公开(公告)号：JP2001055387A

公开(公告)日：2001-02-27

申请号：JP2000172047

申请日：2000-06-08

Applicant: SAGAMI CHEM RES ,  DAINIPPON INK & CHEMICALS

Inventor： KOBORI TAKEO ,  KONDO HITOSHI ,  TSUBOI HIROYUKI ,  IIYAMA MIKA ,  ASADA TORU ,  GOTO TAKASHI ,  SATO KENICHI ,  MATSUTANI SANAE ,  GOTO TOMOKO ,  HAGIWARA EMIKO

IPC: C07D233/64 ,  A01N43/50 ,  A01N43/56 ,  A01N43/60 ,  A01N43/78 ,  A01N43/828 ,  A01N43/832 ,  A01N55/00 ,  C07D231/12 ,  C07D241/12 ,  C07D271/08 ,  C07D277/10 ,  C07D285/06 ,  C07D285/10 ,  C07D401/12 ,  C07D401/14 ,  C07D409/14 ,  C07D413/06 ,  C07D413/12 ,  C07D413/14 ,  C07D417/06 ,  C07D417/12 ,  C07D417/14

Abstract: PROBLEM TO BE SOLVED: To obtain a new compound providing no fear of phytotoxicity to a useful plant body, having efficient activities for controlling plant disease, and useful as an agrochemical, especially a plant disease-controlling agent. SOLUTION: This new compound is the one of formula I (HetA is a group of formula II or the like; Q is H, a halogen or a lower alkyl; HetB is a group of formula III or the like; Y is H or a lower alkyl; HetC is a group of formula IV or the like; X is a lower alkoxy, cyano or the like; n is 0-3; with the proviso that the case in which HetA is a group of formula II or the like, HetB is a group of formula III or the like, and HetC is a group of formula IV is omitted), e.g. (E)-3-(3-methyl-1,2,5-thiadiazol-4-yl)pyridylmethanone O-(2-pyridyl)methyloxime. The compound of formula I is obtained by reacting a compound of formula V [e.g. 3-(3-methyl-1,2,5-thiadiazol-4-yl)pyridinemethanone oxime] with an alkylating agent (e.g. 2-picolyl chloride) in the presence of a base such as potassium carbonate.

公开(公告)号：JP2000247956A

公开(公告)日：2000-09-12

申请号：JP5052599

申请日：1999-02-26

Applicant: JAPAN ENERGY CORP ,  SAGAMI CHEM RES

Inventor： MATSUI JUNKO ,  KUSUMOTO TETSUO ,  HAGIWARA EMIKO ,  HIYAMA TAMEJIRO

IPC: C07D213/06 ,  C07D213/22 ,  C09K19/34 ,  G02F1/13

Abstract: PROBLEM TO BE SOLVED: To obtain a new tricyclic phenylpyridine derivative which is useful as a component for practically excellent liquid crystals responding at high speeds in wide temperature ranges, has alkyl side chains not having oxygen functional groups, and contains a pyridine ring. SOLUTION: A tricyclic phenylpyridine derivative of formula I (R1 is a 1-12C alkyl; R2 is a 1-12C alkyl or H; ring A and ring B are each 1,4-phenylene, pyridin-2,5-diyl, provided that the ring B is 1,4-phenylene, when the ring A is pyridin-2,5-diyl). For example, 2-(4decylphenyl)-5-(4-octylphenyl)pyridine. The compound of formula I is obtained, for example, by reacting an alkylbromobenzene of formula II with buthyllithium or the like to form the lithio compound, reacting the lithio compound with trimethyl borate, reacting the obtained borate derivative with 2,5-dibromopyridine in the presence of a palladium catalyst, and then reacting the obtained bromophenylpyridine derivative with a Grignard reagent in the presence of a nickel catalyst.

公开(公告)号：JP2003212883A

公开(公告)日：2003-07-30

申请号：JP2002012973

申请日：2002-01-22

Applicant: SAGAMI CHEM RES

Inventor： FUCHIGAMI TAKAMASA ,  HAGIWARA EMIKO

IPC: C07F7/18

Abstract: PROBLEM TO BE SOLVED: To provide a simple and highly versatile method for producing a silyl enol ether as a compound useful as an intermediate in organic synthesis. SOLUTION: This method for producing the silyl enol ether of the general formula: RCH=CH(OSiR 1 R 2 R 3 ) comprises reacting the corresponding disilyl acetal of the general formula: RCH 2 CH(OSiR 1 R 2 R 3 ) 2 in the presence of a transition metal catalyst. COPYRIGHT: (C)2003,JPO

公开(公告)号：JPH10147554A

公开(公告)日：1998-06-02

申请号：JP32094596

申请日：1996-11-15

Applicant: SHOWA SHELL SEKIYU ,  SAGAMI CHEM RES

Inventor： KOBAYASHI ICHIRO ,  SUZUKI GIICHI ,  KUSUMOTO TETSUO ,  HAGIWARA EMIKO ,  HIYAMA TAMEJIROU

IPC: G02F1/13 ,  C07C69/84 ,  C09K19/20

Abstract: PROBLEM TO BE SOLVED: To obtain a new antiferroelectric liquid crystal compound free of possibility of showing defects, such as uneven display or the like, when working as a display and excellent in dependence of response speed on temperature by adequately positioning the fluorine-modified site in the main skeleton in the antiferroelectric liquid crystal compound. SOLUTION: This antiferroelectric liquid crystal compound is shown by formula I (R is a 6-16C alkyl; R is a 2-10C alkyl; Cf is CH3 or CF3 ; and *is optically active carbon), e.g. 4- 1-(trifluoromethyl) pentyloxycarbonyl} phenyl-4'-decyl-3'-fluorobiphenyl-4-carboxylate. It has an index of temperature dependence of response time τ

