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    (WATER-BASE) METAL-PROCESSING OIL CONTAINING SULFONATE-CONTAINING COPOLYMER AS MIST PREVENTIVE IN SOLUBLE OIL
    1.
    发明专利
    (WATER-BASE) METAL-PROCESSING OIL CONTAINING SULFONATE-CONTAINING COPOLYMER AS MIST PREVENTIVE IN SOLUBLE OIL 失效

    公开(公告)号：JPH1046178A

    公开(公告)日：1998-02-17

    申请号：JP12114397

    申请日：1997-05-12

    Applicant: LUBRIZOL CORP

    Inventor： KALHAN SANJAY ,  MANN JAMES T ,  DENIS RICHARD A

    IPC: C10M151/02 ,  C10M173/00 ,  C10M173/02 ,  C10N30/00 ,  C10N40/22

    Abstract: PROBLEM TO BE SOLVED: To obtain a water-base metal-processing oil contg. water and a mist- preventive copolymer by copolymerizing a specific hydrophobic monomer and a specific hydrophilic monomer. SOLUTION: A hydrophobic monomer being either an alkylate acrylamide compd. represented by formula I (wherein R1 is H or methyl; and R2 and R3 are each H or hydrocarbyl provided their total number of carbon atoms is 2-36) or an acrylic ester represented by formula III (wherein R1 is H or methyl; and R9 is a 1-20C hydrocarbyl) and a hydrophilic monomer selected from among an acrylamidosulfonic acid salt represented by formula III (wherein R4 is H or methyl; and R is a 2-8C aliph. or arom. hydrocarbon group), an acrylamidodisulfonic acid salt represented by formula IV (wherein R4 is H or methyl; and R is a 2-8C aliph. or arom. hydrocarbon group), and a styrenesulfonic acid salt represented by formula V (wherein X is an alkali or alkaline earth metal caiton, etc.) are subjected to free-radical copolymn.

    BRANCHED SULFONATE-CONTAINING COPOLYMER AS MIST INHIBITOR IN SOLUBLE OIL (WATER-BASE) METAL WORKING FLUID
    2.
    发明专利
    BRANCHED SULFONATE-CONTAINING COPOLYMER AS MIST INHIBITOR IN SOLUBLE OIL (WATER-BASE) METAL WORKING FLUID 失效

    公开(公告)号：JPH11236589A

    公开(公告)日：1999-08-31

    申请号：JP33177798

    申请日：1998-11-20

    Applicant: LUBRIZOL CORP

    Inventor： LANGE RICHARD M ,  KALHAN SANJAY ,  DENIS RICHARD A

    IPC: C10M107/46 ,  C08F212/14 ,  C08F220/10 ,  C08F220/54 ,  C08L25/18 ,  C08L33/00 ,  C10M173/00 ,  C10M173/02 ,  C10N30/00 ,  C10N40/22

    Abstract: PROBLEM TO BE SOLVED: To obtain a working fluid which can inhibit mist appearance in metal working application by incorporating water and a copolymer formed from a specific hydrophobic monomer, a specific hydrophilic monomer, and an ethylenically unsatd. branched monomer into the same. SOLUTION: This working fluid contains water and a copolymer which is formed from (A) a hydrophobic monomer comprising an alkyl-substd. acrylamide of formula I and/or an acrylic ester of formula II, (B) a hydrophilic monomer comprising a sulfonic acid (salt) of formula III and/or styrenesulfonic acid or its salt, and (C) an ethylenically unsatd. branched monomer, both the molar ratio of A/B and the amt. of C being specified. In the formulas, R1 is H or CB3 ; R2 and R3 are each H or hydrocarbyl provided the sum of their numbers of carbon atoms is 2 to about 36; R9 is hydrocarbyl or an alkyl- terminated polyether group; X is O or NY; Y is H, 1-18C hydrocarbyl, or -R(-SO3 H)n ; R4 is R1 ; R is a 2 to about 18C aliph. or arom. hydrocarbylene group; and n is 1 or 2. The salt of monomer B is e.g. an alkali or alkaline earth metal salt.

