -CH
2 -; R
8 is a 1-40C alkyl group or the like; A is a 2-4C alkylene group; n is a number of 0-50; and R
7 is a 1-40C alkyl group or the like] to provide the mixture of the betaine ester of formula (2) [wherein, R
1 is an 8-40C alkyl group or the like; R
2 is a 1-5C alkylene group; R
3 , R
4 and R
5 are each a 1-24C alkyl group or the like; and X is a halogen atom] with the secondary alcohol of formula (1).
COPYRIGHT: (C)2009,JPO&INPITAbstract translation: 要解决的问题：提供一种简单地生产含甜菜碱酯的混合物的方法，赋予毛发良好的柔韧性，平滑性和油性感。 解决方案：制备混合物的方法包括使单卤代羧酸酯与叔胺在式（1）的仲醇的溶剂中反应[其中R 6是R“ 8○○（AO）
-CH 2 R 8是一个1-40C烷基等; A是2-4C亚烷基; n是0-50的数; 并且R 7 是1-40C烷基等]，以提供式（2）的甜菜碱酯的混合物[其中，R 1 = 40C烷基等; R 2 是1-5C亚烷基; R 3 ，R SP＆gt; 4＆lt; SP＆gt;和＆lt; SP＆gt; 5＆lt; SP＆gt;各自为1-24C烷基等; 和X是卤素原子]与式（1）的仲醇反应。 版权所有（C）2009，JPO＆INPIT -
公开(公告)号：JP2004115969A
公开(公告)日：2004-04-15
申请号：JP2002282778
申请日：2002-09-27
Inventor： FUJIO AKIRA , TSUKIYAMA YOICHI , YAMADA ISAO
IPC: D06M13/388 , D06M15/05 , D06M15/11 , D06M15/263 , D06M15/356
Abstract: PROBLEM TO BE SOLVED: To provide a readily washable and stainproof treating agent composition imparting excellent stainproofing property to fiber products such as clothes and having a readily washable property enabling easy removal by washing even when stain is attached to the fiber products. SOLUTION: The readily washable and stainproof treating agent composition comprises (a) an amine oxide compound having one 12-26C hydrocarbon group and two 1-3C hydrocarbon groups, (b) a specific polymer and (c) water. COPYRIGHT: (C)2004,JPO
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公开(公告)号：JP2001172674A
公开(公告)日：2001-06-26
申请号：JP36430599
申请日：1999-12-22
Applicant: KAO CORP
Inventor： TANAKA ATSUSHI , SAKAI TAKANARI , KUBO MAKOTO , FUJIO AKIRA , TAGATA HIDEJI
IPC: C11D3/26 , D06M13/248 , D06M13/256 , D06M15/03
Abstract: PROBLEM TO BE SOLVED: To provide a soil-releasing agent or a detergent composition that show excellent soil-releasing effect on cellulosic fabrics. SOLUTION: Chitosan and/or glucosamine that bears a functional group represented by the following general formula (I) -R1-X (I) [wherein R1 is a 1-6C alkylene group; X is a group selected from OR2, COOM and N+R3R4R5Z (R2 is H or a 1-22C alkyl group), M is H or a cation, R3, R4 and R5 are each a 1-4C alkyl group; Z is an anion) is used as the objective soil-releasing agent.
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公开(公告)号：JP2000192080A
公开(公告)日：2000-07-11
申请号：JP37304298
申请日：1998-12-28
Applicant: KAO CORP
Inventor： SAKAI TAKANARI , TETSU MAKIO , KUBO MAKOTO , FUJIO AKIRA
Abstract: PROBLEM TO BE SOLVED: To obtain a detergent being excellent in stability during formulation and exhibiting excellent foaming power in a neutral to acidic region even in the presence of oil stains by incorporating an amphoteric compound having a specified structure with a surfactant. SOLUTION: This detergent comprises an amphoteric compound (A) represented by formula I and a surfactant in such amounts that the total of both is 0.1-50 wt.%, and the ratio of the amphoteric compound to the surfactant is in the range of 99.9/0.1 to 70/30 by weight. The surfactant is prepared by mixing an anionic surfactant with an amphoteric surfactant in a ratio of 99.1/01 to 80/20 by weight. The amphoteric surfactant is represented by formula II and is exemplified by a carbobetaine or sulfobetaine of a tertiary amine. In the formulae, R1 to R3 are each a 1-6C alkyl, R5AR6, or the like (wherein R5 is a 1-5C alkyl or the like; R6 is a 1-4C alkylene; and A is CONH, NHCO, or the like); R4 is a 1-6C alkylene; X is COO or the like; R7 is an 8-22C alkyl, R10CONHR11 (wherein R10 is hydrogen, a 7-21C alkyl, or the like; and R11 is a 1-4C alkylene); R8 and R9 are each a 1-3C alkyl; and n is 1-4.