公开(公告)号：JPH08310972A

公开(公告)日：1996-11-26

申请号：JP5135396

申请日：1996-03-08

Applicant: SAGAMI CHEM RES

Inventor： HATANAKA YASUO ,  HAGIWARA EMIKO ,  AIDA KENICHI ,  HIYAMA TAMEJIROU

IPC: C07D213/61 ,  B01J27/13 ,  B01J31/04 ,  C07B37/04 ,  C07B61/00 ,  C07C1/32 ,  C07C11/12 ,  C07C15/14 ,  C07C15/44 ,  C07C17/263 ,  C07C22/08 ,  C07C25/18 ,  C07C41/30 ,  C07C43/225 ,  C07C45/68 ,  C07C49/784 ,  C07C49/794 ,  C07C49/84 ,  C07C67/333 ,  C07C69/76 ,  C07C253/30 ,  C07C255/50 ,  C07D213/73 ,  C07D213/75 ,  C07F7/18

Abstract: PURPOSE: To obtain an organic compound such as biaryls and alkenylarenes useful as functional organic materials such as liquid crystal, pharmaceuticals and agrochemicals in short step and high yield. CONSTITUTION: The objective unsaturated organic compound of formula R -R is produced by reacting an organic halosilane compound of formula R -SiR m X3-m (R is an aryl, an alkenyl or an alkyl; R is same as R or a lower alkyl; X is a halogen; (m) is 0-2) with an organic halide of formula R -Y (R is an aryl, a 1-alkenyl or a 2-alkenyl; Y is a halogen) in a solvent (e.g. THF) in the presence of a group 10 transition metal catalyst (e.g. triphenylphosphine-palladium acetate) and a base (e.g. NaOH) at 0-200 deg.C. The amount of the catalyst is 0.2-5mol% based on the organic halide and that of the base is 3-10mol based on 1mol of the organic halosilane compound.

公开(公告)号：JP2003155258A

公开(公告)日：2003-05-27

申请号：JP2002012968

申请日：2002-01-22

Applicant: SAGAMI CHEM RES

Inventor： FUCHIGAMI TAKAMASA ,  HAGIWARA EMIKO

IPC: C07C45/00 ,  C07B61/00 ,  C07C47/02 ,  C07C47/277 ,  C07C47/32 ,  C07C47/542 ,  C07F7/18

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing disilyl acetals and aldehydes useful as an intermediate for an organic synthesis. SOLUTION: This method for producing the disilyl acetals expressed by the general formula RCH(OSiR R R )2 or RCH(OSiR R R )(OSiR R R ) is provided by performing a reaction of a carboxylic acid expressed by the general formula: RCOOH or a carboxylic acid silyl ester expressed by the general formula: RCOOSiR R R with a hydrosilane expressed by the general formula: HSiR R R in the presence of a ruthenium catalyst. The method for producing the aldehydes expressed by the general formula: RCHO is characterized by performing a reaction of the disilyl acetals in the presence of a transition metal catalyst.

公开(公告)号：JPH11302236A

公开(公告)日：1999-11-02

申请号：JP20881998

申请日：1998-07-24

Applicant: SAGAMI CHEM RES

Inventor： SODEOKA MIKIKO ,  HAGIWARA EMIKO ,  FUJII AKIO

IPC: B01J31/22 ,  C07B53/00 ,  C07B61/00 ,  C07C221/00 ,  C07C225/06 ,  C07C227/18 ,  C07C229/18 ,  C07C229/60 ,  C07C303/36 ,  C07C311/16 ,  C07F15/00

Abstract: PROBLEM TO BE SOLVED: To efficiently synthesize the subject compounds useful as an intermediate for producing medicines, etc., by reacting a silyl enol ether with an imine in the presence of a specific catalyst. SOLUTION: A silyl enol ether represented by formula I [R is a substituted silyl; R is a (substituted) alkyl, a (substitute) alkenyl or the like; R and R are each H, a (substituted) alkyl, a (substituted) alkenyl or the like] is reacted with an imine represented by formula II [R is a (substituted) alkyl, a (substituted) alkenyl or the like; R is H, a (substituted) alkyl, a (substituted) alkenyl or the like] in the presence of a catalyst comprising a palladium- optically active phosphine ligand to afford the objective compounds represented by formula III. In the above reaction, e.g. N,N-dimethylformamide is preferably used as a solvent and the reaction is preferably carried out in the presence of a base such as calcium carbonate at a reactional temperature within the range of ambient temperature to 70 deg.C.

公开(公告)号：JPH10147553A

公开(公告)日：1998-06-02

申请号：JP32094396

申请日：1996-11-15

Applicant: SHOWA SHELL SEKIYU ,  SAGAMI CHEM RES

Inventor： KOBAYASHI ICHIRO ,  SUZUKI GIICHI ,  KUSUMOTO TETSUO ,  HAGIWARA EMIKO ,  HIYAMA TAMEJIROU

IPC: G02F1/13 ,  C07C69/84 ,  C09K19/20

Abstract: PROBLEM TO BE SOLVED: To obtain a new antiferroelectric liquid crystal compound free of possibility of showing defects, such as uneven display or the like, when working as a display and excellent in dependence of response speed on temperature by adequately positioning the fluorine-modified site in the main skeleton in the antiferroelectric liquid crystal compound. SOLUTION: This antiferroelectric liquid crystal compound is shown by formula I (R is a 6-16C alkyl; R is a 2-10C alkyl; Cf is CH3 or CF3 ; and *is optically active carbon), e.g. 4- 1-(trifluoromethyl) benzyloxycarbonyl} phenyl-4'-decyl-3-fluorobiphenyl-4-carboxylate. It has an index of temperature dependence of response time τ1