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    PRODUCTION OF NORBORNENE COMPOUND HAVING CHAIN POLYENE GROUP
    2.
    发明专利
    PRODUCTION OF NORBORNENE COMPOUND HAVING CHAIN POLYENE GROUP 失效

    公开(公告)号：JPH08133993A

    公开(公告)日：1996-05-28

    申请号：JP27537594

    申请日：1994-11-09

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： ISHIDA TATSUKAZU ,  YASUDA MASAAKI ,  ONISHI HITOSHI ,  KIHARA NORIAKI

    IPC: B01J31/14 ,  B01J31/24 ,  C07B61/00 ,  C07C2/04 ,  C07C13/42

    Abstract: PURPOSE: To obtain the subject compound, excellent in weather and heat resistances, etc., and capable of providing an unsaturated α-olefin-polyene copolymer having a high vulcanization rate by reacting a vinylnorbornene compound with a conjugated diene compound in the presence of a catalyst. CONSTITUTION: A vinylnorbornene compound of formula I (R and R are each H or a 1-5C alkyl) (preferably 5-vinylnorbornene, etc.) is reacted with a conjugated diene compound of formula II (R and R are each H or a 1-5C alkyl; R is H or a 1-4C alkyl, with the proviso that R and R are not simultaneously H) (e.g. isoprene) in the presence of a catalyst to afford the objective compound of formula III. Furthermore, a catalyst comprising a transition metallic complex in which an organic ligand is coordinated with Co chloride and triethylaluminum is preferred as the catalyst. 9146/28}1,2-Bis(diphenylphosphino)ethane]cobalt (II) chloride, etc., are preferred as the transition metallic complex. The reaction is preferably carried out at 70-150 deg.C under 10-70kg/cm ethylene pressure.

    HERBICIDAL COMPOSITION
    3.
    发明专利
    HERBICIDAL COMPOSITION 失效

    公开(公告)号：JPH06135806A

    公开(公告)日：1994-05-17

    申请号：JP29014692

    申请日：1992-10-28

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： TAKEMATSU TETSUO ,  ISHIDA TATSUKAZU ,  HAMADA NAOSHI ,  ISHITOKU TAKESHI ,  MATSUYOSHI TORU

    IPC: A01N47/30 ,  A01N37/34

    Abstract: PURPOSE:To obtain a herbicidal composition having excellent herbicidal activity against various weeds in a small amount of the chemical and high safety with hardly any phytotoxicity to useful crops. CONSTITUTION:This herbicidal composition comprises (A) a urea compound of formula I [Ar is formula II (R to R are H, lower alkyl or lower alkoxyl; R is further OH, with the proviso that R and R or R and R may be linked or, together with C to which they are bound, may form an alkylene chain forming a 4- to a 6-membered ring or R and R may be linked to denote ethylendioxy; R and R may be linked to denote dichloromethylene); A is CX (X is H, Cl, NO2 or CF3); B is H, methyl or methoxy] and (B) 3,5-dibromo-4- hydroxybenzonitrile of formula III or its salt or ester as active ingredients. Furthermore, a spreading agent containing a nonionic or an anionic surfactant can be added to provide the herbicidal composition better in herbicidal effects and stability.

    METHOD FOR CONTROLLING INJURIOUS WEED
    4.
    发明专利
    METHOD FOR CONTROLLING INJURIOUS WEED 失效

    公开(公告)号：JPH03161405A

    公开(公告)日：1991-07-11

    申请号：JP29752089

    申请日：1989-11-17

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： HATA EIICHIRO ,  ITO FUMI ,  TAKAHASHI KATSUYA ,  MATSUYOSHI TORU ,  ISHIDA TATSUKAZU

    IPC: A01N47/30 ,  A01N47/36

    Abstract: PURPOSE:To control weeds without substantially chemically injuring crops by applying an aqueous dispersion or aqueous emulsion to injurious weeds, the aqueous dispersion or aqueous emulsion being prepared by adding an oil, a surfactant, a solvent, etc., to a water-diluted solution of a herbicide composition containing a specific urea derivative compound. CONSTITUTION:When applies, a herbicide composition containing a compound of formula I [Ar is group of formula II (R , R are H, lower alkyl or lower alkoxy, or both may be combined to each other to form a ring), etc.; A is N or -CX=(X is H, Cl, NO2 or CF2); R is H, CH3 or OCH3] is deluted with water, and the diluted solution is mixed with an oil (e.g. a vegetable oil, animal oil or paraffic oil), a surfactant (nonionic, cationic, anionic or amphoteric), a solvent (e.g. methanol, acetone or toluene) to prepare an aqueous dispersion or aqueous emulsion, which is applied to injurious weeds. The treatment reduces the chemical injury of cross caused by the compound of formula I and reinforces the herbicidal activity thereof.

