公开(公告)号：JPH05158089A

公开(公告)日：1993-06-25

申请号：JP31934491

申请日：1991-12-03

Applicant: SONY CORP

Inventor： BOON HAWAASU ,  FUJIWARA ICHIRO ,  ASAI NOBUTOSHI ,  KISHII NORIYUKI ,  TAMURA SHINICHIRO

IPC: C09K9/02 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361

Abstract: PURPOSE:To stably transfer a monomolecular film on a substrate as a film and to stably form a Langmuir-Blodgett(LB) film by using an org. thin film in which monomolecular layers contg. a specified compd. are laminated in plural layers. CONSTITUTION:This org. nonlinear optical material is shown by the formula where 20

公开(公告)号：JPH06138502A

公开(公告)日：1994-05-20

申请号：JP26238092

申请日：1992-09-30

Applicant: SONY CORP

Inventor： ASAI NOBUTOSHI ,  TAMADA HITOSHI ,  FUJIWARA ICHIRO ,  BOON HAWAASU ,  ISHIBASHI TADASHI

IPC: G02F1/35 ,  G02F1/37

Abstract: PURPOSE:To provide the wavelength conversion element which is greatly improved in second harmonic wave conversion efficiency by introducing the insertion structure of a nonlinear optical sensitivity into an active layer. CONSTITUTION:The wavelength conversion element formed with a light propagating part as an optical wavelength shape is constituted by disposing a nonlinear optical material unified in the code of the nonlinear optical sensitivity in a prescribed direction-and a nonlinear optical material inverted or changed with the code of the nonlinear optical sensitivity on a substrate 1 to form an active layer 2. A clad layer 3 consisting of an org. material having the refractive index smaller than the refractive index of the substrate 1 is laminated on the active layer 2, by which the wavelength conversion element is constituted.

公开(公告)号：JPH0588223A

公开(公告)日：1993-04-09

申请号：JP27861291

申请日：1991-09-30

Applicant: SONY CORP

Inventor： KISHII NORIYUKI ,  ASAI NOBUTOSHI ,  TAMURA SHINICHIRO ,  BOON HAWAASU ,  FUJIWARA ICHIRO

IPC: C09K9/02 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361

Abstract: PURPOSE:To obtain the excellent nonlinear optical characteristics rapid in response by converting 3-methyl-4-aniline (MNA) substituted by a >=19C on the amino group unto built-up molecular films by the Langmuir-Blodgett's method (LB method) to form a waveguide. CONSTITUTION:The organic nonlinear optical material us represented by formula I and the built-up molecular films (LB) films are laminated on a substrate, and it us the MNA alkyl chain derivative made by substituting >=19C long alkyl on the amino group. It is important to increase the carbon number to >=19 to execute the LB method, thus permitting the balance between the hydrophilicness and hydrophobicness of the MNA to be improved and facilitated for building up molecular films as the LB films. If the carbon number is smaller than 19, hydrophobicness becomes insufficient and difficult to laminate such films.