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公开(公告)号：WO2013155400A3
公开(公告)日：2014-06-12
申请号：PCT/US2013036350
申请日：2013-04-12
Applicant: TICONA LLC
Inventor： LUO RONG , ZHAO XINYU , GRENCI JOSEPH J
CPC classification number: C08L81/04 , B32B1/08 , B32B27/286 , B32B2307/3065 , B32B2307/54 , B32B2307/546 , B32B2307/558 , B32B2307/7242 , B32B2307/7265 , B32B2439/40 , B32B2597/00 , B32B2605/08 , B60K15/03177 , B60K15/04 , B60K2015/03039 , B60K2015/0458 , C08L63/00 , C08L2205/06 , C08L2207/04 , Y10T428/1352 , Y10T428/139 , Y10T428/1393
Abstract: Components formed of blow molded thermoplastic compositions are described. The blow molded thermoplastic compositions exhibit high strength and flexibility. Methods for forming the thermoplastic compositions are also described. Formation methods include dynamic vulcanization of a composition that includes an impact modifier dispersed throughout a polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier. The crosslinking agent reacts with the impact modifier to form crosslinks within and among the polymer chains of the impact modifier. The compositions can exhibit excellent physical characteristics at extreme temperatures and can be used to form, e.g., tubular member such as pipes and hoses and fibers.
Abstract translation: 描述了由吹塑热塑性组合物形成的组分。 吹塑成型的热塑性组合物显示出高强度和柔韧性。 还描述了形成热塑性组合物的方法。 形成方法包括动态硫化包含分散在聚芳硫醚中的抗冲改性剂的组合物。 交联剂与抗冲改性剂分散后的组合物的其它成分组合。 交联剂与抗冲改性剂反应以在抗冲改性剂的聚合物链内和之间形成交联。 组合物可以在极端温度下表现出优异的物理特性，并且可用于形成例如管状构件，例如管道，软管和纤维。
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公开(公告)号：WO2013155389A3
公开(公告)日：2014-06-05
申请号：PCT/US2013036333
申请日：2013-04-12
Applicant: TICONA LLC
Inventor： LUO RONG , ZHAO XINYU , GRENCI JOSEPH J , MCGRADY CHRISTOPHER
CPC classification number: C08L81/02 , B29C47/0004 , B29C47/0016 , B29C47/0023 , B29C47/1018 , B29C47/8805 , B29K2081/04 , B29K2105/0005 , B32B1/08 , B32B27/20 , B32B27/286 , B32B2307/558 , B32B2307/7265 , B32B2597/00 , B65D1/0215 , B65D25/14 , B65D31/04 , C08L81/04 , C08L2203/10 , C08L2203/12 , C08L2203/202 , F16L9/133 , F16L9/147 , F16L11/00 , F16L57/04 , F16L57/06 , F16L58/04 , F27B14/00 , Y10T428/1352 , Y10T428/1393 , Y10T428/1397 , Y10T428/2958
Abstract: Polyarylene sulfide compositions are described that exhibit high strength and flexibility. Methods for forming the polyarylene sulfide compositions are also described. Formation methods include dynamic vulcanization of a polyarylene sulfide composition that includes an impact modifier dispersed throughout the polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier throughout the composition. The crosslinking agent reacts with the impact modifier to form crosslinks within and among the polymer chains of the impact modifier. The compositions can exhibit excellent physical characteristics at extreme temperatures and can be used to form, e.g., tubular member such as pipes and hoses and fibers.
Abstract translation: 描述了具有高强度和柔韧性的聚芳硫醚组合物。 还描述了形成聚芳硫醚组合物的方法。 形成方法包括聚芳硫醚组合物的动态硫化，其包括分散在整个聚芳硫醚中的抗冲改性剂。 在整个组合物中将抗冲改性剂分散后，交联剂与组合物的其它组分组合。 交联剂与抗冲改性剂反应以在抗冲改性剂的聚合物链内和之间形成交联。 组合物可以在极端温度下表现出优异的物理特性，并且可用于形成例如管状构件，例如管道，软管和纤维。
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公开(公告)号：WO2013154741A3
公开(公告)日：2014-08-28
申请号：PCT/US2013031315
申请日：2013-03-14
Applicant: TICONA LLC
Inventor： LUO RONG , ZHAO XINYU , GRENCI JOSEPH J
Abstract: Components for automobiles are described that exhibit high strength and flexibility. The components are formed from a polyarylene sulfide that exhibits high strength and flexibility characteristics. Methods for forming the components are also described. Formation methods include dynamic vulcanization of a polyarylene sulfide composition that includes an impact modifier dispersed throughout the polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier throughout the composition. The automotive components can include tubular member such as pipes and hoses that can be utilized in exhaust systems, charge air systems, urea tanks, fuel systems, and so forth.