    PREPARATION OF PYRIDOPYRIMIDINE DERIVATIVE TRIHYDRATE
    7.
    发明专利
    PREPARATION OF PYRIDOPYRIMIDINE DERIVATIVE TRIHYDRATE 失效

    公开(公告)号：JPS5835187A

    公开(公告)日：1983-03-01

    申请号：JP13281081

    申请日：1981-08-26

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： KIHARA NORIAKI ,  ISHIDA TATSUKAZU ,  TAKAHASHI SHIGERU ,  ISAYAMA SHIGERU

    IPC: C07D471/04

    Abstract: PURPOSE:To obtain the titled purified trihydrate useful as an antimicrobial agent, by drying raw pyridopyrimidine derivative trihydrate under a condition to eliminate water of crystallization to give an anhydrous pyridopyrimidine derivative, exposing it to enforced flow of humid gas. CONSTITUTION:Raw 2-(1-piperazinyl)-8-ethyl-5,8-dihydro-5-oxopyrido [2,3-d] pyrimidine-6-carboxylic acid trihydrate (compound A for short) is recrystallized from dimethylformamide to give crystal, which is dried under a condition (preferably at 100-180 deg.C) wherein the water of crystallization of the crystal is at least eliminated in order to remove dimethylformamide completely, to give anhydrous compound A or a mixture of it and the compound A. The anhydrous compound A or the mixture of it and the compound A is exposed to the forced flow of a humid gas containing steam at saturated or lower vapor pressure at

    NORBORNENE COMPOUND HAVING BRANCHED CHAINLIKE POLYENE GROUP AND ITS PRODUCTION
    8.
    发明专利
    NORBORNENE COMPOUND HAVING BRANCHED CHAINLIKE POLYENE GROUP AND ITS PRODUCTION 失效

    公开(公告)号：JPH107601A

    公开(公告)日：1998-01-13

    申请号：JP16158296

    申请日：1996-06-21

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： ISHIDA TATSUKAZU ,  YASUDA MASAAKI ,  MAEDA KEN ,  TSUTSUI TOSHIYUKI

    IPC: C07C2/50 ,  C07C13/43 ,  C08F36/04 ,  C08F36/20

    Abstract: PROBLEM TO BE SOLVED: To produce the subject new compound capable of providing an unsaturated ethylenic copolymer rubber, excellent in weather, heat and ozone resistances and having a high vulcanization rate when copolymerized with an α-olefin. SOLUTION: This compound is represented by formula I (R is H or a 1-3C alkyl; R and R are each a 1-3C alkyl), e.g. 5-[1'-(1''-methyl-1''-propenyl)]-4'- methyl-3'-pentenyl]-2-norbornene. The compound represented by formula I is obtained by reacting a compound represented by formula II with ethylene in the presence of a catalyst comprising a transition metallic compound and an organoaluminum compound, providing a compound represented by formula III and then carrying out the Diels-Alder reaction of the resultant compound represented by formula III with cyclopentadiene.

    PRODUCTION OF BRANCHED-CHAIN POLYENE COMPOUND
    9.
    发明专利
    PRODUCTION OF BRANCHED-CHAIN POLYENE COMPOUND 失效

    公开(公告)号：JPH09124519A

    公开(公告)日：1997-05-13

    申请号：JP28840495

    申请日：1995-11-07

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： MAEDA KEN ,  OYOSHI HAJIME ,  ISHIDA TATSUKAZU ,  KIHARA NORIAKI

    IPC: B01J27/13 ,  C07B61/00 ,  C07C2/22 ,  C07C2/38 ,  C07C11/21

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject new compound copolymerizable with an α-olefin to give an unsaturated ethylenic copolymer having excellent weather resistance and heat-resistance and high vulcanization rate by reacting ethylene with a specific conjugated diene compound. SOLUTION: The objective compound of the formula III is produced by reacting ethylene with a conjugated diene of the formula I [(f) is 1-5; R and R are each H or a 1-5C alkyl; R is H, an alkenyl of the formula II (R to R are each H or a 1-5C alkyl; (n) is 1-5; R to R are not H at the same time), etc.; R to R are not H at the same time] in the presence of a transition metal compound (preferably rhodium chloride) preferably at 40-200 deg.C under an ethylene pressure of 5-100kg/cm . The reaction is usually performed preferably in the presence of a 1-5C alcohol. A preferable example of the compound of the formula I is 7-methyl-3-methylene-1,6-octadiene and, in this case, 4-ethylidene-8- methyl-1,7-nonadiene is obtained as the objective compound.

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