Abstract:
Un adhesivo de laminación que comprende: un componente de poliisocianato (A) que no contiene un derivado de diisocianato de isoforona, y un componente de poliol (B), en el que el componente de poliisocianato (A) contiene un poliisocianato (A1) que no contiene un anillo aromático, y el componente de poliol (B) contiene un macropoliol (B1) que no contiene un anillo aromático sino que contiene un anillo de ciclohexano, dicho macropoliol (B1) es un poliuretano poliol (B1-1') obtenido por reacción de un poliol cristalino (B1-1a') que no contiene un anillo aromático y es cristalino a la temperatura normal con un poliisocianato (B-1-1b) que no contiene un anillo aromático sino que contiene un anillo de ciclohexano; y en el que el poliol cristalino (B1-1a') contiene un policarbonato diol cristalino que es cristalino a la temperatura normal.
Abstract:
Disclosed is an adhesive for laminates, which contains a polyisocyanate component (A) and a polyol component (B). The polyisocyanate component (A) contains a polyisocyanate (A1) having no aromatic ring. The polyol component (B) contains a macropolyol (B1) having a cyclohexane ring but not an aromatic ring.
Abstract:
PROBLEM TO BE SOLVED: To provide a two component curable solvent-free adhesive supply device in which the temperature of a polyisocyanate component can be readily controlled.SOLUTION: In a supply device 1, a two component curable solvent-free adhesive L is prepared by mixing a polyisocyanate component containing a polyisocyanate and not containing a solvent with a polyol component containing a polyol and not containing a solvent, and the adhesive L is supplied to a solvent-free laminator 20. The supply device 1 includes a mixing unit 4 for mixing the polyisocyanate component and the polyol component, a polyisocyanate tank 5 for storing the polyisocyanate component, a polyisocyanate supply line 6 connected to the polyisocyanate tank 5 and the mixing unit 4, and a heater 7 for heating the polyisocyanate supply line 6.
Abstract:
PROBLEM TO BE SOLVED: To provide a curing agent capable of improving adhesion, acid/alkaline resistance, solvent resistance, stain resistance and weather resistance in a good balance, and to provide a two-liquid cured polyurethane composition containing the curing agent.SOLUTION: A curing agent contains 30 to 90 wt.% of a xylylene diisocyanate derivative and 10 to 70 wt.% of a hexamethylene diisocyanate derivative. Adhesion, acid/alkaline resistance, solvent resistance, stain resistance and weather resistance are improved in a good balance by the curing agent and a two-liquid cured polyurethane composition containing the curing agent. Therefore the curing agent and the two-liquid cured polyurethane composition containing the curing agent is used preferably in various industrial fields such as a coating material, an ink and an adhesive agent.
Abstract:
PROBLEM TO BE SOLVED: To provide a polyurethane resin composition which can be suitably used as an adhesive for a base material made of a resin with a low polarity such as a polyolefin film.SOLUTION: The polyurethane resin composition includes an active hydrogen group-containing urethane prepolymer and polyisocyanate or an isocyanate group-containing urethane prepolymer and an active hydrogen compound, and the active hydrogen group- or isocyanate group-containing urethane prepolymer is obtained by reacting allophanate group-containing polyisocyanate having hydrocarbon groups in which the number of carbons is ≥5 on the side chains with an active hydrogen compound of two or more functions. Particularly, the allophanate group-containing polyisocyanate is obtained preferably by reacting a ≥5C alcoholic hydroxy group-containing compound with organic diisocyanate using an organic bismuth carboxylate and organic phosphite triester.
Abstract:
Polyurethane resin compositions include a urethane prepolymer with an active hydrogen group and a polyisocyanate, or a urethane prepolymer with an isocyanate group and an active hydrogen compound. The urethane prepolymers having an active hydrogen group or an isocyanate group are obtained by reacting an allophanate group-containing polyisocyanate with a side-chain hydrocarbon group of 5 or more carbon atoms and a bifunctional or polyfunctional active hydrogen compound. Particularly preferably, the allophanate group-containing polyisocyanate is obtained by reacting a C5 or higher carbon number compound having an alcoholic hydroxyl group and an organic diisocyanate, in the presence of an organic bismuth carboxylate and an organic phosphite triester. The polyurethane resin compositions are suited for use as adhesives for bonding low-polarity resin bases such as polyolefin films.