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公开(公告)号：JP2000096085A
公开(公告)日：2000-04-04
申请号：JP26446098
申请日：1998-09-18
Applicant: KAO CORP
Inventor： KUBO MAKOTO , TERASAKI HIROYUKI , SAKAI TAKANARI , FUJIO AKIRA
Abstract: PROBLEM TO BE SOLVED: To obtain a detergent composition exhibiting excellent detergency especially to oily dirt without using warm water. SOLUTION: This detergent composition contains 3-50 wt.% of a polyoxyalkyleneamine expressed by the formula [R is a 7-19C linear or branched chain alkyl group or alkenyl group. A is a 2-3C alkylene group and plural of the A may be the same or different. (m) and (n) are each a number exhibiting averaged addition mol number of an alkylene oxide.] and 5-45 wt.% of an anion surfactant, and a weight ratio of (the polyoxyalkyleneamine/the anion surfactant) is (10/90)-(90/10).
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Patent Agency Ranking
公开(公告)号：JPH10231277A
公开(公告)日：1998-09-02
申请号：JP3732497
申请日：1997-02-21
Applicant: KAO CORP
Inventor： KUBO MAKOTO , FUJIO AKIRA
IPC: C11D1/90 , C07C231/02 , C07C233/36 , C07C233/38 , C11D1/10
Abstract: PROBLEM TO BE SOLVED: To economically efficiently obtain the subject product excellent in hue even in long-term preservation, by adding an antioxidant and treating the product with it in producing an amide group-containing surfactant by reacting a condensation product with a monohaloalkyl carboxylic acid or its salt. SOLUTION: A higher fatty acid of the formula R COOR (R is an alkyl, etc.; R is H, a 1-3C alkyl, etc.) such as caprylic acid or its ester is reacted with a polyamine such as an alkylene polyamine in the molar ratio of 1:1 to 1:2 to give an amino group-containing derivative of formula I (Z is a 2-4C alkylol), which is reacted with 1-3mol of a monohaloalkyl carboxylic acid of the formula XR COOY (X is a halogen; R is a 1-4C alkylene; Y is an alkali metal) or its salt such as monochloroacetic acid to give an amidoamino acid of formula II. In the reaction, 0.001-5wt.% based on the fatty acid of an antioxidant such as dibutylhydroxytoluene is added to the reaction mixture.
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公开(公告)号：JPH09286791A
公开(公告)日：1997-11-04
申请号：JP10093796
申请日：1996-04-23
Applicant: KAO CORP
Inventor： FUJI HIDEKIYO , MATSUNAGA AKIRA , FUJIO AKIRA
Abstract: PROBLEM TO BE SOLVED: To produce the subject high-quality compound useful as cosmetics, medicines, etc., by phosphorylating a branched dimerized alcohol, providing a branched dimerized alkyl phosphate, then neutralizing the resultant compound with a basic amino acid and depositing a crystal at a specific temperature in a ketonic solvent. SOLUTION: A branched dimerized alcohol (e.g. 2-hexyldecanol) is phosphorylated with polyphosphoric acid, etc., to provide a branched dimerized alkyl phosphate (e.g. 2-hexyldecyl phosphate), which is then dissolved in ethanol. A powder of a basic amino acid such as argninine, histidine or lysine is then added to neutralize the branched dimerized alkyl phosphate. The neutralized compound is subsequently added to a ketonic solvent such as acetone or methyl ethyl ketone to deposit and separate a crystal of a basic amino acid salt of the branched dimerized alkyl phosphate at 0-20 deg.C temperature. The resultant high-quality basic amino acid salt of the branched dimerized alkyl phosphate can be used for fragrant cosmetics, cosmetics, medicines, etc., and is good in odor and hue.
