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    2.
    发明专利
    未知

    公开(公告)号：AT503816T

    公开(公告)日：2011-04-15

    申请号：AT07707333

    申请日：2007-01-24

    Applicant: MITSUI CHEMICALS INC

    Inventor： YASUI SHIGEYUKI ,  OTA SEIJI ,  SAKUMA TAKASHI

    IPC: C09J151/06 ,  B32B27/32 ,  C08F255/02 ,  C08L51/06 ,  C09J123/12 ,  C09J123/16 ,  C09J123/26

    Abstract: An object of the present invention is to provide polypropylene adhesive excellent in both initial adhesion and adhesion after heat history; and a laminate excellent in adhesion and heat resistance. Provided is a polypropylene-based adhesive having an MFR of 2.7 g/10min or higher as measured at 230°C under a load of 2.16 kg, comprising a composition which contains 5-95 parts by weight of (A) an isotactic polypropylene, 95-5 parts by weight of (B) a propylene/ethylene random copolymer, and 0-40 parts by weight of (C) an ethylene/propylene random copolymer, wherein 100 parts by weight of the composition is graft modified with 0.001-5 parts by weight of an unsaturated carboxylic acid and/or a derivative thereof, and wherein (B) is characterized by the following (i) to (iii): (i) the propylene/ethylene random copolymer (B) contains 60-90 mol% units derived from propylene and 10-40 mol% units derived from ethylene; (ii) the melting point (Tm) as measured with a differential scanning calorimeter is in the range of 40-120°C; and (iii) the molecular weight distribution (Mw/Mn) as determined by gel permeation chromatography (GPC) is in the range of 1.0-3.0.

    Laminate structure
    7.
    发明专利
    Laminate structure 有权
    层压结构

    公开(公告)号：JP2008001099A

    公开(公告)日：2008-01-10

    申请号：JP2007139267

    申请日：2007-05-25

    Applicant: Mitsui Chemicals Inc ,  三井化学株式会社

    Inventor： ONOGI TAKAYUKI ,  KANEKO HIDEYUKI ,  MATSUKI TOMOAKI ,  SUZUKI KOTARO ,  OTA SEIJI ,  YASUI SHIGEYUKI ,  ISOGAWA SORO

    IPC: B32B27/32 ,  B32B27/00

    Abstract: PROBLEM TO BE SOLVED: To provide a laminate structure body having a laminate structure at least as a part of it, the laminate structure obtained by strongly bonding a layer containing an olefin-based polymer as a major constituent to at least one layer of a material selected from a polar vinyl-based plastic, an engineering plastic, an organism-based polymer, a thermoplastic elastomer and the like via a hot-melt type adhesion layer containing a specific hybrid polymer. SOLUTION: The laminate structure body has a structure at least as a part of it, wherein the structure comprises a layer (A) containing the olefin-based polymer as a major constituent, a layer (B) containing the hybrid polymer [P]composed of a polyolefin segment [S 1 ] and a polar polymer segment [S 2 ], and at least one layer (C) of a material selected from the polarvinyl-based plastic, an aromatic vinyl-based polymer, a polyester, a polyamide, a polycarbonate, the engineering plastic, the organism-based polymer and the like, and the layer A, the layer B and the layer C being laminated in this order. COPYRIGHT: (C)2008,JPO&INPIT

    Abstract translation: 要解决的问题：为了提供至少一部分具有层叠结构的层压结构体，将通过将含有烯烃类聚合物作为主要成分的层强力结合至至少一层而获得的层叠结构 选自极性乙烯基类塑料，工程塑料，生物体聚合物，热塑性弹性体等的材料，通过含有特定的杂化聚合物的热熔型粘合层。 解决方案：层压结构体至少具有其结构，其中该结构包括含有烯烃类聚合物作为主要成分的层（A），含有杂化聚合物的层（B）[ P]由聚烯烃链段[S 1]和极性聚合物链段[S 2]组成，以及至少一层选自极性乙烯基 基于树脂的塑料，芳香族乙烯基类聚合物，聚酯，聚酰胺，聚碳酸酯，工程塑料，生物体聚合物等，层A，层B和层C依次层叠 。 版权所有（C）2008，JPO＆INPIT

    Propylene-based adhesive polymer composition and laminate thereof
    8.
    发明专利
    Propylene-based adhesive polymer composition and laminate thereof 有权
    丙烯基胶粘聚合物组合物及其层压材料

    公开(公告)号：JP2005263997A

    公开(公告)日：2005-09-29

    申请号：JP2004079280

    申请日：2004-03-18

    Applicant: Mitsui Chemicals Inc ,  三井化学株式会社

    Inventor： YASUI SHIGEYUKI ,  OTA SEIJI

    IPC: B32B27/32 ,  C08F210/16 ,  C08K5/09 ,  C08L23/10 ,  C09J123/14 ,  C09J151/06 ,  C09J157/02 ,  C09J165/00 ,  C09J193/04

