公开(公告)号：EP0704462A4

公开(公告)日：1996-08-07

申请号：EP95914558

申请日：1995-04-11

Applicant: MITSUI PETROCHEMICAL IND

Inventor： UEDA TAKASHI ,  HASHIMOTO MIKIO ,  KAWASAKI MASAAKI ,  FUKUOKA DAISUKE ,  IMUTA JUNICHI

IPC: C08F2/00 ,  C08F297/08 ,  C08L23/04 ,  C08L23/08 ,  C08L23/10 ,  C08F10/06 ,  C08F4/60 ,  C08F297/06 ,  C08L23/14

CPC classification number: C08F297/083 ,  C08F297/08 ,  C08L23/0815 ,  C08L23/10 ,  Y10S526/943 ,  C08L2666/06

Abstract: A process for producing a propylene polymer composition by conducting a multi-stage polymerization comprising the step (a) of producing a propylene (co)polymer (a) and the step (b) of producing an ethylene copolymer (b) in an arbitrary order in the presence of a transition metal compound (A) containing a ligand having a cyclopentadienyl skeleton and a compound (B) capable of activating the compound (A) and also in the presence, in the step (b), of the polymer produced in the preceding step (a), in which process the obtained polymer composition contains 20-90 wt. % of the (co)polymer (a) and 80-10 wt. % of the copolymer (b) and has a melt flow rate of 0.01-500 g/10 min as measured at a temperature of 230 °C under a load of 2.16 kg. This process can provide a propylene polymer composition having an excellent balance among rigidity, heat resistance and impact resistance.

Abstract translation: 一种通过进行多阶段聚合生产丙烯聚合物组合物的方法，该方法包括以任意顺序生产丙烯（共）聚合物（a）和生产乙烯共聚物（b）的步骤（b）的步骤 在含有具有环戊二烯基骨架的配体和能够活化化合物（A）的化合物（B）的过渡金属化合物（A）的存在下，以及在步骤（b）中存在的 在前面的步骤（a）中，在该方法中，所得聚合物组合物含有20-90wt。 （共）聚合物（a）和80-10wt。 共聚物（b）的％，并且在230℃的温度和2.16kg的负荷下测得的熔体流动速率为0.01-500g / 10分钟。 该方法可以提供刚性，耐热性和耐冲击性之间具有优异平衡的丙烯聚合物组合物。

公开(公告)号：EP0630916B1

公开(公告)日：1997-12-29

申请号：EP94112639

申请日：1991-02-26

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KIOKA MAMURO ,  YASHIKI TSUNEO ,  UEDA TAKASHI ,  KOHYAMA MASAKI ,  YAMADA MASAYA ,  IKEYAMA SEIICHI ,  AKANA YOSHINORI ,  IWATA KENJI ,  MATSUMOTO SATOSHI ,  SAKAI HIDEKI

IPC: C08F210/02 ,  C08F210/16 ,  C08J5/18 ,  C08K5/00 ,  C08K5/524 ,  C08L23/08

CPC classification number: C08J5/18 ,  C08F210/16 ,  C08J2323/08 ,  C08K5/005 ,  C08L23/0815 ,  C08F4/6492 ,  C08F4/6546 ,  C08F4/651 ,  C08L23/08 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/20 ,  C08F2500/13 ,  C08F2500/26

公开(公告)号：EP0682042A4

公开(公告)日：1997-03-26

申请号：EP95901603

申请日：1994-11-29

Applicant: MITSUI PETROCHEMICAL IND

Inventor： UEDA TAKASHI ,  MIZUNO AKIRA ,  KAWASAKI MASAAKI ,  FUKUOKA DAISUKE ,  KISO YOSHIHISA ,  TANIZAKI TATSUYA ,  HASHIMOTO MIKIO ,  SUGI MASAHIRO ,  TSUTSUI TOSHIYUKI

IPC: C07C45/46 ,  C07C49/67 ,  C07C49/697 ,  C07F17/00 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  C08F210/08

CPC classification number: C08F210/16 ,  C07C45/46 ,  C07C49/67 ,  C07C49/697 ,  C07F17/00 ,  C08F4/61908 ,  C08F4/61912 ,  C08F4/61927 ,  C08F4/63912 ,  C08F4/63927 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  Y10S526/943 ,  C08F2500/15 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/26 ,  C08F210/14 ,  C08F210/08

Abstract: A novel propylene elastomer having such characteristics that: (1) it is composed of 50-95 mole % of units derived from propylene and 50-5 mole % of units derived from 1-butene, (2) it has a triad tracticity (mm faction) of at least 90 % as determined by 13C-NMR spectrometry (in hexachlorobutadiene using tetramethylsilane as the internal standard), (3) it has a limiting viscosity of 0.1-12 dl/g (at 135 °C in decalin), (4) it has a molecular weight distribution (Mw/Mn) of 3 or less, and (5) it has a randomness parameter (B) of 1.0 to 1.5, preferably 1.0 to 1.3. In addition, it is desirable that: (6) it has a melting point (Tm) of 60-140 °C and the following relationship holds between the Tm and the 1-butene unit content (M, mole %): -2.6 M + 130 « Tm « -2.3 M + 155, (7) the following relationship holds between the degree of crystallinity (C) and the 1-butene unit content (M, mole %) C » -1.5 M + 75, the elastomer is excellent in rigidity, heat and scratch resistances, transparency, heat sealability, and blocking resistance. It can be produced by using a specified transition metal compound as the catalyst.