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公开(公告)号：JPH09227481A
公开(公告)日：1997-09-02
申请号：JP4268896
申请日：1996-02-29
Applicant: KAO CORP
Inventor： ABE HIDEYUKI , MIZUSHIMA YOUSEN , FUJIO AKIRA
IPC: A61K8/30 , A61K8/00 , A61K8/44 , A61Q5/02 , C07C231/02 , C07C233/47 , C07C233/49 , C07C235/08 , C07C303/22 , C07C303/24 , C07C305/06 , C07C309/15 , C07F9/09 , C11D1/10 , C11D1/20 , C11D1/34 , A61K7/00 , A61K7/075
Abstract: PROBLEM TO BE SOLVED: To profitably obtain the subject compound free from the deterioration of color tone due to preservation and useful for cosmetics, perfumeries such as shampoos, etc., by reacting a specific multi-hydrophilic group-type amino acid (salt), etc., with an acid halide and subsequently treating the reaction solution with a reducing agent. SOLUTION: This method for producing a multi-hydrophilic group type N-long chain acylcarboxylic acid or its salt comprises reacting (A) a compound of formula I [R is a 1-3C (branched) alkylene; Y is a group of the formula: COOM (M is H, a cation), a group of the formula: OSO3 M, a group of the component: OPO(OM)2 , etc.; (m) is 1-3] with (B) a compound of the formula: R COX [R is a 5-21C (branched) alkyl, alkenyl, hydroxyalkyl; X is a halogen] and, if necessary, subsequently exchanging the salt, or reacting a compound of formula II with the component B, hydrolyzlng the obtained compound and, if necessary, exchanging the salt, and subsequently treating the reaction solution containing a compound of formula III with (D) a reducing agent such as sodium borohydride or sodium sulfite e.g. in an amount of 50ppm to 5wt.% based on the theoretical amount of the compound of formula III at a pH of 8-14.
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公开(公告)号：JPH09202759A
公开(公告)日：1997-08-05
申请号：JP1016196
申请日：1996-01-24
Applicant: KAO CORP
Inventor： TAKAHASHI MASAKATSU , KABARU TAKESHI , MIZUSHIMA YOUSEN , FUJIO AKIRA
IPC: C07C231/02 , C07C231/10 , C07C235/06 , C07C235/08
Abstract: PROBLEM TO BE SOLVED: To obtain an N-alkylglycolic acid amide by reacting a glycolic acid condensation product with an alkylamine, while inhibiting gelation, bubbling, etc. SOLUTION: This compound of formula I (R is a 6-22C alkyl, an alkenyl, a hydroxyalkyl, etc.; R is H, a 1-22C alkyl, an alkenyl, a hydroxyalkyl, etc.,) is obtained by amidating a glycolic acid condensation product of formula II or III (n is 1.1-200) with an alkylamine of formula IV at 50-250 deg.C. The compound of formula IV is used in an amount of 0.7-1.5 equivalent times (converted into the monomer), preferably 0.95-1.05 equivalent times, based on the compound of formula II or III. The compound of formula I is useful as a base agent or auxiliary agent for various kinds of detergents, and can be derived into various kinds of effective surfactants by adding an alkylene oxide to the terminal hydroxyl group, converting the compound of formula I into a sulfuric ester, etc.
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公开(公告)号：JPH09151169A
公开(公告)日：1997-06-10
申请号：JP31392295
申请日：1995-12-01
Applicant: KAO CORP
Inventor： IMOTO HIROYUKI , FUJIO AKIRA , OSHIMA YUKIKO
IPC: C11D1/06 , C07B61/00 , C07C231/12 , C07C233/18 , C07C233/20
Abstract: PROBLEM TO BE SOLVED: To produce the subject high-purity compound in high yield and selectivity by carrying out the oxidizing reaction of a polyoxyethylene-fatty acid amide in the presence of a stable free radical nitroxide. SOLUTION: A polyoxyethylene-fatty acid amide represented by formula I [R is a 7-21C alkyl or alkenyl; (n) is 0-20] is oxidatevely reacted with an oxidant (e.g. a gas containing oxygen) in the presence of a stable free radical nitroxide represented by formula II (R to R are each a 1-15C alkyl; R and R are each H, a 1-15C alkyl, etc.) and, as necessary, neutralized thereafter to provide an amido-ether carboxylic acid or its salt represented by formula III (M is H or a cation). For example, when the gas containing oxygen is used as the oxidant, a compound generating NOx (e.g. nitric acid) is preferably added thereto and the reaction is carried out at 0-100 deg.C in a solvent (e.g. acetonitrile), or, in the case of using no solvent, at the temperature above the melting point of the raw material and the product to 100 deg.C. 2,2,6,6-Tetramethylpiperidine-1-oxyl is cited as the compound represented by formula II.
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