PROCESS FOR PRODUCING ETHER COMPOUND
    4.
    发明公开
    PROCESS FOR PRODUCING ETHER COMPOUND 审中-公开
    制造方法醚化合物

    公开(公告)号:EP1415968A4

    公开(公告)日:2004-12-08

    申请号:EP02746017

    申请日:2002-07-12

    Applicant: KYOWA YUKA KK

    CPC classification number: G03F7/0392 C07C67/04 C07C69/54

    Abstract: A process by which an ether compound useful in chemical amplification type resist compositions, as an intermediate for medicines, in coating materials, or in other applications can be produced in high yield while diminishing side reactions. The process, which is for producing an ether compound having a group represented by the general formula (II): (II) (wherein R1, R2, and R3 are the same or different and each represents (un)saturated alkyl, (un)saturated aryl, or (un)saturated aralkyl, provided that R1 and R2 may form a cycloalkyl in cooperation with the adjacent carbon atom), is characterized by reacting a compound having a hydroxy (or carboxy) group with an alkenyl ether represented by the general formula (I): (I) (wherein R1, R2, and R3 are the same as defined above).

    PRODUCTION OF CYCLOALKYLDIARYLPHOSPHINES

    公开(公告)号:JP2000128891A

    公开(公告)日:2000-05-09

    申请号:JP30125898

    申请日:1998-10-22

    Applicant: KYOWA YUKA KK

    Abstract: PROBLEM TO BE SOLVED: To obtain a cycloalkyldiaryphosphine in which the 2-position of a cycloalkyl is substituted with an alkyl by an industrially readily handleable method in a short process in a high yield by reacting a lithium diaryl phosphide with a cycloalkylsulfonate in an ether-based solvent. SOLUTION: A lithium diaryl phosphide of the formula LiPR1R2 (R1 and R2 are each a substituted or nonsubstituted aryl) is reacted with a cycloalkylsulfonate of the formula: R3OSO2R4 (R3 is a cycloalkyl substituted with an alkyl at the 2-position; R4 is a lower alkyl or phenyl substituted with a lower alkyl) in an ether-based solvent (a cyclic alkyl monoether preferably such as tetrahydrofuran, etc.), to give the objective compound of the formula. Preferably lithium diphenyl phosphide is reacted with menthyl mesylate or menthyl tosylate to give d-neomenthyldiphenylphosphine. The reaction temperature is preferably 25-35 deg.C.

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