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    1.
    发明专利
    未知

    公开(公告)号：DE69518393T2

    公开(公告)日：2001-01-25

    申请号：DE69518393

    申请日：1995-11-28

    Applicant: KAO CORP

    Inventor： SAKAMOTO YUICHI ,  HAYASE TAEKO ,  IDE KAZUTOSHI ,  TOSAKA MASAKI ,  MORII NORIYUKI ,  SHIBATA TOMOKO

    IPC: C11D1/06 ,  C11D1/52 ,  C11D1/65

    Abstract: A detergent composition, which exerts a sufficient detergency and foaming power even in the presence of oily stains and contains the following components (a) and (b), wherein the weight ratio of the content of the component (a) to the content of the component (b) Ä(a)/(b)Ü is from 0.1 to 100; the molar ratio of the total divalent metal salt ions (X) in the whole composition and to total anionic surfactants (Y) including the component (a) (X/Y) is from 0.025 to 10; and the composition contains substantially no component (z) as specified below or the content of said component (z) is not more than 10 % by weight based on the sum of the contents of the components (a) and (b): (a) an amide ether carboxylate represented by the following formula (I): wherein R1 represents a linear or branched alkyl or alkenyl group having 5 to 21 carbon atoms; n and m represent respectively the average number of moles of (CH2CH2O) added and the average number of moles of added and each represents a number of from 0 to 20, provided that they satisfy the formula 1 is random, block or alternating; A represents a hydrogen atom, or an alkyl group having 1 to 3 carbon atoms, wherein k and j each represents an average degree of polymerization of from 0 to 20, provided that they satisfy the formula 0 is random, block or alternating; and M represents an alkali metal, an alkaline earth metal, ammonium, an alkanolammonium or a basic amino acid, and may represent respectively propyleneoxy or polypropyleneoxy group when m and j is respectively not 0, and the methyl group can be bonded at the 2-position in place of 1-position of the ethoxy unit; (b) an amide ether represented by the following formula (II): wherein B represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, wherein R1, n, m, k and j are each as defined above, and when m and n is respectively not 0, the copolymerization form of (CH2CH2O) and is random, block or alternating, and in the above formulae (I) and (II), R1, n, m, k and j may be either the same or different, and may represent respectively propyleneoxy or polypropyleneoxy group when m and j is respectively not 0, and the methyl group can be bonded at the 2-position in place of 1-position of the ethoxy unit; and (z) glycerol or a glyceryl ether represented by the following formula (III): wherein R represents a hydrogen atom, -(CH2CH2O)pCH2COOM or - (CH2CH2O)qH and three Rs in a molecule may be either the same or different, wherein p and q may be either the same or different and each represents a number of 1 to 20, and M represents a hydrogen atom, an alkali metal, an alkaline earth metal, ammonium or an alkanolammonium.

