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公开(公告)号:DE2059822A1
公开(公告)日:1971-09-09
申请号:DE2059822
申请日:1970-12-04
Applicant: SOLVAY
Inventor: PIERRE HERMANNS JEAN , LECLOUX ANDRE , VAN BOST JACQUES
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公开(公告)号:DE19616263A1
公开(公告)日:1997-10-30
申请号:DE19616263
申请日:1996-04-24
Applicant: SOLVAY DEUTSCHLAND
Inventor: GHISLAIN MICHAUX BERNARD , PIRARD JEAN-PAUL , LECLOUX ANDRE
IPC: B01J13/00 , C01B33/158 , C01B33/16 , C08G16/02 , C08J3/02
Abstract: In the production of aerogels and/or xerogels based on inorganic or organic gels by mixing a gel precursor (I) with an organic solvent, hydrolysis and converting the resultant gel into an aerogel or xerogel with carbon dioxide (CO2) under super-critical conditions, (I) is treated with an aprotic solvent (II) which is soluble in CO2.
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公开(公告)号:FR2578248B1
公开(公告)日:1988-11-18
申请号:FR8503175
申请日:1985-03-01
Applicant: SOLVAY
Inventor: HERMAN JEAN-JACQUES , LECLOUX ANDRE
IPC: C07B43/00 , B01J27/00 , B01J31/00 , C07B31/00 , C07B61/00 , C07C67/00 , C07C231/00 , C07C231/10 , C07C239/00 , C07C269/00 , C07C269/04 , C07C273/02 , C07C273/18 , C07C275/28 , C07D295/18 , C07C102/00 , C07C125/00 , C07C126/00 , C08G71/00
Abstract: Process for the catalytic synthesis of nitrogen-containing organic compounds, comprising the reaction of carbon monoxide with at least one amino compound in a reaction mixture containing a catalyst based on selenium and a substituted pyridine. The process is particularly suitable for the synthesis of ureas and of their polymers.
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公开(公告)号:FR2578248A1
公开(公告)日:1986-09-05
申请号:FR8503175
申请日:1985-03-01
Applicant: SOLVAY
Inventor: HERMAN JEAN-JACQUES , LECLOUX ANDRE
IPC: C07B43/00 , B01J27/00 , B01J31/00 , C07B31/00 , C07B61/00 , C07C67/00 , C07C231/00 , C07C231/10 , C07C239/00 , C07C269/00 , C07C269/04 , C07C273/02 , C07C273/18 , C07C275/28 , C07D295/18 , C07C102/00 , C07C125/00 , C07C126/00 , C08G71/00
Abstract: Process for the catalytic synthesis of nitrogen-containing organic compounds, comprising the reaction of carbon monoxide with at least one amino compound in a reaction mixture containing a catalyst based on selenium and a substituted pyridine. The process is particularly suitable for the synthesis of ureas and of their polymers.
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公开(公告)号:FR2540102A1
公开(公告)日:1984-08-03
申请号:FR8301837
申请日:1983-02-02
Applicant: SOLVAY
Inventor: LECLOUX ANDRE , LEGRAND FRANZ
IPC: B01J21/00 , B01J21/04 , C07C29/48 , B01J23/00 , B01J23/50 , C07B61/00 , C07C27/00 , C07C29/64 , C07C31/38 , C07C31/40 , C07C67/00
Abstract: 2,2,2-Trifluoroethanol is obtained by catalytic oxidation of 1,1-difluoroethylene. The 2,2,2-trifluoroethanol thus obtained is used as a solvent or as a synthesis intermediate.
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公开(公告)号:DE2748210A1
公开(公告)日:1978-05-11
申请号:DE2748210
申请日:1977-10-27
Applicant: SOLVAY
Inventor: LECLOUX ANDRE , GOBILLON YVES DR
IPC: B22F9/20 , B01J23/56 , B01J23/66 , B01J23/89 , C07B61/00 , C07C5/32 , C10G35/09 , C22C1/00 , C22C5/02 , C22C5/04 , C22C5/06 , C22C9/00 , C22C12/00 , C22C18/00 , C22C19/00 , C22C27/00 , C22C5/00 , B01J23/40
Abstract: Particles of alloys of a noble metal chosen from among iridium, osmium, palladium, platinum, rhodium and ruthenium, hereafter represented by M, with at least one non-noble metal chosen among silver, bismuth, cadmium, cobalt, copper, tin, germanium, indium, manganese, mercury, molybdenum, nickel, gold, lead, rhenium, thallium, tellurium, technetium, tungsten, vanadium and zinc, hereafter referred to as Me', and Me', representing at least one non-noble metal, characterized in that they correspond to the general formula MnMe'm where n represents an integer equal to 1, 2 or 3 and where m represents an integer equal to 1, 2 or 3, and in that their specific surface area is between 0.5 and 800 m2/g of alloy and in that the mean diameter of the alloy particles is between 10 and 10,000 A. The particles are prepared by reducing the mixed oxides of the corresponding formula MnMe'mOx They are used as catalyst for dehydrogenation or hydrogenation.
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公开(公告)号:DE3462881D1
公开(公告)日:1987-05-07
申请号:DE3462881
申请日:1984-01-23
Applicant: SOLVAY
Inventor: LECLOUX ANDRE , LEGRAND FRANZ
IPC: C07C29/48 , B01J21/00 , B01J21/04 , B01J23/00 , B01J23/50 , C07B61/00 , C07C27/00 , C07C29/64 , C07C31/38 , C07C31/40 , C07C67/00
Abstract: 2,2,2-Trifluoroethanol is obtained by catalytic oxidation of 1,1-difluoroethylene. The 2,2,2-trifluoroethanol thus obtained is used as a solvent or as a synthesis intermediate.
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公开(公告)号:CH596321A5
公开(公告)日:1978-03-15
申请号:CH1248074
申请日:1974-09-13
Applicant: SOLVAY
Inventor: TYTGAT DANIEL , LECLOUX ANDRE , DEGUELDRE LOUIS
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公开(公告)号:AU2260470A
公开(公告)日:1972-05-25
申请号:AU2260470
申请日:1970-11-24
Applicant: SOLVAY
Inventor: HERMANS JEAN PIERRE , LECLOUX ANDRE , BOST JACQUES VAN
Abstract: 1301399 Polymerization catalyst SOLVAY & CIE 16 Dec 1970 [17ÀDec 1969] 59712/70 Heading C3P A Ziegler-Natta type catalyst is prepared by reducing liquid TiCl 4 , TiBr 4 or VCl 4 with a liquid organometallic compound of a metal of Groups I to III in the presence of a porous inert support, separating and (if required) heating the product, then activating the resulting supported reduced halide with an organometallic compound of a metal of Groups I to III. The reduction is carried out by first impregnating the support with one reatant then adding it to the second reactant which is in the form of a pure liquid or a solution, the non-supported reactant being used in excess if it is a pure liquid and either in excess or in the stoichiometric proportion if it is in solution. The use of Al 2 O 3 , TiO 2 and MgO as support materials is described; the supports are in the form of rounded bodies of diameter 50-250 Á composed of agglomerated particles, the individual particles having diameter 0À2-2 Á. Bulk polymerization of propylene and copolymerization of ethylene and propylene in liquid propylene are described, using catalysts derived from TiCl 4 , reduced with Et 3 Al, (i-Bu) 3 Al or Et 2 AlCl and activated with Et 2 AlCl.
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