Abstract translation: 描述了表现出高强度和柔性的汽车零件。 这些组分由表现出高强度和柔性特性的聚芳硫醚形成。 还描述了用于形成组件的方法。 形成方法包括聚芳硫醚组合物的动态硫化，其包括分散在整个聚芳硫醚中的抗冲改性剂。 在整个组合物中将抗冲改性剂分散后，交联剂与组合物的其它组分组合。 汽车部件可以包括可用于排气系统，增压空气系统，尿素罐，燃料系统等的管状构件，例如管道和软管。
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公开(公告)号：WO2013155393A3
公开(公告)日：2014-07-10
申请号：PCT/US2013036339
申请日：2013-04-12
Applicant: TICONA LLC
Inventor： FENG KE , LUO RONG , ZHAO XINYU
IPC: C08L81/02
CPC classification number: C09K21/14 , D01F1/106 , D01F6/765 , D01G15/00 , Y10T428/139 , Y10T428/2904 , Y10T428/298 , Y10T442/3089 , Y10T442/609
Abstract: Disclosed is a UV stabilized polyarylene sulfide composition, methods of forming the composition, and UV stabilized products that can be formed of the composition. The UV stabilized polyarylene sulfide composition can include a reactively functionalized polyarylene sulfide polymer in conjunction with a UV stabilizer. The reactivity of the polyarylene sulfide polymer is formed during melt processing via reaction of a reactively functionalized disulfide compound with a starting polyarylene sulfide. The reactivity of the polyarylene sulfide can encourage interaction between the polyarylene sulfide polymer and the UV stabilizer, which can improve dispersion of the UV stabilizer throughout the composition and improve miscibility between the polyarylene sulfide polymer and the UV stabilizer. Products can incorporate high concentrations of UV stabilizer and/or can be formed to very small cross sectional dimensions without phase separation between the UV stabilizer and the polyarylene sulfide.
Abstract translation: 公开了一种紫外线稳定化的聚芳硫醚组合物，形成组合物的方法和可以由该组合物形成的UV稳定化产物。 UV稳定化聚芳硫醚组合物可以包括与UV稳定剂结合的反应性官能化聚芳硫醚聚合物。 通过反应性官能化的二硫化物化合物与起始聚芳硫醚的反应，在熔融加工过程中形成聚芳硫醚聚合物的反应性。 聚芳硫醚的反应性可以促进聚芳硫醚聚合物和UV稳定剂之间的相互作用，这可以改善UV稳定剂在整个组合物中的分散，并改善聚芳硫醚聚合物和UV稳定剂之间的混溶性。 产品可以掺入高浓度的UV稳定剂和/或可形成非常小的横截面尺寸，而不会在UV稳定剂和聚芳硫醚之间相分离。
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公开(公告)号：WO2013155516A3
公开(公告)日：2014-06-26
申请号：PCT/US2013036577
申请日：2013-04-15
Applicant: TICONA LLC
Inventor： RUBY MICHAEL A , EASTEP DAVID W , JOHNSON AARON H , LUO RONG , ZHAO XINYU , GRENCI JOSEPH J , MCGRADY CHRISTOPHER
CPC classification number: C08L81/02 , B29C47/0004 , B29C47/0016 , B29C47/0023 , B29C47/1018 , B29C47/8805 , B29K2081/04 , B29K2105/0005 , B32B1/08 , B32B27/20 , B32B27/286 , B32B2307/558 , B32B2307/7265 , B32B2597/00 , B65D1/0215 , B65D25/14 , B65D31/04 , C08L81/04 , C08L2203/10 , C08L2203/12 , C08L2203/202 , F16L9/133 , F16L9/147 , F16L11/00 , F16L57/04 , F16L57/06 , F16L58/04 , F27B14/00 , Y10T428/1352 , Y10T428/1393 , Y10T428/1397 , Y10T428/2958
Abstract: Pipe sections and methods for forming pipe sections are disclosed. A pipe section includes a hollow body formed from a polymer material, the hollow body having an inner surface and an outer surface, the inner surface defining an interior. The pipe section further includes a barrier layer surrounding and unbonded from the hollow body, the barrier layer having an inner surface and an outer surface. The barrier layer is formed from a continuous fiber reinforced thermoplastic material. Such pipe sections may be lightweight and flexible while exhibiting improved strength characteristics.