    EMULSIFIER BLEND REPLACEMENT FOR NATURAL SODIUM SULFONATES IN METALWORKING APPLICATIONS
    5.
    发明专利
    EMULSIFIER BLEND REPLACEMENT FOR NATURAL SODIUM SULFONATES IN METALWORKING APPLICATIONS 未知

    公开(公告)号：CA2544525C

    公开(公告)日：2012-08-07

    申请号：CA2544525

    申请日：2004-11-12

    Applicant: LUBRIZOL CORP

    Inventor： KALHAN SANJAY ,  OLLINGER CHRISTIAN G ,  PHILLIPS DEREK T

    IPC: C09K23/00 ,  C09K23/52 ,  C09K23/12 ,  C09K23/16 ,  C09K23/22 ,  C09K23/34 ,  C09K23/36 ,  C10M159/12

    Abstract: Synthetic alkyl arenesulfonates in combination with the salt of a coupled reaction product of (A)(I) high-molecular weight polycarboxylic acylating agent, said acylating agent (A)(I) having at least one hydrocarbyl substituent having an average of from about 20 to about 500 carbon atoms, and at least one (B)(I) low-molecular weight polycarboxylic acylating agent, said acylating agent (B)(I) optionally having at least one hydrocarbyl substituent having an average of about 6 to about 19 carbon atoms, being coupled together by (C) at least one compound having (i) two or more primary amino groups, (ii) two or more secondary amino groups, (iii) at least one primary amino group and at least one secondary amino group, (iv) at least two hydroxyl groups or (v) at least one primary or secondary amino group and at least one hydroxyl group. These salt compositions are useful as emulsifiers in oil-in-water emulsions useful as functional fluids.

    6.
    发明专利
    未知

    公开(公告)号：DE60107970T2

    公开(公告)日：2005-12-08

    申请号：DE60107970

    申请日：2001-08-03

    Applicant: LUBRIZOL CORP

    Inventor： DENIS A ,  KALHAN SANJAY ,  QUINN E

    IPC: C10M173/00

    Abstract: Aqueous metal working fluids containing a water-soluble mist suppressing copolymer are disclosed. The copolymer includes styrene or hydrocarbyl-substituted styrene hydrophobic monomers and hydrophilic monomers. Optionally, the metal working fluid can be an oil-in-water emulsion.

    COMPOSICIONES SUPRESORAS DE NEBLINAS ESTABLES AL CIZALLAMIENTO.
    7.
    发明专利
    COMPOSICIONES SUPRESORAS DE NEBLINAS ESTABLES AL CIZALLAMIENTO. 未知

    公开(公告)号：ES2234868T3

    公开(公告)日：2005-07-01

    申请号：ES01959459

    申请日：2001-08-03

    Applicant: LUBRIZOL CORP

    Inventor： DENIS RICHARD A ,  KALHAN SANJAY ,  QUINN ROBERT E

    IPC: C10M173/00

    Abstract: Un método para reducir la formación de neblinas en un sistema acuoso sometido a elevado efecto de cizalla que supone la aplicación de una composición acuosa al citado sistema de elevado efecto de cizalla, que comprende: incluir en la citada composición acuosa un copolímero supresor de neblinas, dispersable en agua, que comprende (A) unidades de monómero hidrófobo que comprenden al menos un hidrocarburo insaturado o tal hidrocarburo que tiene un sustituyente hidrocarbilo, conteniendo las citadas unidades de monómero de 3 a 30 átomos de carbono; y (B) unidades de monómero hidrófilo que comprenden al menos un ácido sulfónico polimerizable o sal del mismo seleccionado de los ácidos sulfónicos y sales de los mismos, donde R4 es un hidrógeno o un grupo metilo y R es un grupo hidrocarburo alifático o aromático que contiene 2 a 12 átomos de carbono; donde las sales se seleccionan de sales de metal alcalino, sales de metal alcalino-térreo, sales de los metales Sc, Ti, V. Cr, Mn, Fe, Co, Ni, Cu, Ce yZn y sales de amonio, donde el ión amonio está representado por R5R6R7R8N+ donde R4, R5, R6, R7 y R8 son, independientemente, hidrógeno o grupos hidrocarbilo, siempre que el número total de átomos de carbono en un catión amonio no exceda de 21 átomos de carbono.

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