公开(公告)号：KR840000088B1

公开(公告)日：1984-02-10

申请号：KR790004686

申请日：1979-12-29

Applicant: STANDARD OIL CO

Inventor： HOFF GLEN RICHARD ,  FOTIS PETER

IPC: C08F10/00 ,  C08F4/02

Abstract: A highly active catalyst for polymerization of α-olefins is composed of an organic metal promotor, at least one of IVb, Vb, or VIb metal compd. (I), 2+ metal salt of phosphoric ester (II) contg. at least one of phosphoric ester gp. combined with metals through O or S, and hydrocarbon non-soluble solid composition produced by reaction of at least on of alkyl aluminum halide. The atomic ratio of metals of (II) to (I) is about 0.05:1˜10:1 and an effective amt. of alkyl aluminum halide is used to halogenize metals of (I) and (II)

公开(公告)号：IN153463B

公开(公告)日：1984-07-21

申请号：IN895DE1979

申请日：1979-12-14

Applicant: STANDARD OIL CO

Inventor： HOFF GLEN RICHARD ,  FOTIS PETER

IPC: C08F10/00 ,  B01J11/00

公开(公告)号：MX149390A

公开(公告)日：1983-11-01

申请号：MX17567378

申请日：1978-11-17

Applicant: STANDARD OIL CO

Inventor： HOFF GLEN RICHARD ,  MELQUIST JOHN LESLIE ,  FOTIS PETER

IPC: B01J8/10 ,  B01J8/36 ,  B01J8/38 ,  B01J19/18 ,  C08F2/00 ,  C08F2/34 ,  C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00

Abstract: Vapor phase polymerization of an olefin which comprises conveying inactive high yield titanium catalyst component to a vapor phase polymerization reactor with a liquid comprising recycled quench liquid, reactivating said inactive high yield titanium catalyst component inside the reactor with a metal alkyl reducing agent and polymerizing olefin under gas phase polymerization conditions with reactivated high yield catalyst to form a resinous polymer of an olefin having a low level of catalyst residues.

公开(公告)号：DE2850335A1

公开(公告)日：1979-05-31

申请号：DE2850335

申请日：1978-11-20

Applicant: STANDARD OIL CO

Inventor： HOFF GLEN RICHARD ,  MELQUIST JOHN LESLIE ,  NAPERVILLE ILL ,  FOTIS PETER

IPC: B01J8/10 ,  B01J8/36 ,  B01J8/38 ,  B01J19/18 ,  C08F2/00 ,  C08F2/34 ,  C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00

Abstract: Vapor phase polymerization of an olefin which comprises conveying inactive high yield titanium catalyst component to a vapor phase polymerization reactor with a liquid comprising recycled quench liquid, reactivating said inactive high yield titanium catalyst component inside the reactor with a metal alkyl reducing agent and polymerizing olefin under gas phase polymerization conditions with reactivated high yield catalyst to form a resinous polymer of an olefin having a low level of catalyst residues.

公开(公告)号：DE2967293D1

公开(公告)日：1984-12-13

申请号：DE2967293

申请日：1979-12-17

Applicant: STANDARD OIL CO

Inventor： HOFF GLEN RICHARD ,  FOTIS PETER

IPC: C08F10/00 ,  C07F9/02 ,  C08F4/62

公开(公告)号：RO84440B

公开(公告)日：1984-11-30

申请号：RO10002280

申请日：1980-01-30

Applicant: STANDARD OIL CO

Inventor： HOFF GLEN RICHARD ,  FOTIS PETER

IPC: C08F2/06 ,  C08F4/76

Abstract: Inventia se refera la un procedeu de polimerizare a alfa-olefinelor, care are loc la o temperatura de 40...210 degree C si la o presiune de 7...70 kgf/cm2, în solutie, suspensie sau în faza gazoasa, eventual, în prezenta hidrogenului, pentru reglarea greutatii moleculare în prezenta unui catalizator, format dinmtr-o componenta (A) constînd dintr-un promotor organo-metalic, ales dintre alchil, hidruri, alchilhidruri si alchilhalogenuri ale metalelor din grupele Ia, II a, IIb, IIIa, si IVa, a sistemului periodic si un suport (B) insolubil în hidrocarburi. Procedeul conform inventiei permite sa se obtina poliolefine avînd greutati moleculare cuprinse între 50000 si 3000000 cu randamente mari, eliminîndu-se faza de separare a reziduriilor de catalizator.

公开(公告)号：PH16531A

公开(公告)日：1983-11-10

申请号：PH23473

申请日：1980-01-02

Applicant: STANDARD OIL CO

Inventor： HOFF GLEN RICHARD ,  FOTIS PETER

IPC: C08F4/00