公开(公告)号：EP0704462A4

公开(公告)日：1996-08-07

申请号：EP95914558

申请日：1995-04-11

Applicant: MITSUI PETROCHEMICAL IND

Inventor： UEDA TAKASHI ,  HASHIMOTO MIKIO ,  KAWASAKI MASAAKI ,  FUKUOKA DAISUKE ,  IMUTA JUNICHI

IPC: C08F2/00 ,  C08F297/08 ,  C08L23/04 ,  C08L23/08 ,  C08L23/10 ,  C08F10/06 ,  C08F4/60 ,  C08F297/06 ,  C08L23/14

CPC classification number: C08F297/083 ,  C08F297/08 ,  C08L23/0815 ,  C08L23/10 ,  Y10S526/943 ,  C08L2666/06

Abstract: A process for producing a propylene polymer composition by conducting a multi-stage polymerization comprising the step (a) of producing a propylene (co)polymer (a) and the step (b) of producing an ethylene copolymer (b) in an arbitrary order in the presence of a transition metal compound (A) containing a ligand having a cyclopentadienyl skeleton and a compound (B) capable of activating the compound (A) and also in the presence, in the step (b), of the polymer produced in the preceding step (a), in which process the obtained polymer composition contains 20-90 wt. % of the (co)polymer (a) and 80-10 wt. % of the copolymer (b) and has a melt flow rate of 0.01-500 g/10 min as measured at a temperature of 230 °C under a load of 2.16 kg. This process can provide a propylene polymer composition having an excellent balance among rigidity, heat resistance and impact resistance.

Abstract translation: 一种通过进行多阶段聚合生产丙烯聚合物组合物的方法，该方法包括以任意顺序生产丙烯（共）聚合物（a）和生产乙烯共聚物（b）的步骤（b）的步骤 在含有具有环戊二烯基骨架的配体和能够活化化合物（A）的化合物（B）的过渡金属化合物（A）的存在下，以及在步骤（b）中存在的 在前面的步骤（a）中，在该方法中，所得聚合物组合物含有20-90wt。 （共）聚合物（a）和80-10wt。 共聚物（b）的％，并且在230℃的温度和2.16kg的负荷下测得的熔体流动速率为0.01-500g / 10分钟。 该方法可以提供刚性，耐热性和耐冲击性之间具有优异平衡的丙烯聚合物组合物。

公开(公告)号：EP0646624A4

公开(公告)日：1996-03-20

申请号：EP94904013

申请日：1994-01-11

Applicant: MITSUI PETROCHEMICAL IND

Inventor： HASHIMOTO MIKIO ,  UEDA TAKASI ,  KAWASAKI MASAAKI ,  MORIYA SATORU ,  MIZUNO AKIRA ,  FUKUOKA DAISUKE ,  IMUTA JUNICHI ,  HIROSE KEIJI ,  SAITO JUNJI ,  KISO YOSHIHISA

IPC: C08F4/642 ,  C08L23/08 ,  C08L23/10 ,  C08L23/12 ,  C08L23/14 ,  C08L23/16 ,  C08L23/00 ,  C08L101/00

CPC classification number: C08L23/12 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/142 ,  C08L23/16 ,  C08L2205/02 ,  C08L2314/06 ,  C08L2666/04

Abstract: A propylene polymer composition composed of a propylene polymer (A1) produced by using a metallocene catalyst and having a melt flow rate (MFR) of 0.01-30 g/10 min, a propylene polymer (A2) having an MFR of 30-1,000 g/10 min and, if necessary, a flexible polymer, wherein the ratio of the MFR of the polymer (A2) to that of the polymer (A1) is at least 30. A propylene polymer composition composed of a propylene polymer produced by using a titanium catalyst and having an MFR of 0.01-30 g/10 min, the above polymer (A2) and, if necessary, a flexible polymer. A propylene polymer composition composed of a propylene polymer produced by using a titanium catalyst and having an MFR of 0.01-50 g/10 min and an ethylene-olefin random copolymer produced by using a metallocene catalyst. A propylene polymer composition composed of a propylene polymer produced by using a catalyst containing a specified metallocene compound and at least one synthetic resin selected from among a propylene polymer other than the above propylene polymer, an olefin elastomer and an olefin polymer. All of the above polymer compositions are excellent in heat resistance, mechanical strengths and tensile elongation at break and are suitable for producing various structural materials of automobiles, household electric appliances, etc., daily necessities, films, sheets, and so forth.

