PRODUCTION OF LAMINATED MOLDED ARTICLE

    公开(公告)号:JPH0649239A

    公开(公告)日:1994-02-22

    申请号:JP1728793

    申请日:1993-02-04

    Abstract: PURPOSE:To obtain a heat-resistant laminated molded article without damaging excellent properties of a polyimide resin by using a new prepreg sheet having excellent strength at high temperature prepared from a specific polyamic acid and a reinforcing fiber material by a specific method. CONSTITUTION:First, a solution of a polyamic acid having a unit of formula I (R1 is bifunctional group selected from >=2C aliphatic group, monocyclic aromatic group, etc.; R2 is tetrafunctional group selected from >=2C aliphatic group, heterocyclic group, etc.; Y is H, alkyl, etc.) in an organic solvent is impregnated into a reinforcing fiber material and the solvent contained is extracted with an extracting solvent. Then the prepreg sheet impregnated with the polyamide is heated and dried to remove the residual solvent and to imidate the polyamic acid. Finally, the prepared prepreg sheet impregnated with the polyimide resin having a unit of formula II is laminated and heated to >= the glass transition temperature of the polyimide under pressure. The polyamic acid is preferably obtained by 3,3'-diaminobenzophenone and 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride.

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