公开(公告)号：EP0704463A4

公开(公告)日：1996-08-07

申请号：EP95914559

申请日：1995-04-11

Applicant: MITSUI PETROCHEMICAL IND

Inventor： UEDA TAKASHI ,  HASHIMOTO MIKIO ,  KAWASAKI MASAAKI ,  FUKUOKA DAISUKE ,  IMUTA JUNICHI

IPC: C08F2/00 ,  C08F2/20 ,  C08F4/60 ,  C08F10/06 ,  C08F210/06 ,  C08F210/16 ,  C08F297/08 ,  C08F297/06 ,  C08L23/08 ,  C08L23/14

CPC classification number: C08F297/086 ,  C08F4/65912 ,  C08F10/06 ,  C08F210/06 ,  C08F210/16 ,  C08F2/001 ,  C08F2500/12 ,  C08F2500/17 ,  C08F210/08 ,  C08F210/14 ,  C08F110/06 ,  C08F4/6492 ,  C08F4/65927

Abstract: A process for producing a propylene polymer composition by conducting a multi-stage polymerization comprising the step (a) of producing a propylene (CO) polymer (a), the step (b) of producing a propylene-olefin copolymer (b), and the step (c) of producing an ethylene-olefin copolymer (c) in an arbitrary order in the presence of a transition metal compound (A) containing a ligand having a cyclopentadienyl skeleton and a compound (B) capable of activating the compound (A) and also in the presence, in the steps (b) and (c) of the polymers produced in the preceding steps, in which process the obtained polymer composition contains 20-90 wt.% of the co(polymer) (a), 5-75 wt.% of the copolymer (b), and 5-75 wt.% of the copolymer (c) and has a melt flow rate of 0.01-500 g/10 min. as measured at a temperature of 230 °C under a load of 2.16 kg. This process can provide a propylene polymer composition having an excellent balance among rigidity, heat resistance and impact resistance.

公开(公告)号：CZ283582B6

公开(公告)日：1998-05-13

申请号：CS694290

申请日：1990-12-29

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KIOKA MAMORU ,  NAKANO MASAO ,  UEDA TAKASHI

IPC: C08F4/652 ,  C08F4/60 ,  C08F4/651 ,  C08F4/654 ,  C08F4/656 ,  C08F10/00 ,  C08F10/02 ,  C08F10/06

Abstract: The present invention relates to solid catalyst components for olefin polymerization formed by prepolymerizing at least two types of alpha -olefin on an olefin polymerization catalyst comprising a solid titanium catalyst component, an organometallic compound catalyst component, and if necessary, an electron donor, to olefin polymerization catalyst comprising said soild catalyst component for olefin polymerization, an organometallic compound catalyst component, and if necessary, an electron donor, and to processes for olefin polymerization using said olefin polymerization catalyst. According to the present invention, there can be manufactured olefin polymer particles having low adhesive among the polymer particles as well as good particle distribution and excellent granular properties even when they contain a large amount of an amorphous olefin polymer portion.

公开(公告)号：DE69030489T2

公开(公告)日：1997-09-04

申请号：DE69030489

申请日：1990-12-28

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KIOKA MAMORU ,  NAKANO MASAO ,  UEDA TAKASHI

IPC: C08F4/652 ,  C08F4/60 ,  C08F4/651 ,  C08F4/654 ,  C08F4/656 ,  C08F10/00 ,  C08F10/02 ,  C08F10/06 ,  C08F210/00

Abstract: The present invention relates to solid catalyst components for olefin polymerization formed by prepolymerizing at least two types of alpha -olefin on an olefin polymerization catalyst comprising a solid titanium catalyst component, an organometallic compound catalyst component, and if necessary, an electron donor, to olefin polymerization catalyst comprising said soild catalyst component for olefin polymerization, an organometallic compound catalyst component, and if necessary, an electron donor, and to processes for olefin polymerization using said olefin polymerization catalyst. According to the present invention, there can be manufactured olefin polymer particles having low adhesive among the polymer particles as well as good particle distribution and excellent granular properties even when they contain a large amount of an amorphous olefin polymer portion.