Abstract translation: 公开了用于形成管段的管段和方法。 管段包括由聚合物材料形成的中空本体，所述中空体具有内表面和外表面，所述内表面限定内部。 管段还包括围绕和未与中空本体结合的阻挡层，阻挡层具有内表面和外表面。 阻挡层由连续纤维增强热塑性材料形成。 这种管段可以是轻质的和柔性的，同时具有改进的强度特性。
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Patent Agency Ranking6.发明公开
公开(公告)号：EP3183320A4
公开(公告)日：2018-01-31
申请号：EP15834215
申请日：2015-08-14
Applicant: TICONA LLC
Inventor： MAZAHIR SYED , NAIR KAMLESH P , SUBRAMONIAN SURESH , GRENCI JOSEPH J , FENG KE , ZHAO XINYU , MCILROY DAVID A , CHAKRABARTY KAUSHIK
CPC classification number: C08L67/04 , C08G2650/40 , C08J5/00 , C08L67/00 , C08L71/00 , C08L71/123 , C09K19/3809 , C09K19/542
Abstract: A polymer composition that contains a polyaryletherketone and a liquid crystalline polymer that includes repeating units derived from naphthenic hydroxycarboxylic acids, naphthenic dicarboxylic acids, or a combination thereof in an amount of about 15 mol. % or less of the polymer is provided. The composition optionally contains reinforcing fibers (e.g., glass fibers) in an amount of no more than about 10 wt. %.
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7.发明申请POLYARYLENE SULFIDE COMPOSITION INCLUDING A FUNCTIONALIZED SILOXANE POLYMER AND A NON-AROMATIC IMPACT MODIFIER 审中-公开包含官能化硅氧烷聚合物和非芳香族冲击改性剂的聚亚烷基硫酸酯组合物
公开(公告)号：WO2013155425A3
公开(公告)日：2014-05-30
申请号：PCT/US2013036388
申请日：2013-04-12
Applicant: TICONA LLC
Inventor： LUO RONG , ZHAO XINYU
Abstract: Polyarylene sulfide compositions are described as are methods of forming the polyarylene sulfide compositions. The polyarylene sulfide compositions are formed by melt processing polyarylene sulfide, a reactively functionalized siloxane polymer and a non-aromatic impact modifier. The non-aromatic impact modifier is, e.g., an ethylene-based copolymer or terpolymer or a silicone elastomer. The compositions exhibit good strength and heat resistance characteristics and can be utilized in forming a variety of products such as automotive components and electrical components.
Abstract translation: 聚芳硫醚组合物描述为形成聚芳硫醚组合物的方法。 聚芳硫醚组合物通过熔融加工聚芳硫醚，反应官能化的硅氧烷聚合物和非芳族抗冲改性剂形成。 非芳香族抗冲改性剂是例如乙烯类共聚物或三元共聚物或有机硅弹性体。 该组合物表现出良好的强度和耐热特性，并可用于形成诸如汽车部件和电气部件的各种产品。
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公开(公告)号：WO2013130352A3
公开(公告)日：2013-12-27
申请号：PCT/US2013027355
申请日：2013-02-22
Applicant: TICONA LLC
Inventor： SCHOOTS HARRIE P , CHAKRABARTY KAUSHIK , ZHAO XINYU , KARANDIKAR ARVIND , BRUECK MARTIN , MCGRADY CHRISTOPHER
CPC classification number: D06M15/21 , D01F6/765 , D06P1/5221 , D06P1/5228 , D06P1/5242 , D06P1/525 , D06P1/5257 , D06P1/5278 , D06P1/5285 , D06P3/004
Abstract: A fibrous material that contains polyarylene sulfide fibers coated with an emulsion copolymer is provided. The emulsion copolymer that is coated onto the polyarylene sulfide fibers is crosslinked. For example, the copolymer may contain a reactive co-monomer that acts as a crosslinking agent. Alternatively, a separate crosslinking agent may be combined with the emulsion copolymer. In either case, the resulting copolymer composition is cured after it is applied to the fibers to initiate the formation of crosslink bonds between the emulsion copolymer and create a three-dimensional network that is capable of coating and encapsulating the fibers. Without intending to be limited by theory, it is believed that this three-dimensional network is able to physically entrap disperse dyes when applied to the fibers.