    2.
    发明专利
    未知

    公开(公告)号：DE69518393D1

    公开(公告)日：2000-09-21

    申请号：DE69518393

    申请日：1995-11-28

    Applicant: KAO CORP

    Inventor： SAKAMOTO YUICHI ,  HAYASE TAEKO ,  IDE KAZUTOSHI ,  TOSAKA MASAKI ,  MORII NORIYUKI ,  SHIBATA TOMOKO

    IPC: C11D1/06 ,  C11D1/52 ,  C11D1/65

    Abstract: A detergent composition, which exerts a sufficient detergency and foaming power even in the presence of oily stains and contains the following components (a) and (b), wherein the weight ratio of the content of the component (a) to the content of the component (b) Ä(a)/(b)Ü is from 0.1 to 100; the molar ratio of the total divalent metal salt ions (X) in the whole composition and to total anionic surfactants (Y) including the component (a) (X/Y) is from 0.025 to 10; and the composition contains substantially no component (z) as specified below or the content of said component (z) is not more than 10 % by weight based on the sum of the contents of the components (a) and (b): (a) an amide ether carboxylate represented by the following formula (I): wherein R1 represents a linear or branched alkyl or alkenyl group having 5 to 21 carbon atoms; n and m represent respectively the average number of moles of (CH2CH2O) added and the average number of moles of added and each represents a number of from 0 to 20, provided that they satisfy the formula 1 is random, block or alternating; A represents a hydrogen atom, or an alkyl group having 1 to 3 carbon atoms, wherein k and j each represents an average degree of polymerization of from 0 to 20, provided that they satisfy the formula 0 is random, block or alternating; and M represents an alkali metal, an alkaline earth metal, ammonium, an alkanolammonium or a basic amino acid, and may represent respectively propyleneoxy or polypropyleneoxy group when m and j is respectively not 0, and the methyl group can be bonded at the 2-position in place of 1-position of the ethoxy unit; (b) an amide ether represented by the following formula (II): wherein B represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, wherein R1, n, m, k and j are each as defined above, and when m and n is respectively not 0, the copolymerization form of (CH2CH2O) and is random, block or alternating, and in the above formulae (I) and (II), R1, n, m, k and j may be either the same or different, and may represent respectively propyleneoxy or polypropyleneoxy group when m and j is respectively not 0, and the methyl group can be bonded at the 2-position in place of 1-position of the ethoxy unit; and (z) glycerol or a glyceryl ether represented by the following formula (III): wherein R represents a hydrogen atom, -(CH2CH2O)pCH2COOM or - (CH2CH2O)qH and three Rs in a molecule may be either the same or different, wherein p and q may be either the same or different and each represents a number of 1 to 20, and M represents a hydrogen atom, an alkali metal, an alkaline earth metal, ammonium or an alkanolammonium.

    SPRAY-TYPE SIZING AGENT COMPOSITION
    4.
    发明专利
    SPRAY-TYPE SIZING AGENT COMPOSITION 失效

    公开(公告)号：JPH05171570A

    公开(公告)日：1993-07-09

    申请号：JP33853591

    申请日：1991-12-20

    Applicant: KAO CORP

    Inventor： HASEGAWA YOSHITAKA ,  SHIBATA TOMOKO

    IPC: D06M23/00 ,  D06M13/02 ,  D06M13/322 ,  D06M13/47 ,  D06M13/473 ,  D06M15/21 ,  D06M15/356 ,  D06M15/37 ,  D06M23/06

    Abstract: PURPOSE:To provide the subject composition composed mainly of a polymer having a specific structure, exhibiting film-forming property and antistaticity and having excellent stain-proofing effect. CONSTITUTION:The objective spray-type sizing agent composition is produced by polymerizing a diallyldialkyl ammonium salt having the structure of the formula (R1 and R2 are 1-18C alkyl or hydroxyalkyl; X is halogen, CH3SO4 or C2H5SO4; (n) is number corresponding to a molecular weight of 1,000-6,000,000) and filling the obtained polymer together with a propellant in a pressure vessel for aerosol. A woven fabric sprayed with the composition has excellent bending resistance (tightness), antistaticity and resistance to staining. The attached stain can easily be removed by washing.

    DETERGENT COMPOSITION FOR AUTOMATIC DISHWASHER
    7.
    发明专利
    DETERGENT COMPOSITION FOR AUTOMATIC DISHWASHER 失效

    公开(公告)号：JPH07179900A

    公开(公告)日：1995-07-18

    申请号：JP32879693

    申请日：1993-12-24

    Applicant: KAO CORP

    Inventor： YOSHIDA YUKIKO ,  MORII NORIYUKI ,  SHIBATA TOMOKO

    IPC: C11D1/72 ,  C11D3/10 ,  C11D3/20 ,  C11D3/386 ,  C11D17/00

    Abstract: PURPOSE:To obtain a detergent for automatic dishwashers which is lowly foaming and defoamable and excellent in detergency to oil stains by combining a specific polyoxyalkylene derivative, an enzyme and an alkali in a given weight proportion. CONSTITUTION:One or two compounds selected from an alkylene oxide addition product of a monohydric alcohol of formula I, an alkylene oxide addition product of an alkylphenol of formula II and an alkylene oxide addition product of a monovalent mercaptan of formula III (in each formula R1 is a 10-24 C alkyl or alkenyl; R2 is ethylene or propylene ; R3 is a 4-18 C alkyl or alkenyl; (n) is 3-20) are reacted with a diepoxide compound (e.g. beta, gamma-epoxypropyl ether). Then, 1-20wt.% of the polyoxyalkylene derivative thus obtained, an enzyme (e.g. protease) and 1-85wt.% of an alkali are combined to prepare the objective detergent composition.