公开(公告)号：DE69030489D1

公开(公告)日：1997-05-22

申请号：DE69030489

申请日：1990-12-28

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KIOKA MAMORU ,  NAKANO MASAO ,  UEDA TAKASHI

IPC: C08F4/652 ,  C08F4/60 ,  C08F4/651 ,  C08F4/654 ,  C08F4/656 ,  C08F10/00 ,  C08F10/02 ,  C08F10/06 ,  C08F210/00

Abstract: The present invention relates to solid catalyst components for olefin polymerization formed by prepolymerizing at least two types of alpha -olefin on an olefin polymerization catalyst comprising a solid titanium catalyst component, an organometallic compound catalyst component, and if necessary, an electron donor, to olefin polymerization catalyst comprising said soild catalyst component for olefin polymerization, an organometallic compound catalyst component, and if necessary, an electron donor, and to processes for olefin polymerization using said olefin polymerization catalyst. According to the present invention, there can be manufactured olefin polymer particles having low adhesive among the polymer particles as well as good particle distribution and excellent granular properties even when they contain a large amount of an amorphous olefin polymer portion.

公开(公告)号：AT151782T

公开(公告)日：1997-05-15

申请号：AT90125706

申请日：1990-12-28

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KIOKA MAMORU ,  NAKANO MASAO ,  UEDA TAKASHI

IPC: C08F4/652 ,  C08F4/60 ,  C08F4/651 ,  C08F4/654 ,  C08F4/656 ,  C08F10/00 ,  C08F10/02 ,  C08F10/06 ,  C08F210/00

Abstract: The present invention relates to solid catalyst components for olefin polymerization formed by prepolymerizing at least two types of alpha -olefin on an olefin polymerization catalyst comprising a solid titanium catalyst component, an organometallic compound catalyst component, and if necessary, an electron donor, to olefin polymerization catalyst comprising said soild catalyst component for olefin polymerization, an organometallic compound catalyst component, and if necessary, an electron donor, and to processes for olefin polymerization using said olefin polymerization catalyst. According to the present invention, there can be manufactured olefin polymer particles having low adhesive among the polymer particles as well as good particle distribution and excellent granular properties even when they contain a large amount of an amorphous olefin polymer portion.

公开(公告)号：ES2098318T3

公开(公告)日：1997-05-01

申请号：ES91301167

申请日：1991-02-13

Applicant: MITSUI PETROCHEMICAL IND

Inventor： TSUTSUI TOSHIYUKI ,  UEDA TAKASHI

IPC: C08F10/02 ,  C08F210/16 ,  C08F297/08 ,  C08L23/04

Abstract: A method for the preparation of an ethylene polymer composition having a density of 0.87-0.93 g/cm and an intrinsic viscosity Ä eta Ü of 0.5-6 dl/g, which comprises carrying out a multi-stage process comprising a polymerization step (c): wherein ethylene and another alpha -olefin are copolymerized using an olefin polymerization catalyst ÄIIÜ, which comprises a transition metal compound ÄAÜ containing a ligand having a cycloalkadienyl skeleton and an organoaluminum oxy-compound ÄBÜ, to form an ethylene copolymer ÄIIIÜ having a density of lower than 0.91 g/cm and an intrinsic viscosity Ä eta Ü of 0.5-6 dl/g, and a polymerization step (d): wherein ethylene is homopolymerized or ethylene and another alpha -olefin are copolymerized using an olefin polymerization catalyst ÄIIIÜ, which comprises a titanium catalyst component ÄCÜ containing titanium, magnesium and halogen as its essential ingredients, an organoaluminum compound ÄDÜ and/or an organoaluminum oxy-compound ÄEÜ to form an ethylene copolymer ÄIVÜ having a density greater than that of the ethylene copolymer ÄIIIÜ and an intrinsic viscosity Ä eta Ü of 0.5-6 dl/g, wherein the polymerization steps (c) and (d) are carried out such that step (c) is carried out first and step (d) is carried out in the presence of the ethylene copolymer ÄIIIÜ or step (d) is carried out first and step (c) is carried out in the presence of the ethylene polymer ÄIVÜ so that the ethylene polymer ÄIVÜ amounts to 10-1000 parts by weight based on 100 parts by weight of the ethylene copolymer ÄIIIÜ.

公开(公告)号：HK216296A

公开(公告)日：1996-12-27

申请号：HK216296

申请日：1996-12-19

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KIOKA MAMORU ,  YASHIKI TSUNEO ,  UEDA TAKASHI ,  KOHYAMA MASAKI ,  YAMADA MASAYA ,  IKEYAMA SEIICHI ,  AKANA YOSHINORI ,  IWATA KENJI ,  MATSUMOTO SATOSHI ,  SAKAI HIDEKI

IPC: C08F210/16 ,  C08J5/18 ,  C08F210/02 ,  C08K5/00 ,  C08K5/524 ,  C08L23/08 ,  C08F4/654

Abstract: The present invention relates to an ethylene/pentene-1 copolymer composition comprising an ethylene/pentene-1 copolymer (I) and at least one compound (II) selected from the group consisting of a phenolic stabilizer, an organic phosphite stabilizer, a thioether stabilizer, a hindered amine stabilizer and a metal salt of a higher aliphatic acid, which is excellent in heat stability in the molding stage, long-term heat stability and weatherability.