公开(公告)号：DE69126522T2

公开(公告)日：1997-11-06

申请号：DE69126522

申请日：1991-11-22

Applicant: KAO CORP

Inventor： KITA KATSUMI ,  UNO MITSURU ,  KAMITANI HIROSHI ,  FUJIKURA YOSHIAKI ,  HORINISHI NOBUTAKA ,  KITSUKI TOMOHITO ,  IMAI KAZUYASU ,  KAJIHARA YASUSHI

IPC: C07F9/09 ,  C07F9/655 ,  C07H11/04 ,  C07H15/04 ,  C08B31/06 ,  C11D1/88 ,  C11D3/22 ,  C11D3/36 ,  A61K7/075 ,  C11D1/90

Abstract: A novel phosphobetaine is disclosed. This compound is very excellence in that it exerts a conditioning effect of imparting a good feel to the skin or hair, is excellent in humidifying properties, is available at a low price, and thus it is highly usable in detergents, cosmetics, a bathing preparation and the like. A detergent composition, a cosmetic, and a bathing preparation each containing the phosphobetaine are also disclosed.

公开(公告)号：DE69126522D1

公开(公告)日：1997-07-17

申请号：DE69126522

申请日：1991-11-22

Applicant: KAO CORP

Inventor： KITA KATSUMI ,  UNO MITSURU ,  KAMITANI HIROSHI ,  FUJIKURA YOSHIAKI ,  HORINISHI NOBUTAKA ,  KITSUKI TOMOHITO ,  IMAI KAZUYASU ,  KAJIHARA YASUSHI

IPC: C07F9/09 ,  C07F9/655 ,  C07H11/04 ,  C07H15/04 ,  C08B31/06 ,  C11D1/88 ,  C11D3/22 ,  C11D3/36 ,  A61K7/075 ,  C11D1/90

Abstract: A novel phosphobetaine is disclosed. This compound is very excellence in that it exerts a conditioning effect of imparting a good feel to the skin or hair, is excellent in humidifying properties, is available at a low price, and thus it is highly usable in detergents, cosmetics, a bathing preparation and the like. A detergent composition, a cosmetic, and a bathing preparation each containing the phosphobetaine are also disclosed.

公开(公告)号：JPH05124928A

公开(公告)日：1993-05-21

申请号：JP29306791

申请日：1991-11-08

Applicant: KAO CORP

Inventor： IMAI KAZUYASU ,  KAJIWARA YASUSHI ,  KITA KATSUMI

IPC: A61K8/55 ,  A61K8/00 ,  A61K8/02 ,  A61K8/58 ,  A61K8/60 ,  A61K8/73 ,  A61Q5/00 ,  A61Q5/12 ,  A61Q19/10

Abstract: PURPOSE:To obtain a cosmetic having moisture-retention effect resistant to sweat, water washing, etc., free from stickiness to the skin and hair and giving moist feeling by compounding a specific phosphobetaine. CONSTITUTION:The objective cosmetic contains a phosphobetaine of formula I (Z is residue obtained by removing (m+n) x OH groups from monosaccharide, oligosaccharide, sugar alcohol or glycerol; R to R are alkyl, alkenyl or hydroxyalkyl; M and M are H or cation; (m) is >=0; (n) is >=1) [e.g. alpha-D- glucopyranose-1-[Z-hydroxy-3-(N,N-dimethyl-N-octadecylammonio) propyl]phosphate]. The phosphobetaine of formula I is preferably compounded in an amount of 0.5-10wt.% based on the cosmetic. The compound can be produced e.g. by reacting a phosphoric acid ester of formula 2 with an epoxy compound of formula 3. The cosmetic is especially suitable as a wash-off type rinse and body rinse.

