Abstract:
A mixing device is presented which is suitable for use in the uniform mixing of polymer substances or the uniform mixing of polymer substances with, for example, fillers. This mixing device is composed of one (or more) mixing nozzle(s) which mixing nozzle(s) comprises an orifice portion (14) and an upstream compression zone (13) and/or a downstream diffusion zone (15). The ratio of the maximum opening cross-sectional area of the compression zone or the diffusion zone to the minimum opening cross-sectional area of the orifice portion is 10:1 or more. Two or more such mixing nozzles can be mounted in series and/or in parallel in one or more flow paths to a spinneret assembly. A highly viscous resin component, present as islands (12) in a low viscosity resin component (11) upstream of the orifice portion (14), is subjected to mixing.
Abstract:
A method for preventing fouling in the slurry polymerization of olefins in a solvent in the presence of a catalyst, which comprises causing a small amount of a nitrogen-containing salt of phytic acid or a mixture of it with an alkali metal salt of an organic acid to be present as an anti-fouling agent in the polymerization system.
Abstract:
Spiropiperidinenaphtoxazine compounds represented by general formula (I) are useful as photochromic compounds, wherein (a) R1 represents a C1-18 alkyl group, an optionally substituted C7-15 aralkyl group, a C1-10 alkenyl group, or an optionally substituted C6-15 aryl group; (b) R2 to R9 are the same as defined for R1, or each represents a hydrogen atom or is bound to each other to form a C5-10 alicyclic ring, norbornyl or adamantyl on the same skeletal carbon atom or between adjacent (o-position) skeletal carbon atoms; (c) R10 represents a hydrogen atom, a C1-18 alkyl group, a C7-15 aralkyl group which may be optionally substituted, or a C1-10 alkenyl group; and (d) R11 to R16 each represents a hydrogen atom, a C1-9 alkyl, C1-5 alkoxy, halogen, nitro or cyano group.
Abstract:
PROBLEM TO BE SOLVED: To obtain a powdered solder, which is stable for oxidation, excellent in storage stability and has inert surface, by treating the surface of powdered solder with a specific organic silane compound. SOLUTION: The surface of a material for powdered solder is treated with at least one kind of a silane compound shown by the equation I, equation II, equation III. Where, R1 -R4 in the equations I, II, III are of an alkyl base/aryl base or an aryl base. Further, a hydrogen atom of R1 can be substituted with one piece or more fluorine atoms. A means to coat a silane compound to a material for powdered solder can be either of dry process, wet process, spray process, etc. A concentration of the silane compound for coating is desirable to be below 4% and above 0.007 for the weight of material for powdered solder.
Abstract:
PURPOSE:To produce the high quality plastic lens with good yield, while the surface contamination or unevenness of a molding, the mold release in polymerization process and the occurrence of voids are prevented by thermally polymerizing the raw material-monomer under the atmosphere whose oxygen concentration is lower than that of normal atmosphere until the stage where said monomer is polymerized and its gelation is initiated. CONSTITUTION:Two matrixes with desired curved surfaces are fixed oppositely by using an annular gasket, or two matrixes are positioned oppositely and are fixed by winding a tape around these matrixes. The raw material monomer containing a radical polymerization initiator and other additives is poured into the cavity between two matrixes, and is thermally polymerized under the atmosphere whose oxygen concentration is lower than that of normal atmosphere until the stage where its gelation is initiated. Next, the annular gasket or the tape is removed from the matrixes, and the thermal polymerization is further advanced and finished in the oxygen concentration of the normal atmosphere. The annular gasket or the tape is generally used as the means for fastening the matrixes, but the tape is preferably used from the point of operability.
