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公开(公告)号：KR830000022A
公开(公告)日：1983-03-25
申请号：KR780002329
申请日：1978-07-28
Applicant: STANDARD OIL CO
Inventor： GUTTMANN ANDREW TYTUS , GRASSELLI ROBERT KARL
IPC: C07C47/20
Abstract: Unsaturated aldehydes and acids was prepared by the oxidation of olefins at 200-400≦̸C in the presence of catalyst, K0.1Ni2.5Co4.5Mo12Ox (X = the no. required to satisfy stoichiometry) and a promoter Fe2LZ0.5 (L = Cr, Sb, Ce, Pb, Ge, S Sn), or Mg7.5Fe3Z0.5 (Z = p,w). Using Fe2CrW0.5 as the promoter at 350≦̸C, conversion yield of acrolein and acrylic acid was 80.4 % and 77 %, resp.
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公开(公告)号：JPS59112939A
公开(公告)日：1984-06-29
申请号：JP22365582
申请日：1982-12-20
Applicant: Standard Oil Co Ohio
Inventor： GRASSELLI ROBERT KARL , GUTTMANN ANDREW TYTUS
IPC: C07C67/317 , B01J23/00 , C07B61/00 , C07C51/00 , C07C51/353 , C07C51/377 , C07C57/04 , C07C67/00 , C07C69/54
CPC classification number: C07C51/353 , C07C57/04
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公开(公告)号：NO151083B
公开(公告)日：1984-10-29
申请号：NO782583
申请日：1978-07-27
Applicant: STANDARD OIL CO OHIO
Inventor： GUTTMANN ANDREW TYTUS , GRASSELLI ROBERT KARL
IPC: B01J23/88 , B01J23/89 , B01J27/057 , B01J27/186 , C07C45/35 , C07C51/25 , C07C47/22 , C07C27/14 , C07C57/05
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公开(公告)号：ATA551778A
公开(公告)日：1980-03-15
申请号：AT551778
申请日：1978-07-28
Applicant: STANDARD OIL CO OHIO
Inventor： GUTTMANN ANDREW TYTUS , GRASSELLI ROBERT KARL
IPC: B01J23/88 , B01J23/89 , B01J27/057 , B01J27/186 , C07C45/35 , C07C51/25 , C07C47/22 , C07C27/14 , C07C57/05
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公开(公告)号：FR2393786A1
公开(公告)日：1979-01-05
申请号：FR7816230
申请日：1978-05-31
Applicant: STANDARD OIL CO
Inventor： GUTTMANN ANDREW TYTUS , CALLAHAN JAMES LOUIS , GRASSELLI ROBERT KARL
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Patent Agency Ranking
公开(公告)号：DE2726267A1
公开(公告)日：1978-12-21
申请号：DE2726267
申请日：1977-06-10
Applicant: STANDARD OIL CO OHIO
Inventor： GUTTMANN ANDREW TYTUS , GRASSELLI ROBERT KARL
Abstract: Prepn. of ethers (I) comprises liquid phase reaction of a tert. olefin of formula RCH=CR'2 (II) (R = H or alkyl, R' = alkyl) with methanol in the presence of a homogeneous catalyst (III) free from heteropolyacid. (III) has formula HnAaDcOy.xH2O (A is P, B, Si, Ge, Sn, As, Sb, U, Mn, Re, Cu, Ni, Co, Fe, Ce, Th and/or Cr. D is Mo, W and/or V. a = 0.1-10, c = 6-18. n = 1 and is the no. of acidic H atoms in the catalyst. y = 10-70 and x = 0-40). Pref. A is P, Si or Ge, specifically (III) is H4SiMo12O40. - xH2O. Process avoids the corrosion problems associated with strong acid catalysts and minimises the amt. of by-product CH3OCH3 formed. In an example reaction of isobutylene and methanol over the specified catalyst at mole ratio 1:4 gave 81.5% isobutylene conversion and 100% selectivity for methyl tert. butyl ether.
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公开(公告)号：MX159552A
公开(公告)日：1989-07-03
申请号：MX19065881
申请日：1981-12-15
Applicant: STANDARD OIL CO OHIO
Inventor： GUTTMANN ANDREW TYTUS , GRASSELLI ROBERT KARL
IPC: C07C69/52 , B01J27/00 , C07B61/00 , C07C51/00 , C07C51/353 , C07C57/04 , C07C67/00 , C07C69/54 , C07C67/343
Abstract: Promoted phosphate catalysts have been found to be effective for the vapor phase condensation of saturated monocarboxylic acids or esters with formaldehyde, to produce unsaturated carboxylic acids or esters.
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公开(公告)号：AT359055B
公开(公告)日：1980-10-27
申请号：AT551778
申请日：1978-07-28
Applicant: STANDARD OIL CO OHIO
Inventor： GUTTMANN ANDREW TYTUS , GRASSELLI ROBERT KARL
IPC: B01J23/88 , B01J23/89 , B01J27/057 , B01J27/186 , C07C45/35 , C07C51/25 , C07C47/22 , C07C27/14 , C07C57/05
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公开(公告)号：AU3301778A
公开(公告)日：1979-08-16
申请号：AU3301778
申请日：1978-02-06
Applicant: STANDARD OIL CO
Inventor： GUTTMANN ANDREW TYTUS , GRASSELLI ROBERT KARL , CALLAHAN JAMES LOUIS
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公开(公告)号：ATA112378A
公开(公告)日：1979-05-15
申请号：AT112378
申请日：1978-02-16
Applicant: STANDARD OIL CO OHIO
Inventor： GUTTMANN ANDREW TYTUS , CALLAHAN JAMES LOUIS , GRASSELLI ROBERT KARL
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