公开(公告)号：JPH05294906A

公开(公告)日：1993-11-09

申请号：JP10122992

申请日：1992-04-21

Applicant: KAO CORP

Inventor： UNO MITSURU ,  KITSUKI TOMOHITO ,  KITA KATSUMI ,  IMAI KAZUYASU ,  FUJIKURA YOSHIAKI

IPC: A61K8/06 ,  A61K8/00 ,  A61K8/40 ,  A61Q5/00 ,  A61Q19/10 ,  C07C227/18 ,  C07C229/04 ,  A61K7/00 ,  A61K7/06 ,  A61K7/50

Abstract: PURPOSE:To obtain a new carbobetaine, excellent in humectant properties, good in touch, producible at a low cost and useful as a base for hair or skin cosmetics, etc., and humectants, etc. CONSTITUTION:The objective carbobetaine of formula I [Z is residue obtained by removing (m+n) OH groups from glycerol or glycerol condensate; A and A are 1-6C alkylene which may have OH; R is 1-24C alkyl or alkenyl which may have OH; R is 2-24C alkyl or alkenyl which may have OH; (m) is >=0; (n) is >=1 and (m+n) is same as the valence of Z], e.g. 1-carboxy-N-methyl-N- hexyl-N-(2,6,7-trihydroxy-4-oxaheptyl)methanaminium hydroxide inert salt. This compound of formula I is obtained by reacting an amino compound of formula II with a compound of formula III (X is halogen; M is cation).

公开(公告)号：JPH05294905A

公开(公告)日：1993-11-09

申请号：JP10122892

申请日：1992-04-21

Applicant: KAO CORP

Inventor： KITSUKI TOMOHITO ,  UNO MITSURU ,  KITA KATSUMI ,  IMAI KAZUYASU ,  FUJIKURA YOSHIAKI

IPC: A61K8/06 ,  A61K8/00 ,  A61K8/40 ,  A61Q5/00 ,  A61Q19/10 ,  C07C227/18 ,  C07C229/04 ,  A61K7/00 ,  A61K7/06 ,  A61K7/50

Abstract: PURPOSE:To obtain a new carbobetaine, excellent in humectant properties, good in touch and producible at a low cost. CONSTITUTION:The objective carbobetaine of formula I [Z is residue obtained by removing (m+n) hydroxyl groups from glycerol or glycerol condensate; R and R are H or methyl; A and A are alkylene which may have OH; (m) is >=0; (n) is >=1 and (m+n) is same as the valence of Z], e.g. 1-carboxy-N,N- dimethyl-N-(2,6,7-trihydroxy-4-oxaheptyl)methanaminium hydroxide inner salt. This carbobetaine of formula I is obtained by reacting an amino compound of formula II with a compound of formula III (X is halogen; M is cation).

公开(公告)号：JPH05132695A

公开(公告)日：1993-05-28

申请号：JP29453091

申请日：1991-11-11

Applicant: KAO CORP

Inventor： IMAI KAZUYASU ,  KAJIWARA YASUSHI ,  KITA KATSUMI

IPC: A61K8/00 ,  A61K8/73 ,  A61Q5/02 ,  A61Q19/10 ,  C11D1/88

Abstract: PURPOSE:To obtain a detergent composition containing a specific phosphobetaine, exhibiting sufficient moisture-preservation effect after cleaning, free from skin feeling of dryness and stretching as well as stickness and capable of giving a moistened touch. CONSTITUTION:The objective composition contains a phosphobetaine of the formula [Z is a polysaccharide which may have a substituent and whose condensation degree of monosaccharide is >=10. (residue obtained eliminating (m+n) hydroxyl groups from a partially hydrolyzed product); R , R and R are H, 1-24C alkyl, alkenyl or alkylphenyl; M and M are H or cationic group; (m) is >=0; (n) is >=1] as an essential component in a detergent component such as anionic surfactant or ethylene glycol, and is suitable as skin cleaner such as face washing agent, body shampoo or cleaning agent for dish.