    SPRAY-TYPE PASTE COMPOSITION
    8.
    发明专利
    SPRAY-TYPE PASTE COMPOSITION 失效

    公开(公告)号：JPH05209369A

    公开(公告)日：1993-08-20

    申请号：JP21275592

    申请日：1992-08-10

    Applicant: KAO CORP

    Inventor： HASEGAWA YOSHITAKA ,  SHIBATA TOMOKO ,  YAMAMURA MASAAKI

    IPC: D06M23/00 ,  D06M15/21 ,  D06M15/356 ,  D06M23/06

    Abstract: PURPOSE:To provide the subject composition excellent in sticking ability also adhered dirt-removing effect, comprising a polymer of from a sulfonate group- contg. vinyl monomer or its copolymer with another vinyl monomer. CONSTITUTION:The objective composition with e.g. liquefied propane as propellant, having the above-mentioned advantages, consists mainly of (A) a polymer from sulfonate group-contg. vinyl monomer (e.g. styrenesulfonic acid) or its salt (pref. sodium salt), (B) a copolymer (or its salt) from at least two kinds of such monomer, or (C) a copolymer from the above monomer with another monomer [e.g. (meth)acrylic monomer], where the content of the former monomer is >=30mol% of the copolymer.

    DISPOSABLE DIAPER
    9.
    发明专利
    DISPOSABLE DIAPER 失效

    公开(公告)号：JPH1052454A

    公开(公告)日：1998-02-24

    申请号：JP21091596

    申请日：1996-08-09

    Applicant: KAO CORP

    Inventor： HAYASE TORU ,  SHIBATA TOMOKO

    IPC: A61F13/494 ,  A61F5/44 ,  A61F13/15 ,  A61F13/49 ,  A61F13/496 ,  A61F13/511

    Abstract: PROBLEM TO BE SOLVED: To provide a disposable diaper which does not harm the skin of an user and prevents leakage at the waist region. especially at the abdomen region of the waist. SOLUTION: This disposable diaper is provided with a liquid permeable surface sheet 2, a liquid impermeable back sheet 3, and a liquid retaining absorption member 4 between them, and multiple leakage proof walls 10 of 3 to 10mm height are arranged at the surface sheet 2 side of a waist region 5 located at the waist of an user during using. If a height h of the leakage proof wall 10 is less than 3mm, the leakage proof wall does not function and urine is leaked at the abdomen of the waist region, and if more than 10mm, a desired purpose cannot be realized since the leakage proof wall fall down, further it may have a bad affect on the skin.

    10.
    发明专利
    失效

    公开(公告)号：JPH05239774A

    公开(公告)日：1993-09-17

    申请号：JP3508392

    申请日：1992-02-21

    Applicant: KAO CORP

    Inventor： HASEGAWA YOSHITAKA ,  SHIBATA TOMOKO ,  YAMAMURA MASAAKI

    IPC: D06M15/11 ,  D06M15/643

    Abstract: PURPOSE:To obtain a sizing agent containing a water soluble high polymer sizing agent, a water insoluble silicone having a specific particle shape and water, excellent in long-period stability, good in sliding of iron and especially suitable for manual type spray. CONSTITUTION:The objective textile finishing agent for household, stable without separating and good in sliding of iron is obtained by adding a surfactant, preferably of polyoxyethylene alkyl ether, etc., to an aqueous sizing agent containing (A) 0.1-10wt.% water soluble high polymer sizing agent, e.g. hydroxyalkylated starch or CMC and (B) 0.005-1wt.% water-insoluble silicone having 0.001-1mum particle diameter of dispersed particles, e.g. dimethylpolysiloxane and/or carboxy-modified polysiloxane. The finishing agent is unnecessary to shake before using and suitable as a manual type spray.

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