公开(公告)号：EP0682042A4

公开(公告)日：1997-03-26

申请号：EP95901603

申请日：1994-11-29

Applicant: MITSUI PETROCHEMICAL IND

Inventor： UEDA TAKASHI ,  MIZUNO AKIRA ,  KAWASAKI MASAAKI ,  FUKUOKA DAISUKE ,  KISO YOSHIHISA ,  TANIZAKI TATSUYA ,  HASHIMOTO MIKIO ,  SUGI MASAHIRO ,  TSUTSUI TOSHIYUKI

IPC: C07C45/46 ,  C07C49/67 ,  C07C49/697 ,  C07F17/00 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  C08F210/08

CPC classification number: C08F210/16 ,  C07C45/46 ,  C07C49/67 ,  C07C49/697 ,  C07F17/00 ,  C08F4/61908 ,  C08F4/61912 ,  C08F4/61927 ,  C08F4/63912 ,  C08F4/63927 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  Y10S526/943 ,  C08F2500/15 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/26 ,  C08F210/14 ,  C08F210/08

Abstract: A novel propylene elastomer having such characteristics that: (1) it is composed of 50-95 mole % of units derived from propylene and 50-5 mole % of units derived from 1-butene, (2) it has a triad tracticity (mm faction) of at least 90 % as determined by 13C-NMR spectrometry (in hexachlorobutadiene using tetramethylsilane as the internal standard), (3) it has a limiting viscosity of 0.1-12 dl/g (at 135 °C in decalin), (4) it has a molecular weight distribution (Mw/Mn) of 3 or less, and (5) it has a randomness parameter (B) of 1.0 to 1.5, preferably 1.0 to 1.3. In addition, it is desirable that: (6) it has a melting point (Tm) of 60-140 °C and the following relationship holds between the Tm and the 1-butene unit content (M, mole %): -2.6 M + 130 « Tm « -2.3 M + 155, (7) the following relationship holds between the degree of crystallinity (C) and the 1-butene unit content (M, mole %) C » -1.5 M + 75, the elastomer is excellent in rigidity, heat and scratch resistances, transparency, heat sealability, and blocking resistance. It can be produced by using a specified transition metal compound as the catalyst.

公开(公告)号：EP0704463A4

公开(公告)日：1996-08-07

申请号：EP95914559

申请日：1995-04-11

Applicant: MITSUI PETROCHEMICAL IND

Inventor： UEDA TAKASHI ,  HASHIMOTO MIKIO ,  KAWASAKI MASAAKI ,  FUKUOKA DAISUKE ,  IMUTA JUNICHI

IPC: C08F2/00 ,  C08F2/20 ,  C08F4/60 ,  C08F10/06 ,  C08F210/06 ,  C08F210/16 ,  C08F297/08 ,  C08F297/06 ,  C08L23/08 ,  C08L23/14

CPC classification number: C08F297/086 ,  C08F4/65912 ,  C08F10/06 ,  C08F210/06 ,  C08F210/16 ,  C08F2/001 ,  C08F2500/12 ,  C08F2500/17 ,  C08F210/08 ,  C08F210/14 ,  C08F110/06 ,  C08F4/6492 ,  C08F4/65927

