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    (WATER-BASE) METAL-PROCESSING OIL CONTAINING SULFONATE-CONTAINING COPOLYMER AS MIST PREVENTIVE IN SOLUBLE OIL
    6.
    发明专利
    (WATER-BASE) METAL-PROCESSING OIL CONTAINING SULFONATE-CONTAINING COPOLYMER AS MIST PREVENTIVE IN SOLUBLE OIL 失效

    公开(公告)号：JPH1046178A

    公开(公告)日：1998-02-17

    申请号：JP12114397

    申请日：1997-05-12

    Applicant: LUBRIZOL CORP

    Inventor： KALHAN SANJAY ,  MANN JAMES T ,  DENIS RICHARD A

    IPC: C10M151/02 ,  C10M173/00 ,  C10M173/02 ,  C10N30/00 ,  C10N40/22

    Abstract: PROBLEM TO BE SOLVED: To obtain a water-base metal-processing oil contg. water and a mist- preventive copolymer by copolymerizing a specific hydrophobic monomer and a specific hydrophilic monomer. SOLUTION: A hydrophobic monomer being either an alkylate acrylamide compd. represented by formula I (wherein R1 is H or methyl; and R2 and R3 are each H or hydrocarbyl provided their total number of carbon atoms is 2-36) or an acrylic ester represented by formula III (wherein R1 is H or methyl; and R9 is a 1-20C hydrocarbyl) and a hydrophilic monomer selected from among an acrylamidosulfonic acid salt represented by formula III (wherein R4 is H or methyl; and R is a 2-8C aliph. or arom. hydrocarbon group), an acrylamidodisulfonic acid salt represented by formula IV (wherein R4 is H or methyl; and R is a 2-8C aliph. or arom. hydrocarbon group), and a styrenesulfonic acid salt represented by formula V (wherein X is an alkali or alkaline earth metal caiton, etc.) are subjected to free-radical copolymn.

    BRANCHED SULFONATE-CONTAINING COPOLYMER AS MIST INHIBITOR IN SOLUBLE OIL (WATER-BASE) METAL WORKING FLUID
    7.
    发明专利
    BRANCHED SULFONATE-CONTAINING COPOLYMER AS MIST INHIBITOR IN SOLUBLE OIL (WATER-BASE) METAL WORKING FLUID 失效

    公开(公告)号：JPH11236589A

    公开(公告)日：1999-08-31

    申请号：JP33177798

    申请日：1998-11-20

    Applicant: LUBRIZOL CORP

    Inventor： LANGE RICHARD M ,  KALHAN SANJAY ,  DENIS RICHARD A

    IPC: C10M107/46 ,  C08F212/14 ,  C08F220/10 ,  C08F220/54 ,  C08L25/18 ,  C08L33/00 ,  C10M173/00 ,  C10M173/02 ,  C10N30/00 ,  C10N40/22

    Abstract: PROBLEM TO BE SOLVED: To obtain a working fluid which can inhibit mist appearance in metal working application by incorporating water and a copolymer formed from a specific hydrophobic monomer, a specific hydrophilic monomer, and an ethylenically unsatd. branched monomer into the same. SOLUTION: This working fluid contains water and a copolymer which is formed from (A) a hydrophobic monomer comprising an alkyl-substd. acrylamide of formula I and/or an acrylic ester of formula II, (B) a hydrophilic monomer comprising a sulfonic acid (salt) of formula III and/or styrenesulfonic acid or its salt, and (C) an ethylenically unsatd. branched monomer, both the molar ratio of A/B and the amt. of C being specified. In the formulas, R1 is H or CB3 ; R2 and R3 are each H or hydrocarbyl provided the sum of their numbers of carbon atoms is 2 to about 36; R9 is hydrocarbyl or an alkyl- terminated polyether group; X is O or NY; Y is H, 1-18C hydrocarbyl, or -R(-SO3 H)n ; R4 is R1 ; R is a 2 to about 18C aliph. or arom. hydrocarbylene group; and n is 1 or 2. The salt of monomer B is e.g. an alkali or alkaline earth metal salt.

    COMPOSICIONES SUPRESORAS DE NEBLINAS ESTABLES AL CIZALLAMIENTO.
    8.
    发明专利
    COMPOSICIONES SUPRESORAS DE NEBLINAS ESTABLES AL CIZALLAMIENTO. 未知

    公开(公告)号：ES2234868T3

    公开(公告)日：2005-07-01

    申请号：ES01959459

    申请日：2001-08-03

    Applicant: LUBRIZOL CORP

    Inventor： DENIS RICHARD A ,  KALHAN SANJAY ,  QUINN ROBERT E

    IPC: C10M173/00

    Abstract: Un método para reducir la formación de neblinas en un sistema acuoso sometido a elevado efecto de cizalla que supone la aplicación de una composición acuosa al citado sistema de elevado efecto de cizalla, que comprende: incluir en la citada composición acuosa un copolímero supresor de neblinas, dispersable en agua, que comprende (A) unidades de monómero hidrófobo que comprenden al menos un hidrocarburo insaturado o tal hidrocarburo que tiene un sustituyente hidrocarbilo, conteniendo las citadas unidades de monómero de 3 a 30 átomos de carbono; y (B) unidades de monómero hidrófilo que comprenden al menos un ácido sulfónico polimerizable o sal del mismo seleccionado de los ácidos sulfónicos y sales de los mismos, donde R4 es un hidrógeno o un grupo metilo y R es un grupo hidrocarburo alifático o aromático que contiene 2 a 12 átomos de carbono; donde las sales se seleccionan de sales de metal alcalino, sales de metal alcalino-térreo, sales de los metales Sc, Ti, V. Cr, Mn, Fe, Co, Ni, Cu, Ce yZn y sales de amonio, donde el ión amonio está representado por R5R6R7R8N+ donde R4, R5, R6, R7 y R8 son, independientemente, hidrógeno o grupos hidrocarbilo, siempre que el número total de átomos de carbono en un catión amonio no exceda de 21 átomos de carbono.

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