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公开(公告)号:JPH101575A
公开(公告)日:1998-01-06
申请号:JP15722996
申请日:1996-06-18
Applicant: MITSUI PETROCHEMICAL IND , OKURA INDUSTRIAL CO LTD
Inventor: KASHIWA HIDENORI , KOBAYASHI TOSHIO , FUJIMOTO SHIYUUEI , MATSUDA HIDEAKI , UEDA MINORU , MATSUMOTO HIROSHI
Abstract: PROBLEM TO BE SOLVED: To obtain an polyolefin resin composite material excellent in fabricability and mechanical strengths at a low cost from a resin composition containing a woody material. SOLUTION: This composite material is produced by reacting a composition comprising 30-90 pts.wt. polyolefin (A), 70-10 pts.wt. (the total of components A and B being 100 pts.wt.)lignocellulosic or cellulosic substance (B), 0.1-5 pts.wt. crosslinking agent (C), 0.01-1 pt.wt. orgnaic peroxide (D), and either 0.1-10 pts.wt. modified polyolefin having a degree of modification of 0.1-20wt.% or 1-20 pts.wt. polybasic acid anhydride (E) (the amounts of components C to E being based on 100 pts.wt. total of components A and B) by kneading under heating for 30sec to 30min at 150-200 deg.C.
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公开(公告)号:JPH06241919A
公开(公告)日:1994-09-02
申请号:JP2880693
申请日:1993-02-18
Applicant: MITSUI PETROCHEMICAL IND
Inventor: KASHIWA HIDENORI , NIIMI KOJI
IPC: G01L1/00
Abstract: PURPOSE:To enable non-destructive measurement for residual stress or strain of a plastic moulded bottle, and conduct smoothly the successive measurements of the bottle on various physical properties without changing its internal stress or strain for the measurement. CONSTITUTION:A deflecting plate and an illuminating device 4 are fixed in the inside of a table on which a bottle 1 is placed, and an optical fiber scope 15 is inserted into the bottle 1 from the mouth. An image which is sensed by the scope 15 and picked up by a CCD camera 17 through a deflecting plate 16 placed in the outside of the bottle is sent to an image processor 10 for binarization and noise-processing and displayed on a monitor 11, so that the internal stress and strain can be measured by observing the patterns of interference fringe.
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公开(公告)号:JPH0338253A
公开(公告)日:1991-02-19
申请号:JP22969689
申请日:1989-09-05
Applicant: MITSUI PETROCHEMICAL IND
Inventor: TAKAHATA KAZUNORI , KASHIWA HIDENORI , TANIGUCHI KATSUO
IPC: B01J31/26 , B01J31/38 , C07C45/46 , C07C49/83 , C07C201/08 , C07C205/06 , C07C317/14
Abstract: PURPOSE:To obtain a fluorine contg. aromatic sulfonic acid catalyst excellent in water repellency and highly active even in the presence of water by bonding a substituted aryl group in a specific structure to the matrix of an inorg. substrate. CONSTITUTION:An aryl group with fluorine and sulfonic acid group introduced thereinto is bonded to the matrix of an inorg. substrate such as zirconium compound, mica and montomorillonite, thereby obtaining on the matrix the fluorine contg. aromatic sulfonic acid catalyst linked with a substituted aryl group of the general formula I (wherein X is F or fluorine contg. 1-14C alkyl group which may contain ether oxygen atoms, Ar is aryl group, (n) is an integer of 1-5 and (m) is an integer of 1-3). This catalyst is highly active against acid catalytic reaction such as esterification and Fries rearrangement and capable of maintaining its high activity even in the presence of water.
