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公开(公告)号:DE3173308D1
公开(公告)日:1986-02-06
申请号:DE3173308
申请日:1981-08-27
Applicant: TORAY INDUSTRIES
Inventor: HASUMI SHIGERU , TANAKA KAZUO , NISHIDOI TAKASHI
IPC: H04R7/02
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公开(公告)号:JPS6354418A
公开(公告)日:1988-03-08
申请号:JP19729086
申请日:1986-08-25
Applicant: TORAY INDUSTRIES
Inventor: KUBODERA KAZUNAO , NAKAE TAKEJI , HASUMI SHIGERU
Abstract: PURPOSE:To obtain the title composition which can give a cured product excellent in heat resistance, water resistance and toughness, by mixing an epoxy compound with a cyanate resin, a polysulfone resin and a specified bis(hydroxyphenyl) sulfone or its formalin condensate. CONSTITUTION:A mixture obtained by mixing an epoxy compound (A) having at least two epoxy groups in the molecule (e.g., bisphenol A-derived epoxy resin) with a polycyanate (prepolymer) (B) having at least two cyanato groups in the molecule or a mixture thereof with a polymaleimide (prepolymer) (B) having at least two maleimide groups in the molecule at 9:1-2:8 is mixed with 6-60pts.wt. per 100pts.wt. component B, polysulfone resin (C) of formula I (wherein Ar is a group of formula II, III or IV) and 0.5-20pts.wt., per 100pts.wt. component A, bis(hydroxyphenyl) sulfone of formula VI or its formaline condensate (D).
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公开(公告)号:JPS62185720A
公开(公告)日:1987-08-14
申请号:JP2673486
申请日:1986-02-12
Applicant: TORAY INDUSTRIES
Inventor: SUZUE SHIGERU , HASUMI SHIGERU , MURAKI TOSHIO
Abstract: PURPOSE:To produce the titled high-quality composition within a short time, by dissolving a specified ground thermoplastic resin in an epoxy resin and mixing the resulting solution with a cyanic ester resin. CONSTITUTION:100-20wt% cyanic ester of formula I (wherein R is an aromatic organic group and m is 2-5) and 0-80wt% maleimide of formula II (wherein R is a bi- to penta-valent aromatic or aliphatic organic group and m is 2-5) are prepolymerized at 80-160 deg.C for 1-4hr to obtain a cyanic ester (C). A thermoplastic resin of a glass transition temperature >=100 deg.C (e.g., polyether sulfone) is ground with an impact mill and classified to obtain a thermoplastic resin powder (A) of a particle diameter
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公开(公告)号:JPS63205328A
公开(公告)日:1988-08-24
申请号:JP3671487
申请日:1987-02-19
Applicant: TORAY INDUSTRIES
Inventor: HASUMI SHIGERU , KAWAZU YUKIO , HIRAMATSU TORU
Abstract: PURPOSE:To obtain a prepreg which can give a composite material excellent in water and impact resistances in a high-temperature wet state, by using a carbon fiber subjected to a specified surface treatment and a cyanate resin as essential component. CONSTITUTION:A prepreg for composite materials which essentially consists of a carbon fiber (A) (preferably of an elongation >=1.6%) having a nitrogenous functional group content (NIS/CIS) on the surface of the carbon fiber (as determined by X-ray photoelectron spectroscopy) in the range of 0.06-0.25 and a cyanate resin (B) [e.g., (a) a polycyanate and/or a prepolymer thereof of a resin composition (b) obtained by mixing or pre-reacting a polymaleimide with said component (a)] and optionally contains an epoxy resin and a polysulfone resin. This prepreg is excellent in the resistance to acid, water and impact in a high-temperature wet state. Said resin A can be obtained by subjecting a carbon fiber to electrolysis in an ammonium ion-containing electrolyte solution by using the fiber as an anode.
