公开(公告)号：US3850975A

公开(公告)日：1974-11-26

申请号：US13388671

申请日：1971-04-14

Applicant: SNAM PROGETTI

Inventor： FATTORE V ,  NOTARI B

IPC: C07C253/26 ,  B01J23/00 ,  B01J27/02 ,  B01J27/057 ,  C07C29/00 ,  C07C45/34 ,  C07C255/08 ,  C07C121/02

CPC classification number: C07C253/26 ,  B01J27/0576 ,  Y02P20/52 ,  C07C255/08

Abstract: 1. PROCESS FOR THE PREPARATION OF ACRYLONITRILE WHILD COMPRISES CONTACTING, AT A TEMPERATURE OF FROM 300*C. TO 500*C., A GASEOUS MIXTURE OF PROPYLENE, AMMONIA AND OXYGEN IN THE PRESENCE OF A CATALYST CONSISTING ESSENTIALLY OF A MIXTURE OF URANIUM OXIDE AND TELLURIUM OXIDE WHEREIN THE TE/U ATOMIC RATIO IS IN THE RANGE FROM 2 TO 5.

公开(公告)号：US3836436A

公开(公告)日：1974-09-17

申请号：US27593772

申请日：1972-07-28

Applicant: SNAM PROGETTI

Inventor： RIVOLA L ,  MORMINO V ,  NOTARI B

IPC: B01J23/50 ,  B01J37/34 ,  C07D301/10 ,  C25C5/02 ,  C22D5/00 ,  B01K3/00

CPC classification number: C07D301/10 ,  B01J23/50 ,  B01J37/348 ,  C25C5/02 ,  Y02P20/52

Abstract: A process is disclosed whereby a silver containing catalyst is produced, in a particle size ranging from 300 to 1,500 A, through the pulsed electrolysis of a solution of a silver salt (e.g., silver nitrate) in the presence of a complexing agent (e.g., ammonia) wherein current is fed to the solution for spaced periods of a few seconds duration. Advantageously, after about 10-15 cycles of feeding and interrupting the current to the solution, a current inversion lasting from a few seconds is effected. The silver is obtained in the form of a powder which, after washing, can be used directly or supported on a ceramic material as catalyst for the production of ethylene oxide.

Abstract translation: 公开了一种方法，其中通过在络合剂存在下通过脉冲电解银盐（例如硝酸银）溶液，制备粒度范围为300至1,500的含银催化剂（例如， 氨），其中电流被供给溶液，持续时间为几秒。 有利的是，在供给和中断电流到溶液的约10-15个循环之后，进行持续几秒的电流反转。 银以粉末的形式获得，其在洗涤后可直接使用或负载在陶瓷材料上作为生产环氧乙烷的催化剂。

公开(公告)号：US3792107A

公开(公告)日：1974-02-12

申请号：US3792107D

申请日：1971-07-21

Applicant: SNAM PROGETTI

Inventor： FATTORE V ,  MAZZEI M ,  NOTARI B

IPC: B01J23/888 ,  C07C6/04 ,  C07C3/62

CPC classification number: C07C6/04 ,  B01J23/888 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/72 ,  C07C2523/888

Abstract: A PROCESS IS DISCLOSED FOR DISPROPORTIONATING AN OLEFIN HAVING FROM 3 TO 30 CARBON ATOMS, WHEREIN THE OLEFIN IS CONTACTED WITH A CATALYST CONSISTING ESSENTIALLY OF AN OXIDE OF TUNGSTEN AND COPPER OR OF TUNGSTEN AND A METAL OF THE 8TH GROUP OF THE PERIODIC SYSTEM, PREFERABLY IRON, COBALT OR BICKEL, IN WHICH THE RATIO OF METAL TO TUNGSTEN IS IN THE RANGE OF 1:3 TO 5:1. THE CATALYST IS ADVANTAGEOUSLY SUPPORTED BY A CARRIER SUCH AS SILICA AND ITS CONTACT WITH THE OLEFIN IS EFFECTED AT A TEMPERATURE IN THE RANGE OF 400 TO 700*C, AT A PRESSURE IN THE RANGE OF 1 TO 50 ATMOSPHERES AND FOR A CONTACT TIME IN THE RANGE OF 0.1 TO 60 SECONDS.

公开(公告)号：US3764635A

公开(公告)日：1973-10-09

申请号：US3764635D

申请日：1971-04-14

Applicant: SNAM PROGETTI

Inventor： FATTORE V ,  MAZZEI M ,  NOTARI B

IPC: B01J23/31 ,  C07C6/04 ,  C07C3/62

CPC classification number: C07C6/04 ,  B01J23/31 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/31

Abstract: A process for disproportionating olefins is disclosed which employs a catalyst which includes tungsten and bismuth in the form of oxides or other forms.