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公开(公告)号:JPH101576A
公开(公告)日:1998-01-06
申请号:JP15723096
申请日:1996-06-18
Applicant: MITSUI PETROCHEMICAL IND , OKURA INDUSTRIAL CO LTD
Inventor: KASHIWA HIDENORI , KOBAYASHI TOSHIO , FUJIMOTO SHIYUUEI , MATSUDA HIDEAKI , UEDA MINORU , MATSUMOTO HIROSHI
Abstract: PROBLEM TO BE SOLVED: To obtain a polyolefin resin composite material excellent in fabricability and mechanical strengths at a low cost from a resin composition containing a woody material. SOLUTION: This composite material is produced by reacting a composition comprising 30-90 pts.wt. polyolefin (A), 70-10 pts.wt. (the total of components A and B being 100 pts.wt.) lignocellulosic or cellulosic substance (B) having a polymerizable double bond, 0.1-5 pts.wt. crosslinking agent (C) and 0.01-1 pt.wt. organic peroxide (D) (the amounts of components C and D being based on 100 pts.wt. total of components A and B) by kneading under heating for 30sec to 30min at 150-200 deg.C.
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公开(公告)号:JPH0782408A
公开(公告)日:1995-03-28
申请号:JP23053093
申请日:1993-09-16
Applicant: MITSUI PETROCHEMICAL IND
Inventor: KASHIWA HIDENORI , NIIMI KOJI
Abstract: PURPOSE:To quickly remove an adsorbed material from a polyester bottle to enable the reuse of the bottle by contacting a polyester bottle having a bottle body part having a specific average crystallinity with water, steam, etc., at a specific temperature, thereby desorbing the material adsorbed on the bottle. CONSTITUTION:A polyester resin (e.g. polyethylene terephthalate) is molded by an injection molding machine. The formed preform is heated to the surface temperature of 90-100 deg.C at the middle of the preform body part and formed by a drawing blow molding with a molding machine to obtain a polyester bottle 1 having an average crystallinity of 32-70% at the body part 4 of the bottle. Methanol (or p-xylene) is poured into the bottle 1, left standing at 25 deg.C for 7 days and discharged from the bottle. The bottle is washed with distilled water of 20 deg.C and dried to effect the adsorption of methanol (or p-xylene) to the bottle and the bottle 1 is brought into contact with water or steam of 40-150 deg.C to quickly desorb and remove the material adsorbed on the polyester bottle 1.
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公开(公告)号:JPH06286717A
公开(公告)日:1994-10-11
申请号:JP6974293
申请日:1993-03-29
Applicant: MITSUI PETROCHEMICAL IND
Inventor: MORIWAKI TSUTOMU , KASHIWA HIDENORI , NIIMI KOJI
IPC: B65B17/02
Abstract: PURPOSE:To reduce the distribution cost at the time of storage or transport, etc., by reducing the volume of a container made of a synthetic resin under an empty condition smaller than the volume under a condition in which a content is filled. CONSTITUTION:A container 1 made of a synthetic resin consists of a mouth part 2 without flexibility which is formed in such a manner that a cap can be fastened on, body part 3 with flexibility which has a larger diameter than the mouth part 2 and has a low rigidity, and a bottom part 4 which has a higher rigidity and is thicker than the body part 3. When the container 1 made of a synthetic resin is under an empty condition, i.e., a content is not filled inside, the body part 3 with flexibility is narrowed wholly from the mouth part 2 to the bottom part 4, and the volume is reduced. At this time, the body part 3 extends in the lateral direction for the portion which is narrowed, and is deformed into a flat plate shape. Thus, the volume of the container 1 made of a synthetic resin under an empty condition is reduced from the volume under a filled condition, and the container 1 is carried or stored under this condition.
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公开(公告)号:JPH04266852A
公开(公告)日:1992-09-22
申请号:JP2719691
申请日:1991-02-21
Applicant: MITSUI PETROCHEMICAL IND
Inventor: KASHIWA HIDENORI , ISHIBASHI MASAYASU , TAKAHATA KAZUNORI
Abstract: PURPOSE:To provide an industrially advantageous recrystallization purification process to get phenyl p-hydroxybenzoate having high purity. CONSTITUTION:Phenyl p-hydroxybenzoate is dissolved in a 1-5C aliphatic alcohol (e.g. ethanol) and water is added to the solution to precipitate phenyl p- hydroxybenzoate.