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公开(公告)号:JPS6017450B2
公开(公告)日:1985-05-02
申请号:JP9834582
申请日:1982-06-08
Applicant: TORAY INDUSTRIES
Inventor: HASUMI SHIGERU , KABASHIMA AKIHIRO , SUEYOSHI TADAHIRO , AYA TOSHIHIKO
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公开(公告)号:EP0086837A4
公开(公告)日:1984-04-27
申请号:EP81902444
申请日:1981-08-27
Applicant: TORAY INDUSTRIES
Inventor: HASUMI SHIGERU , TANAKA KAZUO , NISHIDOI TAKASHI
IPC: H04R7/02
CPC classification number: H04R7/02
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公开(公告)号:JPS6366219A
公开(公告)日:1988-03-24
申请号:JP20960186
申请日:1986-09-08
Applicant: TORAY INDUSTRIES
Inventor: KUBODERA KAZUNAO , NAKAE TAKEJI , HASUMI SHIGERU
Abstract: PURPOSE:To obtain the titled composition, containing a specific epoxy resin, cyanic acid ester based resin and sulfone based compound, having excellent water and heat resistance and capable of giving cured resin articles suitable as matrix resins for prepreg of FRP and IC sealing media. CONSTITUTION:A composition containing (A) an epoxy compound having >=2 epoxy groups in one molecule, (B) a cyanic acid ester based resin and (C) a sulfone based compound expressed by the formula (n and m are integers of >=1; R is H or CH3). Furthermore, the component (A) preferably consists of (i) polyfunctional cyanic acid esters (prepolymer blend) containing >=2 cyanate groups in one molecule or together with (ii) polyfunctional maleimides (prepolymer blend) containing >=2 maleimide groups in the molecule.
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公开(公告)号:JPS6257417A
公开(公告)日:1987-03-13
申请号:JP19607885
申请日:1985-09-06
Applicant: TORAY INDUSTRIES
Inventor: NAKAHARA MASANORI , HASUMI SHIGERU , MURAKI TOSHIO
Abstract: PURPOSE:The titled composition having improved toughness, heat resistance, water resistance and tack.draping properties, containing specific components such as tetraglycidyldiaminodiphenylmethane, bisphenol A type epoxy resin, diaminodiphenylsulfone, etc. CONSTITUTION:(A) N,N,N',N'-Tetraglycidyldiaminodiphenylmethane is blended with (B) bisphenol A type epoxy resin shown by the formula I (G is group shown by the formula II), (C) bisphenol F type epoxy resin, (D) diaminodiphenylsulfone and (E) a polyether sulfone shown by the formula III, as essential components, to give the aimed composition.
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公开(公告)号:JPS6236460A
公开(公告)日:1987-02-17
申请号:JP17564885
申请日:1985-08-12
Applicant: TORAY INDUSTRIES
Inventor: MURAKI TOSHIO , NAKAHARA MASANORI , HASUMI SHIGERU
Abstract: PURPOSE:To provide the titled compsn. which gives a composite material having a high mechanical strength at a high temp. and excellent toughness and heat resistance, consisting of a polyfunctional cyanate ester having a specified composition, a bismaleimide and a polysulfone. CONSTITUTION:A polyfunctionl cyanate ester (A) of formula I (wherein R is a residue of an arom. hydrocarbon formed by removing OH groups from a polyfunctional phenol compd.; n is at least 2), a bismaleimide (B) derived from maleic anhydride and an arom. diamine (e.g. m-phenylenediamine) and a polysulfone (C) of formula II (wherein n s 10-150) are blended in a weight ratio of A/B of 100/0-40/60 and C/(A+B+C) of 5/100-50/100.
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公开(公告)号:JPS5748288A
公开(公告)日:1982-03-19
申请号:JP12230980
申请日:1980-09-05
Applicant: Toray Industries
Inventor: KATAOKA TOSHIROU , HASUMI SHIGERU
IPC: H05K1/05
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