Abstract translation: 公开了一种用于歧化烯烃的方法，其采用包含氧化物或其它形式的钨和铋的催化剂。

公开(公告)号：US3843491A

公开(公告)日：1974-10-22

申请号：US31906072

申请日：1972-12-27

Applicant: SNAM PROGETTI

Inventor： PIRO M ,  RIVOLA L ,  NOTARI B

IPC: B01J23/50 ,  B01J37/34 ,  C07D301/10 ,  C07D303/04 ,  C25C1/20 ,  C25C5/00 ,  C22D5/00 ,  C22D1/12

CPC classification number: C07D301/10 ,  B01J23/50 ,  B01J37/348 ,  Y02P10/138

Abstract: 1. A PROCESS FOR THE PREPARATION OF SILVER USEFUL AS A CATALYST BY SILVER ELECTROCHEMICAL DEPOSITION COMPRISING: COMPLEXING A SILVER COMPOUND WITH A MEMBER SELECTED FROM THE GROUP CONSISTING OF AMMONIC AND FLUOBORIC IONS, ELECTROLYTICALLY DEPOSITING THE SILVER COMPOUND ON A CATHODE, AND CONCURRENTLY REMOVING THE DEPOSITED SILVER FROM SAID CATHODE WHEREBY THE REMOVED SILVER HAS A SIZE OF LESS THAN 1500 A.

公开(公告)号：KR820000689B1

公开(公告)日：1982-04-28

申请号：KR790001954

申请日：1979-06-15

Applicant: SNAM PROGETTI

Inventor： FOTTORE V ,  MANARA G ,  NOTARI B ,  TARMASSO M

IPC: C07C1/00

Abstract: Me2 in good to excellent yields over cryst. SiO2 catalysts contg. 1 or more oxides of amphoteric elements Cr, Be, Ti, V, Mn, Fe, Co, Zn, Zr, Rh, Ag, Sn, Sb or B and/or optionally Al2O3, in their crystal lattices. Thus, a mixt. of (EtO)4Si and Cr (NO3)3 hydrolyzed and calcined gave a catalyst contg. 90.5 wt.% SiO2 and 6.0 wt.% Cr2O3, with sp. surface 300m2/g. Methyl-t-butylether passed over this catalyst at 13.3 LHSV, 270oC and 6 bar was 97.8% converted with 99.5% selectively to CH2:CMe2.

公开(公告)号：KR820001276B1

公开(公告)日：1982-07-19

申请号：KR750002468

申请日：1975-11-13

Applicant: SNAM PROGETTI

Inventor： FATTORE V ,  MANARA G ,  NOTARI B

IPC: B01J33/00 ,  C07C41/09

Abstract: The dehydration of aliph. alcs. to the resp. ethers at 200-400≦̸C was catalyzed by WSiXYZ [W, X, Y, and Z are R (R = hydrogen, methyl, ethyl, isopropyl, n-propyl, n-buthyl, isobuthyl, cyclohexyl, cyclopentyl, phenyl, phenylcyclohexylalkylphenyl), OR, Cl, Br, SiH3, COOR, SiHnClm(n and m are 1-3) Thus, MeOH was contacted with (EtO)4Si/Al2O3 at 300≦̸C to give Me2O.

公开(公告)号：KR800001030B1

公开(公告)日：1980-09-26

申请号：KR770002917

申请日：1977-12-14

Applicant: SNAM PROGETTI

Inventor： NOTARI B ,  MANARA G ,  FWATORE V

IPC: B01J21/12

Abstract: Me2O was prepd. in high conversion and yield by hydrogenation of CO over Si compd. stabilized catalysts contg. Al, Cr, Ta, Mn, Cu, and/or Zn at 300-330≦̸C, 50-100 kg/cm2, and space velocity 1,000-10,000/h. Thus, passing 3:1 H- CO over a Cu-Zn-Cr catalyst on stabilized Al2O3 at 300≦̸C, 50kg/cm2, and space velocity 3,500/h gave CO conversion 56% and selectivity for Me2O 61.3, MeOH 3.3, and CO2 35.4%

公开(公告)号：KR800000972B1

公开(公告)日：1980-09-17

申请号：KR750000811

申请日：1975-04-17

Applicant: SNAM PROGETTI

Inventor： NOTARI B ,  RIVOLA L

IPC: C01F7/56

Abstract: Compds. of formula Al2(OH)2Cly, where X is 1-4 and Y is 5-2, are made by reaction Al2O3 or Al(OH)3 at 160-270≦̸C under pressure with 30-7% HCl in an amt. equiv. to Al2(OH)3Cl3. In an example, Al2O33H2O 50 and 33% HCl 110kg were placed in an autoclave under 0.5 atm. N, heated to 180≦̸C in 30 min, and held there for 4 hr. more, the final pressure being 8 atm. The product was a soln, of Al2(OH)3Cl3 with a density of 1.40 at 20≦̸C contg. 19.5% Al2O3 and 21% C at pH 0.9

公开(公告)号：KR790000503B1

公开(公告)日：1979-05-29

申请号：KR740004034

申请日：1974-11-11

Applicant: SNAM PROGETTI

Inventor： NOTARI B ,  BUONOMO F ,  FATTORE V

Abstract: The mechanical and thermal properties of aluminium oxides were improved by treating with a hydrozable Si compd. Aluminium oxides were dipped in Si compd. and heated in an inert atmosphere for reaction with Si compd. The products and excess Si compd. were removed by vaporization. The residual Si compd. was hydrolyzed by water vapor, and the hydrolyzed products in the vapor phase were removed.