Abstract: A process for producing a propylene polymer composition by conducting a multi-stage polymerization comprising the step (a) of producing a propylene (CO) polymer (a), the step (b) of producing a propylene-olefin copolymer (b), and the step (c) of producing an ethylene-olefin copolymer (c) in an arbitrary order in the presence of a transition metal compound (A) containing a ligand having a cyclopentadienyl skeleton and a compound (B) capable of activating the compound (A) and also in the presence, in the steps (b) and (c) of the polymers produced in the preceding steps, in which process the obtained polymer composition contains 20-90 wt.% of the co(polymer) (a), 5-75 wt.% of the copolymer (b), and 5-75 wt.% of the copolymer (c) and has a melt flow rate of 0.01-500 g/10 min. as measured at a temperature of 230 °C under a load of 2.16 kg. This process can provide a propylene polymer composition having an excellent balance among rigidity, heat resistance and impact resistance.

公开(公告)号：AU658089B2

公开(公告)日：1995-03-30

申请号：AU5633694

申请日：1994-02-24

Applicant: MITSUI PETROCHEMICAL IND

Inventor： HIRAOKA SHOJI ,  YAMAGUCHI MASAYOSHI ,  INAGAKI HAJIME ,  HASHIMOTO MIKIO

IPC: C08L23/00 ,  C08K5/17 ,  C08L23/06 ,  C08L23/08 ,  C08L23/10 ,  C08L23/16 ,  C08L23/20 ,  C08L23/26 ,  C08L23/36 ,  C08L51/06 ,  C08L53/00 ,  C08L53/02 ,  C08L23/12

公开(公告)号：CA2125247A1

公开(公告)日：1994-12-08

申请号：CA2125247

申请日：1994-06-06

Applicant: MITSUI PETROCHEMICAL IND

Inventor： FUKUOKA DAISUKE ,  TASHIRO TAKASHI ,  KAWAAI KOJI ,  SAITO JUNJI ,  UEDA TAKASHI ,  KISO YOSHIHISA ,  MIZUNO AKIRA ,  KAWASAKI MASAAKI ,  ITOH MASAAKI ,  IMUTA JUNICHI ,  FUJITA TERUNORI ,  NITABARU MASATOSHI ,  YOSHIDA MASAYASU ,  HASHIMOTO MIKIO

IPC: C07C45/46 ,  C07C49/67 ,  C07C49/697 ,  C07F17/00 ,  C08F4/60 ,  C08F4/602 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  C07F7/00 ,  C07F9/00 ,  C07F11/00 ,  C08F4/42

Abstract: The novel transition metal compound of the invention is represented by the following formula (I): (see formula I) wherein M is a transition metal; R1 is a hydrocarbon group of 2 to 6 carbon atoms, R2 is an aryl group of 6 to 16 carbon atoms; X1 and X2 are each a halogen atom or the like; and Y is a divalent hydrocarbon group, a divalent silicon-containing group or the like. An olefin polymerization catalyst component of the present invention comprises the aforementioned transition metal compound. An olefin polymerization catalyst of the present invention comprises the aforementioned olefin polymerization catalyst component. The propylene homopolymer, the propylene copolymer and the propylene elastomer according to the present invention have such properties that the triad tacticity of propylene units chain is high, a proportion of the inversely units based on the 2,1-insertion of propylene monomer is in the specific range, and the intrinsic viscosity [.pi.], as measured in decahydronaphthalene at 135.degree.C, is in the specific range.