    Abstract: PROBLEM TO BE SOLVED: To provide a polypropylene-based adhesive resin composition suppressed in adhesive force decline even in a high-temperature atmosphere while having moderate flexibility needed as an adhesive, and to provide a laminate comprising the resin composition and high in interlaminar adhesive force in a high-temperature atmosphere. SOLUTION: The propylene-based adhesive polymer composition(C) comprises 1-39 pt(s). wt. of an isotactic polypropylene(A) and 99-61 pts. wt. of a propylene-ethylene-α-olefin random copolymer(B), wherein the molar ratio(propylene/(ethylene+α-olefin)) is (45:55) to (90:10). The laminate has at least one layer of the above resin composition. COPYRIGHT: (C)2005,JPO&NCIPI

    Abstract translation: 待解决的问题：为了提供即使在高温气氛中也抑制粘合力下降的聚丙烯类粘合剂树脂组合物，同时具有作为粘合剂所需的适度的柔性，并且提供包含该树脂组合物的高分子 在高温环境下的层间粘合力。 解决方案：丙烯类粘合剂聚合物组合物（C）包含1-39pt（s）。 重量。 的全同立构聚丙烯（A）和99-61点。 重量。 的丙烯 - 乙烯-α-烯烃无规共聚物（B），其中丙烯/（乙烯+α-烯烃）的摩尔比为（45:55）〜（90:10）。 层压体具有至少一层上述树脂组合物。 版权所有（C）2005，JPO＆NCIPI

    Modified polyolefin composition and laminate using the same
    9.
    发明专利
    Modified polyolefin composition and laminate using the same 有权

    公开(公告)号：JP2004269688A

    公开(公告)日：2004-09-30

    申请号：JP2003062377

    申请日：2003-03-07

    Applicant: Mitsui Chemicals Inc ,  三井化学株式会社

    Inventor： YASUI SHIGEYUKI ,  OGA AKIHITO

    IPC: C08L23/10 ,  C08L45/00 ,  C08L51/06 ,  C08L57/00 ,  C09J123/08 ,  C09J123/10 ,  C09J151/06

    Abstract: PROBLEM TO BE SOLVED: To provide a modified polyolefin composition for bonding having a high interlayer bonding strength especially in a high temperature atmosphere, and a laminate using the same.
    SOLUTION: The modified polyolefin composition for bonding includes (A) a propylene polymer, (B) a tackifier, (C) a graft-modified modified propylene polymer, (D) a high pressure low density polyethylene and (E) an amorphous or a low crystalline ethylene-α-olefin random copolymer in a specified ratio. All or a part of the component (E) may be graft-modified. The layer consisting of the modified polyolefin composition is laminated with at least one side of the base material layer in the laminated structure. Preferably, the base material is covered with a vapor-deposited layer of an inorganic substance such as aluminum oxide.
    COPYRIGHT: (C)2004,JPO&NCIPI

    MODIFIED POLYPROPYLENE COMPOSITION AND LAMINATE USING THE COMPOSITION
    10.
    发明专利
    MODIFIED POLYPROPYLENE COMPOSITION AND LAMINATE USING THE COMPOSITION 失效

    公开(公告)号：JP2001261905A

    公开(公告)日：2001-09-26

    申请号：JP2000083263

    申请日：2000-03-21

    Applicant: MITSUI CHEMICALS INC

    Inventor： YASUI SHIGEYUKI ,  SAWADA YUJI ,  KAWACHI HIDESHI

    IPC: B32B27/32 ,  C08L23/16 ,  C08L23/26 ,  C08L25/04 ,  C08L51/06 ,  C09J151/06

    Abstract: PROBLEM TO BE SOLVED: To obtain a modified propylene composition capable of presenting a laminate excellent in interlayer adhesiveness and capable of preventing reduction of an interlayer adhesive strength even when heat-treated at temperatures of 80-125 deg.C by using the composition as a laminate-forming composition or an adhesive resin composition. SOLUTION: This modified polypropylene composition comprises (A) a modified polypropylene a part or the whole of which is modified by grafting an unsaturated carboxylic acid or its derivative, (B) an amorphous or low crystalline ethylene/α-olefin copolymer having a specific MFR and density and (C) a styrene-based elastomer in a specific ratio. The component (A) is a graft a modified product of a homopolymer of propylene and/or a graft modified product of a propylene/α-olefin random copolymer. This laminate consists of a composition layer comprising the aforesaid composition and a resin layer or resin layers laminated on one side or both sides of the composition layer.

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