3.
    发明专利
    未知

    公开(公告)号:AT503816T

    公开(公告)日:2011-04-15

    申请号:AT07707333

    申请日:2007-01-24

    Abstract: An object of the present invention is to provide polypropylene adhesive excellent in both initial adhesion and adhesion after heat history; and a laminate excellent in adhesion and heat resistance. Provided is a polypropylene-based adhesive having an MFR of 2.7 g/10min or higher as measured at 230°C under a load of 2.16 kg, comprising a composition which contains 5-95 parts by weight of (A) an isotactic polypropylene, 95-5 parts by weight of (B) a propylene/ethylene random copolymer, and 0-40 parts by weight of (C) an ethylene/propylene random copolymer, wherein 100 parts by weight of the composition is graft modified with 0.001-5 parts by weight of an unsaturated carboxylic acid and/or a derivative thereof, and wherein (B) is characterized by the following (i) to (iii): (i) the propylene/ethylene random copolymer (B) contains 60-90 mol% units derived from propylene and 10-40 mol% units derived from ethylene; (ii) the melting point (Tm) as measured with a differential scanning calorimeter is in the range of 40-120°C; and (iii) the molecular weight distribution (Mw/Mn) as determined by gel permeation chromatography (GPC) is in the range of 1.0-3.0.

    4.
    发明专利
    未知

    公开(公告)号:DE60141777D1

    公开(公告)日:2010-05-20

    申请号:DE60141777

    申请日:2001-09-07

    Abstract: The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit represented by the following formula (1) and a constituent unit represented by the following formula (4), and optionally a constituent unit represented by the following formula (5), having a molecular weight distribution (Mw/Mn) of not more than 3, and having an intensity ratio of T±² to T±± (T±²/T±±), as determined from a 13 C-NMR spectrum of said copolymer, of not more than 1.0: wherein R 1 is a hydrogen atom or a straight-chain or branched aliphatic hydrocarbon group of 1 to 18 carbon atoms; R 5 is a hydrocarbon group; R 6 is a hetero atom or a group containing a hetero atom; r is 0 or 1; Z is a polymer segment obtained by any one of anionic polymerization, ring-opening polymerization and polycondensation; W is a hydroxyl group or an epoxy group; p is an integer of 1 to 3, q is 0, 1 or 2, and p+q ‰ 3; when p is 2 or 3, each -O-Z may be the same or different, and in this case, if r is 0, -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, -O-Z may be bonded to the same or different atom of R 6 ; when q is 2, each W may be the same or different, and in this case, if r is 0, W may be bonded to the same or different atom of R 5 , and if r is 1, W may be bonded to the same or different atom of R 6 ; in case of p‰¥1 and q‰¥1, if r is 0, W and -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, W and -O-Z may be bonded to the same or different atom of R 6 ; m is 0 or 1; n is an integer of 1 to 3; and when n is 2 or 3, each W may be the same or different, and in this case, if m is 0, W may be bonded to the same or different atom of R 6 , and if m is 1, W may be bonded to the same or different atom of R 7 . The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

    8.
    发明专利
    未知

    公开(公告)号:DE60124829D1

    公开(公告)日:2007-01-11

    申请号:DE60124829

    申请日:2001-09-07

    Abstract: The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit represented by the following formula (1) and a constituent unit represented by the following formula (4), and optionally a constituent unit represented by the following formula (5), having a molecular weight distribution (Mw/Mn) of not more than 3, and having an intensity ratio of T±² to T±± (T±²/T±±), as determined from a 13 C-NMR spectrum of said copolymer, of not more than 1.0: wherein R 1 is a hydrogen atom or a straight-chain or branched aliphatic hydrocarbon group of 1 to 18 carbon atoms; R 5 is a hydrocarbon group; R 6 is a hetero atom or a group containing a hetero atom; r is 0 or 1; Z is a polymer segment obtained by any one of anionic polymerization, ring-opening polymerization and polycondensation; W is a hydroxyl group or an epoxy group; p is an integer of 1 to 3, q is 0, 1 or 2, and p+q ‰ 3; when p is 2 or 3, each -O-Z may be the same or different, and in this case, if r is 0, -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, -O-Z may be bonded to the same or different atom of R 6 ; when q is 2, each W may be the same or different, and in this case, if r is 0, W may be bonded to the same or different atom of R 5 , and if r is 1, W may be bonded to the same or different atom of R 6 ; in case of p‰¥1 and q‰¥1, if r is 0, W and -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, W and -O-Z may be bonded to the same or different atom of R 6 ; m is 0 or 1; n is an integer of 1 to 3; and when n is 2 or 3, each W may be the same or different, and in this case, if m is 0, W may be bonded to the same or different atom of R 6 , and if m is 1, W may be bonded to the same or different atom of R 7 . The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

    POLAR GROUP-CONTAINING OLEFIN COPOLYMER, PROCESS FOR PREPARING THE SAME, THERMOPLATIC RESIN COMPOSITION CONTAINING THE COPOLYMER, AND USES THEREOF

    公开(公告)号:SG102636A1

    公开(公告)日:2004-03-26

    申请号:SG200105472

    申请日:2001-09-07

    Abstract: The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit represented by the following formula (1) and a constituent unit represented by the following formula (4), and optionally a constituent unit represented by the following formula (5), having a molecular weight distribution (Mw/Mn) of not more than 3, and having an intensity ratio of T±² to T±± (T±²/T±±), as determined from a 13 C-NMR spectrum of said copolymer, of not more than 1.0: wherein R 1 is a hydrogen atom or a straight-chain or branched aliphatic hydrocarbon group of 1 to 18 carbon atoms; R 5 is a hydrocarbon group; R 6 is a hetero atom or a group containing a hetero atom; r is 0 or 1; Z is a polymer segment obtained by any one of anionic polymerization, ring-opening polymerization and polycondensation; W is a hydroxyl group or an epoxy group; p is an integer of 1 to 3, q is 0, 1 or 2, and p+q ‰ 3; when p is 2 or 3, each -O-Z may be the same or different, and in this case, if r is 0, -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, -O-Z may be bonded to the same or different atom of R 6 ; when q is 2, each W may be the same or different, and in this case, if r is 0, W may be bonded to the same or different atom of R 5 , and if r is 1, W may be bonded to the same or different atom of R 6 ; in case of p‰¥1 and q‰¥1, if r is 0, W and -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, W and -O-Z may be bonded to the same or different atom of R 6 ; m is 0 or 1; n is an integer of 1 to 3; and when n is 2 or 3, each W may be the same or different, and in this case, if m is 0, W may be bonded to the same or different atom of R 6 , and if m is 1, W may be bonded to the same or different atom of R 7 . The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

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