公开(公告)号：CA2116413A1

公开(公告)日：1994-08-26

申请号：CA2116413

申请日：1994-02-24

Applicant: MITSUI PETROCHEMICAL IND

Inventor： HIRAOKA SHOJI ,  YAMAGUCHI MASAYOSHI ,  INAGAKI HAJIME ,  HASHIMOTO MIKIO

IPC: C08L23/00 ,  C08K5/17 ,  C08L23/06 ,  C08L23/08 ,  C08L23/10 ,  C08L23/16 ,  C08L23/20 ,  C08L23/26 ,  C08L23/36 ,  C08L51/06 ,  C08L53/00 ,  C08L53/02

Abstract: Disclosed is a propylene polymer composition comprising (a) a propylene polymer, (b) an olefin type elastomer and (c) a polar group-containing olefin polymer composition obtained by heating (c-1) an olefin polymer containing a carboxyl group or an acid anhydride group in its molecule and (c-2) an amino compound, each in a specific amount. Also disclosed is a propylene polymer composition comprising (a) a propylene polymer, (b) an olefin type elastomer, (c-1) an olefin polymer containing a carboxyl group or an acid anhydride group in its molecule and (c-2) an amino compound, each in a specific amount. The propylene polymer compositions of the present invention are excellent in properties of being coated with various coatings.

公开(公告)号：CA1286817C

公开(公告)日：1991-07-23

申请号：CA548384

申请日：1987-10-01

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KOGA HITOSHI ,  IWATA KAZUO ,  NISHIMOTO MASUSHI ,  HASHIMOTO MIKIO

IPC: C08L51/06 ,  C08L67/02 ,  C08L67/03

Abstract: An amorphous polyester composition according to the present invention comprises (A) a low crystalline polyolefin modified with unsaturated carboxylic acids, (B) an amorphous polyester, (C) a silane coupling agent and (D) an optional inorganic filler, wherein (A) forms a matrix phase and (B) forms a domain phase. This amorphous polyester composition has excellent adhesion properties to different materials such as metal and has excellent damping performance, and therefore a damping material having excellent initial adhesion properties and waterresistant adhesion properties and excellent damping performance, particularly at high temperatures can be obtained from such an amorphous polyester composition.

公开(公告)号：AU605845B2

公开(公告)日：1991-01-24

申请号：AU1379788

申请日：1988-03-28

Applicant: MITSUI PETROCHEMICAL IND

Inventor： HASHIMOTO MIKIO ,  NIIMI HIROJI ,  YATSU TADAO ,  SHIRAKI SHIGEMI

IPC: C08G63/672 ,  C08G63/66 ,  B65D1/40

Abstract: Polyethylene terephthalates having 97 to 98.6 mole % of repeating ethylene terephthalate units and 3 to 1.4 mole % of repeating units of diethyleneoxy terephthalate units have excellent mechanical strength, heat resistance and transparency, and can be used to provide blow molded containers of excellent high temperature filling properties such that they can be filled at high temperature without deforming and can be sterilized.

公开(公告)号：CA2157400C

公开(公告)日：2003-07-29

申请号：CA2157400

申请日：1995-04-11

Applicant: MITSUI PETROCHEMICAL IND

Inventor： UEDA TAKASHI ,  HASHIMOTO MIKIO ,  KAWASAKI MASAAKI ,  FUKUOKA DAISUKE ,  IMUTA JUNICHI

IPC: C08F2/00 ,  C08F297/08 ,  C08L23/04 ,  C08L23/08 ,  C08L23/10 ,  C08F10/06 ,  C08F297/06 ,  C08F4/60

Abstract: A process for preparing a propylene polymer composition comprising conducting multistage polymerization including a step (a) for preparing a propylene (co)polymer (a) and a step (b) for preparing an ethylene copolymer (b) in the presence of (A) a transition metal compound and (B) a compound activating the transition metal compound (A), in which the steps (a) and (b) may be carried out in any order, and the resulting propylene polymer composition contains the propylene (co)polymer (a) in an amount of 20 to 90 a by weight and the ethylene copolymer (b) in an amount of 10 to 80 % by weight and has MFR, as measured at 230 .degree.C under a load of 2.16 kg, of 0.01 to 500 g/10 min; and a propylene polymer composition prepared by this process. The process according to the invention can prepare a propylene polymer composition having excellent rigidity, heat resistance and impact resistance.