公开(公告)号：JPH05125392A

公开(公告)日：1993-05-21

申请号：JP29170891

申请日：1991-11-07

Applicant: KAO CORP

Inventor： IMAI KAZUYASU ,  KAJIWARA YASUSHI ,  KITA KATSUMI

IPC: A61K8/00 ,  A61K8/60 ,  A61K8/73 ,  A61Q5/02 ,  A61Q19/10 ,  C11D1/88

Abstract: PURPOSE:To obtain a cleaner composition not causing dryness and stretch of skin, not providing hair with smart, having no greasiness, providing a moist touch after cleaning, containing a specific phosphobetaine. CONSTITUTION:A cleaner comprising ethylene glycol, a surfactant, coconut oil, etc., is mixed with a phosphobetaine of the formula (Z is sugaralcohol, glycerol, oligosaccharide or residue after removal of (m+n) hydroxyl groups from pentose; R , R and R are H, 1-4C alkyl or alkenyl; M and M are H or cationic group; (m) is >=0; (n) is >=1) to give a cleaner composition suitable for skin cleaner such as face washing agent, body shampoo or soap, shampoo or cleaner for tableware, etc.

公开(公告)号：JPH06212198A

公开(公告)日：1994-08-02

申请号：JP773793

申请日：1993-01-20

Applicant: KAO CORP

Inventor： IMAI KAZUYASU ,  HAMADA HIROICHI

IPC: A61K8/00 ,  A61K8/34 ,  A61K8/36 ,  A61K8/37 ,  A61Q5/02 ,  A61Q19/10 ,  C11D9/26 ,  A61K7/075 ,  A61K7/50

Abstract: PURPOSE:To obtain a detergent composition which is excellent in lathering property, detergency, and feeling in its use and stably has a desired viscosity by incorporating a fatty acid soap, a sugar alcohol, and a specific glycerol derivative. CONSTITUTION:The detergent composition comprises a fatty acid soap (e.g. potassium salt of coconut-oil fatty acid), a sugar alcohol (e.g. sorbitol), and a glycerol derivative represented by the formula [wherein one of Z and Z is R -Y- and the other is OH; R and R each is a hydrocarbon group, provided that the sum of the carbon atoms of both is 13-400; and X and Y each is O or -C(=O)-O-].

公开(公告)号：JPH069517A

公开(公告)日：1994-01-18

申请号：JP16625592

申请日：1992-06-24

Applicant: KAO CORP

Inventor： KITSUKI TOMOHITO ,  ATAKA YOSHIHARU ,  KITA KATSUMI ,  IMAI KAZUYASU ,  FUJIKURA YOSHIAKI

IPC: C07C227/10 ,  C07C229/22 ,  C07C229/30

Abstract: PURPOSE:To obtain a new inexpensive carboxybetaine useful as a base for hair and skin cosmetic, etc., a humectant, having excellent moisture retention. CONSTITUTION:A carboxybetaine of formula I (A is straight-chain or branched- chain 3-36C alkylene; R and R are straight-chain or branched-chain 1-36C alkyl or 2-36C alkenyl) such as 1-carboxybutyl-N,N-dimethyl-N-hydroxyethyl-N- methaneaminium hydroxide inner salt. The carboxybetaine of formula I, for example, is obtained by reacting an amine compound of formula II with a compound of formula III (X is halogen; M is H or cation). The carboxybetaine of formula I is useful as an compounding component for a hair cosmetic such as shampoo, rinse and hair conditioner, a skin cosmetic such as toilet lotion and foundation, a humectant, etc.

公开(公告)号：JPH05125394A

公开(公告)日：1993-05-21

申请号：JP29306691

申请日：1991-11-08

Applicant: KAO CORP

Inventor： IMAI KAZUYASU ,  KAJIWARA YASUSHI ,  KITA KATSUMI

IPC: A61K8/00 ,  A61K8/40 ,  A61K8/60 ,  A61K8/73 ,  A61Q5/02 ,  A61Q19/10 ,  C11D1/88

Abstract: PURPOSE:To obtain a cleaner composition not causing dryness and stretch of skin, not providing hair with smart, having no greasiness and providing a moist touch after cleaning, containing a specific phosphobetaine. CONSTITUTION:A cleaner composition comprising a phosphobetaine of the formula (Z is residue after removal of (m+n) hydroxyl groups from monosaccharide, oligosaccharide, sugaralcohol or glycerol; R , R and R are H, 1-24C alkyl or alkenyl; M and M are H or cationic group; (m) is >=0; (n) is >=1) as an essential component to give a cleaner composition suitable for skin cleaner such as face washing agent, body shampoo or soap, shampoo or cleaner for tableware, etc.