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公开(公告)号:EP0646624A4
公开(公告)日:1996-03-20
申请号:EP94904013
申请日:1994-01-11
Applicant: MITSUI PETROCHEMICAL IND
Inventor: HASHIMOTO MIKIO , UEDA TAKASI , KAWASAKI MASAAKI , MORIYA SATORU , MIZUNO AKIRA , FUKUOKA DAISUKE , IMUTA JUNICHI , HIROSE KEIJI , SAITO JUNJI , KISO YOSHIHISA
CPC classification number: C08L23/12 , C08L23/0815 , C08L23/10 , C08L23/142 , C08L23/16 , C08L2205/02 , C08L2314/06 , C08L2666/04
Abstract: A propylene polymer composition composed of a propylene polymer (A1) produced by using a metallocene catalyst and having a melt flow rate (MFR) of 0.01-30 g/10 min, a propylene polymer (A2) having an MFR of 30-1,000 g/10 min and, if necessary, a flexible polymer, wherein the ratio of the MFR of the polymer (A2) to that of the polymer (A1) is at least 30. A propylene polymer composition composed of a propylene polymer produced by using a titanium catalyst and having an MFR of 0.01-30 g/10 min, the above polymer (A2) and, if necessary, a flexible polymer. A propylene polymer composition composed of a propylene polymer produced by using a titanium catalyst and having an MFR of 0.01-50 g/10 min and an ethylene-olefin random copolymer produced by using a metallocene catalyst. A propylene polymer composition composed of a propylene polymer produced by using a catalyst containing a specified metallocene compound and at least one synthetic resin selected from among a propylene polymer other than the above propylene polymer, an olefin elastomer and an olefin polymer. All of the above polymer compositions are excellent in heat resistance, mechanical strengths and tensile elongation at break and are suitable for producing various structural materials of automobiles, household electric appliances, etc., daily necessities, films, sheets, and so forth.
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公开(公告)号:AT133984T
公开(公告)日:1996-02-15
申请号:AT88908752
申请日:1988-10-07
Applicant: MITSUI PETROCHEMICAL IND
Inventor: MORIYA SATORU , ISHIMOTO AKIO , AKANA YOSHINORI , YAMAMOTO YOZO , KISHIMURA KOTARO , CHOME , IKEJIRI FUMITOSHI
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公开(公告)号:DE69017964T2
公开(公告)日:1995-08-24
申请号:DE69017964
申请日:1990-07-18
Applicant: MITSUI PETROCHEMICAL IND
Inventor: MORIYA SATORU , TAKAHASHI MAMORU , ISHIMOTO AKIO , HIROSE TOSHIYUKI
Abstract: A polyolefin resin composition comprising (A) a polyolefin resin, (B) a graft-modified alpha -olefin copolymer grafted with an unsaturated carboxylic acid and its derivative, and(C) an amino group-containing compound,(D) said polyolefin resin composition containing a crosslinked structure between the amino group-containing compound (C) and the graft-modified alpha -olefin copolymer (B), and containing, based on 100 parts by weight of the polyolefin resin (A) and the graft-modified alpha -olefin copolymer (B) in total, 1 to 99 parts by weight of each of the polyolefin resin (A) and the graft-modified alpha -olefin copolymer (B) and 0.01 to 10 parts by weight of the amino group-containing compound (C). The polyolefin resin composition gives a crosslinked molded article havig impact resistance at ordinary temperature and a low temperature.
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公开(公告)号:DE69017964D1
公开(公告)日:1995-04-27
申请号:DE69017964
申请日:1990-07-18
Applicant: MITSUI PETROCHEMICAL IND
Inventor: MORIYA SATORU , TAKAHASHI MAMORU , ISHIMOTO AKIO , HIROSE TOSHIYUKI
Abstract: A polyolefin resin composition comprising (A) a polyolefin resin, (B) a graft-modified alpha -olefin copolymer grafted with an unsaturated carboxylic acid and its derivative, and(C) an amino group-containing compound,(D) said polyolefin resin composition containing a crosslinked structure between the amino group-containing compound (C) and the graft-modified alpha -olefin copolymer (B), and containing, based on 100 parts by weight of the polyolefin resin (A) and the graft-modified alpha -olefin copolymer (B) in total, 1 to 99 parts by weight of each of the polyolefin resin (A) and the graft-modified alpha -olefin copolymer (B) and 0.01 to 10 parts by weight of the amino group-containing compound (C). The polyolefin resin composition gives a crosslinked molded article havig impact resistance at ordinary temperature and a low temperature.
