Abstract:
The present invention provides oils for cosmetics comprising a dibasic acid diester represented by general formula (I) (wherein R , R , R and R , which are the same or different, each represent lower alkyl) and excellent in solubility of a long-wave ultraviolet light absorber or the like, and so forth.
Abstract:
A process by which an ether compound useful in chemical amplification type resist compositions, as an intermediate for medicines, in coating materials, or in other applications can be produced in high yield while diminishing side reactions. The process, which is for producing an ether compound having a group represented by the general formula (II): (II) (wherein R1, R2, and R3 are the same or different and each represents (un)saturated alkyl, (un)saturated aryl, or (un)saturated aralkyl, provided that R1 and R2 may form a cycloalkyl in cooperation with the adjacent carbon atom), is characterized by reacting a compound having a hydroxy (or carboxy) group with an alkenyl ether represented by the general formula (I): (I) (wherein R1, R2, and R3 are the same as defined above).
Abstract:
The present invention provides dibasic acid diesters, which are suitable for use in lubricating base oils, etc. and excellent in hydrolysis resistance, etc., represented by general formula (I): (wherein R and R , which may be the same or different, each represent lower alkyl; and R and R , which may be the same or different, each represent alkyl having 7 or more carbon atoms).
Abstract:
A composition which comprises a compound having at least one five-membered dithiocarbonate ring group represented by general formula (I) (wherein R?1, R2, and R3¿ are the same or different and each represents hydrogen or lower alkyl) and either a secondary diamine represented by general formula (II) (wherein X represents C¿4-20? alkylene) or an enamine derivative thereof. It is useful in applicatios such as a coating composition, adhesive, ink, sealing material, and encapsulation material.
Abstract:
PROBLEM TO BE SOLVED: To obtain a cycloalkyldiaryphosphine in which the 2-position of a cycloalkyl is substituted with an alkyl by an industrially readily handleable method in a short process in a high yield by reacting a lithium diaryl phosphide with a cycloalkylsulfonate in an ether-based solvent. SOLUTION: A lithium diaryl phosphide of the formula LiPR1R2 (R1 and R2 are each a substituted or nonsubstituted aryl) is reacted with a cycloalkylsulfonate of the formula: R3OSO2R4 (R3 is a cycloalkyl substituted with an alkyl at the 2-position; R4 is a lower alkyl or phenyl substituted with a lower alkyl) in an ether-based solvent (a cyclic alkyl monoether preferably such as tetrahydrofuran, etc.), to give the objective compound of the formula. Preferably lithium diphenyl phosphide is reacted with menthyl mesylate or menthyl tosylate to give d-neomenthyldiphenylphosphine. The reaction temperature is preferably 25-35 deg.C.