公开(公告)号：YU34387B

公开(公告)日：1979-07-10

申请号：YU304268

申请日：1968-12-20

Applicant: STANDARD OIL CO OHIO

Inventor： KARL GRASSELLI ROBERT ,  GRASSELLI ROBERT KARL ,  STRADA FRIEDRICH MARIS ,  FRIEDRICH MARIS STRADA ,  GARSIDE SHAW WILFRID ,  SHAW WILFRID GARSIDE ,  FOCH HARDMAN HARLEY ,  HARDMAN HARLEY FOCH

IPC: B01J21/08 ,  B01J23/00 ,  B01J23/18 ,  B01J23/28 ,  B01J23/31 ,  B01J23/84 ,  B01J23/88 ,  B01J23/887 ,  B01J37/02 ,  B01J37/04 ,  C07C5/48 ,  C07C45/35 ,  C22B41/00 ,  C07C3/00

公开(公告)号：DE1958290A1

公开(公告)日：1970-07-16

申请号：DE1958290

申请日：1969-11-20

Applicant: STANDARD OIL CO

Inventor： KARL GRASSELLI ROBERT ,  FOCH HARDMAN HARLEY

IPC: B01J23/88 ,  B01J23/887 ,  B01J27/192 ,  C07B61/00 ,  C07C1/00 ,  C07C1/20 ,  C07C5/48 ,  C07C11/12 ,  C07C67/00 ,  H01H3/40 ,  C07C5/18

Abstract: 1284464 Oxidation catalyst STANDARD OIL CO 12 Nov 1969 [30 Dec 1968 20 Oct 1969] 55385/69 Heading B1E [Also in Division C5] A catalyst composition consisting of a calcined catalytic oxide complex of an alkali metal, bismuth, iron, molybdenum and optionally oxides of alkaline earth metals, phosphorus, arsenic, antimony, cobalt, or nickel, has the formula wherein Q is an alkali metal, R is an alkaline earth metal, T is phosphorus, arsenic and/or antimony, m is cobalt and/or nickel; and a, b and c are 0.1 to 12, d is 0.1 to 8, e is 0 to 8, f is 0 to 6, g is 0 to 12 and x is number determined by the valence requirements of the other elements present. The catalyst may optionally be supported, specified carriers being alumina, pumice, silicon carbide, zirconia, titania, silica, alumina-silica, and the inorganic phosphates, silicates, aluminates, borates and carbonates. The composition is activated by calcining 500‹F to 1250‹F for 2 to 24 hours, optionally followed by further activation comprising heat treating at above 800‹F, e.g. at 800-1400‹F for 1 to 48 hours, in the presence of an oxygen containing gas.

公开(公告)号：DE1808990A1

公开(公告)日：1969-07-03

申请号：DE1808990

申请日：1968-11-15

Applicant: STANDARD OIL CO

Inventor： KARL GRASSELLI ROBERT ,  STRADA FRIEDRICH MARIA ,  GARSIDE SHAW WILFRID ,  FOCH HARDMAN HARLEY

IPC: C07C47/22 ,  B01J21/08 ,  B01J23/00 ,  B01J23/16 ,  B01J23/18 ,  B01J23/28 ,  B01J23/31 ,  B01J23/84 ,  B01J23/843 ,  B01J23/88 ,  B01J23/887 ,  B01J37/02 ,  B01J37/04 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C11/12 ,  C07C45/00 ,  C07C45/34 ,  C07C51/25 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C22B41/00 ,  B01J11/46