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公开(公告)号:CA1329437C
公开(公告)日:1994-05-10
申请号:CA586482
申请日:1988-12-20
Applicant: MITSUI PETROCHEMICAL IND
Inventor: MORIYA SATORU , ISHIMOTO AKIO , AKANA YOSHINORI , YAMAMOTO YOHZO , KISHIMURA KOTAROH , IKEJIRI FUMITOSHI
Abstract: In accordance with the present invention, there are provided cycloolefin type random copolymer compositions excellent in heat resistance, chemical resistance, rigidity, impact resistance, etc., which comprise (A) a cycloolefin type random copolymer containing 40-85 mol% of an ethylene component and 60-15 mol% of a cycloolefin component represented by the following general formula ¢I! or ¢II! and having an intrinsic viscosity ¢?! of 0.05-10 dl/g as measured at 135.degree.C in decalin and a softening temperature (TMA) of not lower than 70.degree.C, and (B) one or more non-rigid copolymers selected from the group consisting of: (i) a cycloolefin type random copolymer containing an ethylene component, at least one other .alpha.-olefin component and a cycloolefin component and having an intrinsic viscosity ¢?! of 0.01-10 dl/g as measured at 135.degree.C in decalin and a softening temperature (TMA) of below 70.degree.C, (ii) a non-crystalline to low crystalline .alpha.-olefin type elastomeric copolymer formed from at least two .alpha.olefins having a crystallinity index as measured by X-ray diffractometry of 0-50%, (iii) an .alpha.-olefin-diene type elastomeric copolymer formed from at least two .alpha.-olefins and at least one nonconjugated diene, and (iv) an aromatic vinyl type hydrocarbon-conjugated diene copolymer or a hydrogenated product thereof, and optionally (C) an inorganic filler or organic filler: General formula ¢I! ¢II! wherein n and m are each 0 or a positive integer, ? is an integer of at least 3, and R1 to R10 each represents hydrogen atom, halogen atom or hydrocarbon group.
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公开(公告)号:SG49298A1
公开(公告)日:1998-05-18
申请号:SG1996008897
申请日:1989-09-28
Applicant: MITSUI PETROCHEMICAL IND
Inventor: MORIYA SATORU , YAMAMOTO YOHZOH
Abstract: A polymer composition comprising (A) 100 parts by weight of a cyclo-olefinic random copolymer comprising an ethylene component and a cyclo-olefin component and having an intrinsic viscossity [ eta ] of 0.05 to 10 dl/g, a glass transition temperature (tg) of 50 to 230 DEG C, and a softening point of at least 70 DEG C, (B) 5 to 150 parts by weight of at least one flexible polymer having a glass transition temperature of not more than 0 DEG C and (C) 0.004 to 1.0 part by weight of an organic peroxide and its reaction product.
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公开(公告)号:DE68927491T2
公开(公告)日:1997-03-27
申请号:DE68927491
申请日:1989-09-28
Applicant: MITSUI PETROCHEMICAL IND
Inventor: YAMAMOTO YOHZOH , MORIYA SATORU
Abstract: A polymer composition comprising (A) 100 parts by weight of a cyclo-olefinic random copolymer comprising an ethylene component and a cyclo-olefin component and having an intrinsic viscossity [ eta ] of 0.05 to 10 dl/g, a glass transition temperature (tg) of 50 to 230 DEG C, and a softening point of at least 70 DEG C, (B) 5 to 150 parts by weight of at least one flexible polymer having a glass transition temperature of not more than 0 DEG C and (C) 0.004 to 1.0 part by weight of an organic peroxide and its reaction product.
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公开(公告)号:DE68927491D1
公开(公告)日:1997-01-09
申请号:DE68927491
申请日:1989-09-28
Applicant: MITSUI PETROCHEMICAL IND
Inventor: YAMAMOTO YOHZOH , MORIYA SATORU
Abstract: A polymer composition comprising (A) 100 parts by weight of a cyclo-olefinic random copolymer comprising an ethylene component and a cyclo-olefin component and having an intrinsic viscossity [ eta ] of 0.05 to 10 dl/g, a glass transition temperature (tg) of 50 to 230 DEG C, and a softening point of at least 70 DEG C, (B) 5 to 150 parts by weight of at least one flexible polymer having a glass transition temperature of not more than 0 DEG C and (C) 0.004 to 1.0 part by weight of an organic peroxide and its reaction product.
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公开(公告)号:DE3854997D1
公开(公告)日:1996-03-21
申请号:DE3854997
申请日:1988-10-07
Applicant: MITSUI PETROCHEMICAL IND
Inventor: MORIYA SATORU , ISHIMOTO AKIO , AKANA YOSHINORI , YAMAMOTO YOZO , KISHIMURA KOTARO , IKEJIRI FUMITOSHI
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公开(公告)号:AT120220T
公开(公告)日:1995-04-15
申请号:AT90307868
申请日:1990-07-18
Applicant: MITSUI PETROCHEMICAL IND
Inventor: MORIYA SATORU , TAKAHASHI MAMORU , ISHIMOTO AKIO , HIROSE TOSHIYUKI
Abstract: A polyolefin resin composition comprising (A) a polyolefin resin, (B) a graft-modified alpha -olefin copolymer grafted with an unsaturated carboxylic acid and its derivative, and(C) an amino group-containing compound,(D) said polyolefin resin composition containing a crosslinked structure between the amino group-containing compound (C) and the graft-modified alpha -olefin copolymer (B), and containing, based on 100 parts by weight of the polyolefin resin (A) and the graft-modified alpha -olefin copolymer (B) in total, 1 to 99 parts by weight of each of the polyolefin resin (A) and the graft-modified alpha -olefin copolymer (B) and 0.01 to 10 parts by weight of the amino group-containing compound (C). The polyolefin resin composition gives a crosslinked molded article havig impact resistance at ordinary temperature and a low temperature.
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