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公开(公告)号：CA2124049C
公开(公告)日：2005-11-15
申请号：CA2124049
申请日：1994-05-20
Applicant: TEXACO DEVELOPMENT CORP
Inventor： LEININGER THOMAS FREDERICK , ROBIN ALLEN MAURICE , WOLFENBARGER JAMES KENNETH , SUGGITT ROBERT MURRAY
Abstract: A partial oxidation process for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H2, CO, CO2, H2O, CH4 NH3, HCl, HF, H2S, COS, N2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N2 and H2. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000.degree.F.
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公开(公告)号：DE69415872T2
公开(公告)日：1999-06-10
申请号：DE69415872
申请日：1994-06-02
Applicant: TEXACO DEVELOPMENT CORP
Abstract: The process produces a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A solid carbonaceous fuel with or without liquid or gaseous hydrocarbonaceous fuel and containing halides, alkali metal compounds, sulfur, nitrogen and inorganic ash, is reacted by partial oxidation to produce a hot raw gas stream comprising H2, CO, CO2, H2O, CH4, NH3, HCl, HF, H2S, COS, N2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N2 and H2. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 540 DEG C.
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公开(公告)号：DE69101970T2
公开(公告)日：1994-08-18
申请号：DE69101970
申请日：1991-02-26
Applicant: TEXACO DEVELOPMENT CORP
Inventor： LEININGER THOMAS FREDERICK , CARY RICHARD DENNIS , ZACHARIOU GUS
Abstract: An apparatus for measuring temperatures inside enclosures or conduits containing hot gases laden with entrained solids using a pyrometer (1), utilizing an optical access port consisting of a high strength sight tube (7), a safety valve (5), a double sight glass (21,22), various purge connections (35-37) and provisions for optical alignment. A dynamic purge system keeps the optical sight path clear during normal operation, and clears the path if it begins to become occluded during operational upsets within the enclosure or conduit. The optical access port is mounted on the exterior wall of the vessel or conduit (8).
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公开(公告)号：ZA9101291B
公开(公告)日：1992-07-29
申请号：ZA9101291
申请日：1991-02-21
Applicant: TEXACO DEVELOPMENT CORP
Inventor： LEININGER THOMAS FREDERICK , THOMAS FREDERICK LEININGER , CARY RICHARD DENNIS , RICHARD DENNIS CARY , ZACHARIOU GUS , GUS ZACHARIOU
IPC: G01J20060101 , G01J
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公开(公告)号：DE3887884D1
公开(公告)日：1994-03-24
申请号：DE3887884
申请日：1988-09-02
Applicant: TEXACO DEVELOPMENT CORP
Inventor： NAJJAR MITRI SALIM , LEININGER THOMAS FREDERICK
IPC: G01K1/10
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Patent Agency Ranking
公开(公告)号：DK501088A
公开(公告)日：1990-03-10
申请号：DK501088
申请日：1988-09-09
Applicant: TEXACO DEVELOPMENT CORP
Inventor： NAJJAR MITRI SALIM , LEININGER THOMAS FREDERICK
Abstract: A thermocouple-based temperature monitoring device for use in a high temperature reactor, wherein a carbonaceous fuel is burned to produce a usable gas and a residual slag. The thermocouple wires 26, 27 are enclosed in a gas- tight metal protection sheath 29 which is inserted inside a multi-segment refractory thermal well 32. An annular space 38 formed between the sheath and the thermal well is continuously purged with a small quantity of a gas or a gaseous mixture. Gasification products from the residual slag, which are normally in a form that reacts with and destroys the thermocouple wires, are neutralized within the annular space 38 by reaction with the purge gas mixture.
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公开(公告)号：ES2125409T3
公开(公告)日：1999-03-01
申请号：ES94303954
申请日：1994-06-02
Applicant: TEXACO DEVELOPMENT CORP
Inventor： LEININGER THOMAS FREDERICK , ROBIN ALLEN MAURICE , WOLFENBERGER JAMES KENNETH , SUGGITT ROBERT MURRAY
Abstract: The process produces a stream of hot clean gas substantially free from particulate matter, alkali metal compounds, hydrogen halides, hydrogen cyanide, sulfur-containing gases, and with or without ammonia for use as synthesis gas, reducing gas, or fuel gas. A pumpable fuel selected from liquid hydrocarbonaceous fuel or liquid emulsions thereof, an aqueous slurry of petroleum coke, and mixtures thereof and containing halides, alkali metal compounds, sulfur, nitrogen and inorganic ash, it reacted by partial oxidation to produce a hot raw gas stream comprising H2, CO, CO2, H2O, CH4, NH3, HCN, HC1, HF, H2S, COS, N2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream is cooled and cleaned. Optionally, ammonia is removed by being catalytically disproportionated into N2 and H2. The process gas stream is cooled and halides and HCN in the gas stream are reacted with a supplementary alkali metal compound to remove HC1, HF and HCN. Alkali metal halides and alkali metal cyanide, vaporized alkali metal compounds and residual fine particulate matter are removed by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 540 DEG C.
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公开(公告)号：DK0501049T3
公开(公告)日：1994-06-13
申请号：DK91301514
申请日：1991-02-26
Applicant: TEXACO DEVELOPMENT CORP
Inventor： LEININGER THOMAS FREDERICK , CARY RICHARD DENNIS , ZACHARIOU GUS
Abstract: An apparatus for measuring temperatures inside enclosures or conduits containing hot gases laden with entrained solids using a pyrometer (1), utilizing an optical access port consisting of a high strength sight tube (7), a safety valve (5), a double sight glass (21,22), various purge connections (35-37) and provisions for optical alignment. A dynamic purge system keeps the optical sight path clear during normal operation, and clears the path if it begins to become occluded during operational upsets within the enclosure or conduit. The optical access port is mounted on the exterior wall of the vessel or conduit (8).
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公开(公告)号：DE3887884T2
公开(公告)日：1994-05-19
申请号：DE3887884
申请日：1988-09-02
Applicant: TEXACO DEVELOPMENT CORP
Inventor： NAJJAR MITRI SALIM , LEININGER THOMAS FREDERICK
IPC: G01K1/10
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公开(公告)号：DE69415728T2
公开(公告)日：1999-06-10
申请号：DE69415728
申请日：1994-06-02
Applicant: TEXACO DEVELOPMENT CORP
Inventor： LEININGER THOMAS FREDERICK , ROBIN ALLEN MAURICE , WOLFENBERGER JAMES KENNETH , SUGGITT ROBERT MURRAY
Abstract: The process produces a stream of hot clean gas substantially free from particulate matter, alkali metal compounds, hydrogen halides, hydrogen cyanide, sulfur-containing gases, and with or without ammonia for use as synthesis gas, reducing gas, or fuel gas. A pumpable fuel selected from liquid hydrocarbonaceous fuel or liquid emulsions thereof, an aqueous slurry of petroleum coke, and mixtures thereof and containing halides, alkali metal compounds, sulfur, nitrogen and inorganic ash, it reacted by partial oxidation to produce a hot raw gas stream comprising H2, CO, CO2, H2O, CH4, NH3, HCN, HC1, HF, H2S, COS, N2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream is cooled and cleaned. Optionally, ammonia is removed by being catalytically disproportionated into N2 and H2. The process gas stream is cooled and halides and HCN in the gas stream are reacted with a supplementary alkali metal compound to remove HC1, HF and HCN. Alkali metal halides and alkali metal cyanide, vaporized alkali metal compounds and residual fine particulate matter are removed by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 540 DEG C.
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