Abstract:
A method is provided for producing a self-supporting ceramic body comprising a polycrystalline material comprised of the oxidation reaction product of a parent metal (10) and having therein one or more channels which inversely replicate the geometry of a configured fugitive metal (6). The method includes providing an assembly of the configured fugitive metal (6) and the parent metal (10), optionally including a bed of permeable filler (4), and heating the assembly to form a body of molten parent metal. The molten parent metal is oxidized under selected conditions to grow the polycrystalline material to engulf the configured fugitive metal (6) (and to infiltrate the filler (4), if the filler (4) is present) and to cause the fugitive metal (6) to disperse into the engulfing polycrystalline material thereby leaving behind as the one or more channels the space formerly occupied by the configured fugitive metal (6). The method provides self-supporting ceramic bodies having therein one or more channels inversely replicating the shape of the configured fugitive metal (6).
Abstract:
A method is provided for producing a self-supporting ceramic body comprising a polycrystalline material comprised of the oxidation reaction product of a parent metal (10) and having therein one or more channels which inversely replicate the geometry of a configured fugitive metal (6). The method includes providing an assembly of the configured fugitive metal (6) and the parent metal (10), optionally including a bed of permeable filler (4), and heating the assembly to form a body of molten parent metal. The molten parent metal is oxidized under selected conditions to grow the polycrystalline material to engulf the configured fugitive metal (6) (and to infiltrate the filler (4), if the filler (4) is present) and to cause the fugitive metal (6) to disperse into the engulfing polycrystalline material thereby leaving behind as the one or more channels the space formerly occupied by the configured fugitive metal (6). The method provides self-supporting ceramic bodies having therein one or more channels inversely replicating the shape of the configured fugitive metal (6).
Abstract:
This invention relates to a method for producing a self-supporting ceramic structure comprising an oxidation reaction product of a parent metal and a vapor-phase oxidant characterized by a refined microstructure attributable to the addition of one or more process modifiers relative to substantially the same oxidation reaction product produced without a process modifier.
Abstract:
Self-supporting bodies are produced by reactive infiltration of a «boron source with a parent metal» typically resulting in a composite comprising a parent metal boride and metal. The mass to be infiltrated may contain one or more inert fillers admixed with the boron source to produce a composite by reactive infiltration, which composite comprises a matrix of metal and parent metal boride embedding the filler. The relative amounts of reactants and process conditions may be altered or controlled to yield a body containing varying volume percents of ceramic, metal and/or porosity.
Abstract:
Self-supporting bodies are produced by reactive infiltration of a parent metal (10) into boron carbide (12) typically resulting in a composite comprising a boron-containing compound and metal. The mass to be infiltrated may contain one or more inert fillers (14) admixed with the boron carbide (12) to produce a composite by reactive infiltration, which composite comprises a matrix of metal and boron-containing compound embedding the filler (14). The relative amounts of reactants and process conditions may be altered or controlled to yield a body containing varying volume percents of ceramic, metal and/or porosity.
Abstract:
This invention relates to a method for producing a self-supporting ceramic structure comprising an oxidation reaction product of a parent metal and a vapor-phase oxidant characterized by a refined microstructure attributable to the addition of one or more process modifiers relative to substantially the same oxidation reaction product produced without a process modifier.