Abstract:
PURPOSE:To improve the productivity and the quality of products by coating a magnetic head element with a specified acetal compd. and a mercapto compd. or a mixture of the compds. and a specified acrylate compd., curing the matrial and then forming an inorg. lubricative coated film on the part to be brought into contact with a tape. CONSTITUTION:The acetal compd. to be used consists of an unsaturated cycloacetal compd. having, in one molecule, at least 2 unsaturated cycloacetal groups expressed by formula (I) (unsaturated dioxane type) and/or formula (II) (unsaturated dioxolane type). The mercapto compd. to be used is a compd. having, in one molecule, at least 2 mercapto groups and is aliphatic or aromatic mercaptan. Beisides, any compd. having at least 2 acryloyl or metacryloyl groups in one molecule, copolymerizable with an acetal compd. and a mercapto compd. and uniformly miscible with each other can be used as the acrylate compd.
Abstract:
PURPOSE:To prevent the influence of external air and to improve water resistance by sealing the titled element by the cross linked matter of an acetal compd. and mercapto compd. or a mixture composed of these compds. and acrylate compd. CONSTITUTION:This element is sealed by the cured matter of the acetal compd. and mercapto compd. or the mixture composed of these compds. and the acrylate compd. The acetal compd. refers to the unsatd. cycloacetal compd. having at least two unsatd. cycloacetal groups expressed by formula 1 (unsatd. dioxane type) and (or) formula 2 (unsatd. dioxolane type) in one molecule. The mercapto compd. is aliphat. or arom. polymercaptan. The acrylate compd. is further used in combination with these compds. by which the viscosity of the mixture is decreased and the workability is improved. In addition, the hardness of the cured matter is made more thorough.
Abstract:
PURPOSE: To obtain the titled very fine size-controlled particles of virtually shperical form, by incorporating a polybasic acid in a mixture of resin and an incompatible medium, stirring the system at temperatures above a specified level to disperse the resin followed by separation of said resin (particles) from the medium. CONSTITUTION: A polybasic acid is incorporated in a mixture of a thermoplastic resin and a medium virtually incompatible with said resin, the resultant system being stirred at temperatures above the melting or softening point of the medium to fully disperse the resin (particles) followed by separation of said resin (particles) from the medium, thus obtaining the objective fine particles. The thermoplastic resin is e.g. polyethylene, polyamide. The medium is e.g. polyethylene glycol. The polybasic acid is e.g. sulfuric acid, sulfurous acid sulfonic acid, fuming sulfuric acid, phosphoric acid. The size of the particles finally obtained is ≤50μm. COPYRIGHT: (C)1985,JPO&Japio
Abstract:
PURPOSE:To obtain a mixer which can be used even in the mixing of a system having a low compatibility, i.e., liable to phase separation, by using a structure in which the ratio of the maximum opening sectional area of compression part and/or diffusion part to the sum of the minimum opening sectional areas of each independent opening of throttled part located between the compression part and the diffusion part is specifically designated. CONSTITUTION:The mixer is equipped with one or parallelized two or more mixers 7 consisting of a throttled part 4 and a compression part 3 on the front side and/or a diffusion part 5 on the rear side. And, the ratio of the sectional area, or maximum opening sectional area S1, of the port of the compression part 3 to the sum S2 of the minimum sectional areas of each independent opening of the throttled part 4 is designated to S1/S2=10 or more, preferably 50 or more or more preferably 100 or more. Also, the minimum sectional area S3 of each independent opening of the throttled part 4 is desinated to 10mm. or less, particularly 30-0.001mm. . In case where a molecular component (or high-viscous component) and a low molecular component (or low-viscous component) of the same synthetic resin are melted and mixed, the mixer can uniformly mix both the components.
Abstract:
PURPOSE:To increase the draw ratio in a molten state extremely and improve the orientation and the fiber strength, by means of a tapered introductory part immediately before a land and at a specific ration between the maximum cross-sectional area and the outlet cross-sectional area of the land. CONSTITUTION:An introductory part 15 of a land 16 in a spinneret 10 is formed into a tapered shap, and the ratio between the amximum opening cross-sectional area of the introductory part 15 and the outlet cross-sectional area of the land 16 is 50:1 or more, preferably 100:1 or more. A molten polyolefin resin 13 fed from an extruder is passed through an annular path 14 of an adapther 11 to a spinneret 12, and extruded through the tapered introductory part 15 and the land 16 to give a fiber having a strength 15% higher than that of the conventional fiber.