Abstract:
By a method for producing a diamine comprising the step of purifying a diamine from an aqueous solution containing a diamine salt, the method comprising a step of adding an alkaline substance to the aqueous solution and then filtering the resulting solution by allowing the solution to pass through a nanofiltration membrane to remove the salt, thereby obtaining an aqueous diamine solution, a diamine suitable as a raw material for a polyamide can be obtained by a simpler operation than by a conventional extraction operation with an organic solvent.
Abstract:
Disclosed is a process for producing a diamine, comprising the step of purifying a diamine from an aqueous solution containing a diamine salt. Specifically, the process comprises the step of adding an alkaline substance to the aqueous solution and then filtering the aqueous solution through a nanofiltration film to remove the salt and thus to obtain an aqueous diamine solution, whereby a diamine suitable as a starting material for a polyamide can be obtained by a simpler operation than a conventional extraction operation with an organic solvent.
Abstract:
Provided is a polyamide resin composition comprising a melt blend of (A) a polyamide resin, (B) a phyllosilicate, and (C) an olefin compound having a carboxylic acid anhydride group in the molecule or a polymer of the olefin compound, in which the phyllosilicate (B) has a reactive functional group bonded thereto and is such that the exchangeable metal ions existing in the interlayers are ion-exchanged with organic onium ions. The composition has a reduced inorganic ash content and has both high stiffness and high ductility. Optionally, the composition contains an inorganic filler apart from the phyllosilicate, an impact modifier, and a flame retardant, still having high stiffness and high ductility.
Abstract:
A polyester resin composition having excellent hydrolysis resistance and excellent transparency and a method of producing the same are provided. There is provided a polyester resin composition comprising a polyester resin that is obtained from a dicarboxylic acid or an ester-forming derivative thereof and a diol as main raw material; and a copper-containing compound and a nitrogen-containing compound having a nitrogen-containing heterocyclic structure or a tertiary amine structure that are mixed with the polyester resin.
Abstract:
A polyamide resin obtained by heating and condensation-polymerizing ingredients mainly comprising pentamethylenediamine having a total content of 2,3,4,5-tetrahydropyridine and piperidine of 0.10 wt.% or lower and an aliphatic dicarboxylic acid having 7 or more carbon atoms, a 0.01 g/mL solution of the polyamide resin in 98% sulfuric acid having a relative viscosity at 25 °C of 1.8-4.5. The polyamide resin has excellent heat resistance, extremely low water absorption, and excellent melt residence stability and is hence suitable for use as long molded articles represented by automotive radiator tanks, etc.
Abstract:
The present invention addresses the problem of providing a high molecular weight, terminal modified polyamide resin having a low melt viscosity and excellent molding processability. The problem is solved by a terminal modified polyamide resin having a relative viscosity (·r), as measured at 25°C in a 98% sulfuric acid solution at a resin concentration of 0.01 g/ml, of 2.1 to 10, the resin comprising 0.05 to 4.5% by mass of a terminal structure represented by general formula (I): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ-X-(R 1 -O) n -R 2 €ƒ€ƒ€ƒ€ƒ€ƒ(I) wherein n ranges from 2 to 100; R 1 represents a hydrocarbon group of 2 to 10 carbon atoms; R 2 represents a hydrocarbon group of 1 to 30 carbon atoms; -X- represents - NH- or -N(CH 3 )-; and n R 1 s in the general formula (I) may be the same or different.