Abstract translation: 提供了包含涂布有乳液共聚物的聚芳硫醚纤维的纤维材料。 涂布在聚芳硫醚纤维上的乳液共聚物是交联的。 例如，共聚物可以含有作为交联剂的反应性共聚单体。 或者，单独的交联剂可以与乳液共聚物组合。 在任一种情况下，所得的共聚物组合物在施加到纤维上之后固化，以引发乳液共聚物之间的交联键的形成并产生能够涂覆和包封纤维的三维网络。 不期望受理论的限制，据信这种三维网络能够在施加到纤维上时物理地捕获分散染料。
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公开(公告)号：WO2013052269A3
公开(公告)日：2013-09-12
申请号：PCT/US2012055856
申请日：2012-09-18
Applicant: TICONA LLC
Inventor： LUO RONG , ZHAO XINYU , FENG KE
CPC classification number: H05K5/03 , C08G75/029 , C08K5/372 , C08K7/02 , C08L81/02
Abstract: An injection molded housing for a portable electronic device is provided. The housing contains a thermoplastic composition that includes a polyarylene sulfide melt processed in the presence of a disulfide compound and a filler. Without intending to be limited by theory, it is believed that the disulfide can undergo a chain scission reaction with the starting polyarylene sulfide to lower its melt viscosity, which can lead to decreased attrition of the filler and thus improved mechanical properties. Due to this ability to reduce viscosity during melt processing, the present inventors have discovered that relatively high molecular weight polyarylene sulfides can be fed to the extruder with little difficulty.
Abstract translation: 提供了一种用于便携式电子设备的注塑外壳。 壳体包含热塑性组合物，其包含在二硫化物化合物和填料的存在下加工的聚芳硫醚熔体。 不期望受理论的限制，相信二硫化物可以与起始聚芳硫醚发生断链反应以降低其熔体粘度，这可导致填料的磨损减少，从而改善机械性能。 由于这种在熔融加工过程中降低粘度的能力，本发明人已经发现，相对高分子量的聚亚芳基硫化物可以很少地进料到挤出机中。
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公开(公告)号：WO2013155517A3
公开(公告)日：2014-06-26
申请号：PCT/US2013036579
申请日：2013-04-15
Applicant: TICONA LLC
Inventor： RUBY MICHAEL A , EASTEP DAVID W , LUO RONG , ZHAO XINYU , GRENCI JOSEPH J , MCGRADY CHRISTOPHER
CPC classification number: C08L81/02 , B29C47/0004 , B29C47/0016 , B29C47/0023 , B29C47/1018 , B29C47/8805 , B29K2081/04 , B29K2105/0005 , B32B1/08 , B32B27/20 , B32B27/286 , B32B2307/558 , B32B2307/7265 , B32B2597/00 , B65D1/0215 , B65D25/14 , B65D31/04 , C08L81/04 , C08L2203/10 , C08L2203/12 , C08L2203/202 , F16L9/133 , F16L9/147 , F16L11/00 , F16L57/04 , F16L57/06 , F16L58/04 , F27B14/00 , Y10T428/1352 , Y10T428/1393 , Y10T428/1397 , Y10T428/2958
Abstract: Pipe sections and methods for forming pipe sections are disclosed. A pipe section includes a hollow body, the hollow body having an inner surface and an outer surface, the inner surface defining an interior. The pipe section further includes a barrier layer surrounding the hollow body, the barrier layer having an inner surface and an outer surface. The barrier layer is formed from a polyarylene sulfide composition. The polyarylene sulfide composition includes a polyarylene sulfide and a crosslinked impact modifier. Such pipe sections exhibit high strength characteristics and flexibility as well as resistance to degradation, even in extreme temperature environments, while maintaining desirable processing characteristics.
Abstract translation: 公开了用于形成管段的管段和方法。 管段包括中空体，中空体具有内表面和外表面，内表面限定内部。 管段还包括围绕中空体的阻挡层，阻挡层具有内表面和外表面。 阻挡层由聚芳硫醚组合物形成。 聚芳硫醚组合物包括聚芳硫醚和交联的抗冲改性剂。 这样的管段即使在极端温度环境下也表现出高的强度特性和柔韧性以及耐劣化性，同时保持理想的加工特性。
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