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公开(公告)号:JPH02132124A
公开(公告)日:1990-05-21
申请号:JP17171489
申请日:1989-07-03
Applicant: MITSUI PETROCHEMICAL IND
Inventor: TAKAI TOSHIHIRO , KASHIWA HIDENORI , TANIGUCHI KATSUO , TAKAHATA KAZUNORI
IPC: B01J31/06 , B01J31/02 , B01J31/12 , B01J31/40 , C07C45/45 , C07C45/46 , C07C49/83 , C07C67/08 , C07C201/06 , C07C201/08 , C07C205/06 , C08G77/38 , C08G77/392
Abstract: PURPOSE:To obtain the title compound excellent in water repellency and usable as an acid catalyst of easy catalyst separation giving high acid catalyst activity even in the presence of water by fluorination and sulfonation of polyphenylsiloxane. CONSTITUTION:The objective fluorine-contg. sulfonated polyphenylsiloxane catalyst made up of recurring unit of the formula [X is fluorine atom or (ether oxygen atom-contg.) 2-14C fluorine-contg. alkyl; n is integer: 1-5; m is integer: 1-3] can be obtained by fluorination and sulfonation of polyphenylsiloxane. Alternatively, the objective compound can be obtained either by sulfonation of a fluorine-contg. polyphenylsiloxane using a sulfonating agent or by fluorination of a sulfonic acid-introduced polyphenylsiloxane using a fluorine- contg. compound.
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公开(公告)号:JPH08244099A
公开(公告)日:1996-09-24
申请号:JP5011495
申请日:1995-03-09
Applicant: MITSUI PETROCHEMICAL IND
Inventor: KASHIWA HIDENORI , HATA ISAO , TSUGAWA MICHIO , HATAHO SUSUMU , NAKAMACHI KOJI
IPC: B65D1/00 , B29C49/08 , B29C49/64 , B29K67/00 , B29L22/00 , B65D1/09 , C08J5/00 , C08L67/00 , C08L67/02 , C08L93/00 , C08L93/04
Abstract: PURPOSE: To avoid deformation of a bottle even when a heated drink is filled by preparing the bottle of a polyester compsn. formed of a polyester and rosins or their derivatives. CONSTITUTION: A bottle 1 with a crystallinity at the center of the bottle trunk part of 25-60% prepd. of a polyester compsn. is prepd. by performing draw blow molding of a preform consisting of 95-99.99wt.% polyester and 0.01-5wt.% rosins or their derivatives in a mold. The draw ratio when this draw blow molding is performed is 6 to 15-fold in terms of area draw ratio. In addition, the crystallinity of the mouth and neck part 2 of this bottle 1 is made in the range of 25-60% and the crystallinity of the bottom part is made in the range of 0-60%. The bottle 1 prepd. thus exhibits excellent heat-resistant characteristics and transparency and can be easily reused to a bottle by melting it after use.
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公开(公告)号:JPH08164555A
公开(公告)日:1996-06-25
申请号:JP30930894
申请日:1994-12-13
Applicant: MITSUI PETROCHEMICAL IND
Inventor: KASHIWA HIDENORI , NAKAMACHI KOJI , HATA ISAO , HATAHO SUSUMU , TSUGAWA MICHIO
Abstract: PURPOSE: To obtain an autonomous bottle which can be reused by a method wherein a bottle is filled with a carbon dioxide-containing beverage having a specified volume at a specified temperature, changes of a bottle height and a barrel diameter at a specified temperature before and after warm bath test in a sealed state are set to below specified percentages and an inversion angle after the test is set to above a specified angle. CONSTITUTION: When a saturated polyester bottle is filled with a carbon dioxide beverage of 2.5 gas volume at 23 deg.C and tested by warm bath test being dipped in a warm bath of 70 deg.C in a sealed state for an hour, the following condition is to be satisfied. That is, a changing rate of dimension of the bottle filled with the carbon dioxide beverage in the direction of height before and after the warm bath test is 5% or below and a changing rate of dimension in the direction of barrel diameter is 5% or below. An inversion angle of the bottle after the warm bath test is 10 deg. or above. The crystallization degree of this saturated polyester bottle is 25-60% at the neck (mouth, mouth cock) and 25-60% at the barrel center, and preferably 25-60% at the central part of the bottom.
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