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    POLYESTER-POLYETHER COPOLYMER COMPOSITION
    2.
    发明专利
    POLYESTER-POLYETHER COPOLYMER COMPOSITION 未知

    公开(公告)号：DE3266731D1

    公开(公告)日：1985-11-14

    申请号：DE3266731

    申请日：1982-02-09

    Applicant: TORAY INDUSTRIES

    Inventor： KOMATSU HIDEO ,  HARADA HIROYUKI ,  MATSUKI TOMIJI

    IPC: C08L67/00 ,  C08K5/20 ,  C08K5/57 ,  C08L67/02 ,  C08L77/00

    Abstract: The invention comprises a polyester-polyether copolymer composition which comprises a polyester-polyether copolymer composed mainly of an aromatic dicarboxylic acid, 1,4-butanediol, and polyalkylene glycol of average molecular weight from about 400 to 6,000, an effective amount of organotin compound, and an amide-containing phenolic antioxidant. … The antioxidant which is used has at least one group of the formula … … where R is a secondary or tertiary alkyl group, R min is a hydrogen atom or a secondary or tertiary alkyl group, and n is from 0 to 6. … The glycol component of the polyester component comprises glycols of molecular weight less than 250 with at least 70 mol percent of 1,4-butanediol. The polyalkylene glycol component preferably consists mainly of tetramethylene glycol units.

    3.
    发明专利
    未知

    公开(公告)号：DE2149053A1

    公开(公告)日：1972-04-13

    申请号：DE2149053

    申请日：1971-10-01

    Applicant: TORAY INDUSTRIES

    Inventor： HAGIWARA YOSHICHI ,  SATO KATUNOBU ,  KOMATSU HIDEO ,  YUGUCHI SADAO ,  YOSHIZUMI NOBUO ,  NAGAI KENYA ,  TAKEDA HIROMU ,  OHNISHI SEI-ICHIRO

    IPC: C08L61/10 ,  D01D5/24 ,  D01F6/76 ,  C08G53/00

    Abstract: 1339181 Phenol-formaldehyde fibres TORAY INDUSTRIES Inc 1 Oct 1971 [2 Oct 1970 23 Dec 1970 13 April 1971 4 May 1971] 45751/71 Heading C3R [Also in Division B5] Cross-linked phenol-formaldehyde fibres are prepared by mixing a novolac resin having a pH of at least 4 with tetraoxymethylene and/or trioxan, melt-spinning the mixture to yield fibres and then curing in the presence of an acid catalyst preferably at a temperature of 0-150‹ C., preferably followed by a heat treatment, at 70-250‹ C. The phenolic component of the resin is preferably phenol or bisphenol A. Suitable acid catalysts include mineral acids, Lewis' acids, sulphonic acids, organic carboxylic acids, acid precursors and acid salts. The catalyst may be used in conjunction with formaldehyde and/or a compound producing formaldehyde. The fibre may be modified by reaction with a compound other than HCHO during or after the curing process to block and/or cross-link the phenolic hydroxy groups. The modifying compound may be the same as the acid catalyst. Suitable modifying compounds include acid halides ; acid anhydrides; a compound of the formula R-(COX) n wherein R represents a C-C bond, a di-, tri- or quadrivalent acyclic hydrocarbon or an aromatic radical, n = 2-4 and X is a halogen atom; a compound of the formula R-(X) n wherein R represents -CO-, -Si(R 1 ) 2 -, -P(R 1 )-, -P(O)R 1 )-, -O 2 S-R 2 -SO 2 -, -P-(-R 1 ) 3 - or wherein R 1 is a halogen atom or an organic group such as alkyl, phenyl, alkoxy or phenoxy, n > 2, and X is a halogen atom, and R 2 is phenylene, where Z is -O-, -S-, -CH 2 -, -CO-, When the modification treatment is effected with an halogenated phosphorus compound the fibres are subsequently stabilized by reaction with an epoxy compound such as propylene oxide. In Examples 1 and 2 fibres prepared from a mixture of a phenol-HCHO novolac resin and 10% wt. tetraoxymethylene or trioxan are cured by heating in the presence of one of the following acid catalysts: H 2 SO 4 , PCl 3 , p-toluenesulphonic chloride, oxalic acid, acetyl chloride both in the presence and absence of HCHO. In Example 5 cross-linked fibres are prepared from novolac resins prepared from formaldehyde and (i) a mixture of phenol and p-cresol, (ii) bisphenol A, (iii) phenol, aniline, (iv) phenol, nylon 6 by melt spinning the resins with 10% wt. tetraoxymethylene and then curing the fibres in the presence of p-toluene sulphonic acid. In Example 6 fibres melt spun from a phenol-HCHO novolac and 10% wt. tetraoxymethylene mixture are cured in the presence of HCl and HCHO and then heat treated in the presence of acetic anhydride and one of the following catalysts: p-toluene sulphonic acid, HCl, BF 3 etherate, acetyl chloride, dimethyl formamide hydrochloride, and oxalic acid. In Example 7 fibres prepared from the resin of Example 1 are cured in the presence of various acid chlorides and subsequently heat-treated. In Example 8 fibres are melt spun from the resin mixtures of Example 5 and cured in the presence of one of the following modifying compounds: succinyl dichloride, fumaric acid dichloride, butenetetracarboxylic acid tetrachloride, benzophenonetetracarboxylic acid tetrachloride, naphthalene - 1 - 5 - dicarboxylic acid dichloride, oxalyl chloride, butenetricarboxylic acid trichloride, maleic acid dichloride, isophthalic acid dichloride. In Example 9 fibres melt spun from a mixture of a phenol- HCHO novolac resin and 10% wt. tetraoxymethylene are reacted with various halogenated phosphorus compounds and subsequently stabilized by reaction with propylene oxide.

    CURED FIBERS FROM PHENOL-FORMALDEHYDE RESINS
    5.
    发明专利
    CURED FIBERS FROM PHENOL-FORMALDEHYDE RESINS 未知

    公开(公告)号：AU3413771A

    公开(公告)日：1973-04-05

    申请号：AU3413771

    申请日：1971-10-01

    Applicant: TORAY INDUSTRIES

    Inventor： HAGIWARA YOSHICHI ,  SATO KATUNOBU ,  KOMATSU HIDEO ,  YUGUCHI SADAO ,  YOSHIZUMI NOBUO ,  NAGAI KENYA ,  TAKEDA HIROMU ,  OHNISHI SEI-ICHIRO

    IPC: C08L61/10 ,  D01D5/24 ,  D01F6/76 ,  D01D1/04 ,  D01D5/10 ,  D01F7/00 ,  D06M13/00 ,  C08G37/08

    Abstract: 1339181 Phenol-formaldehyde fibres TORAY INDUSTRIES Inc 1 Oct 1971 [2 Oct 1970 23 Dec 1970 13 April 1971 4 May 1971] 45751/71 Heading C3R [Also in Division B5] Cross-linked phenol-formaldehyde fibres are prepared by mixing a novolac resin having a pH of at least 4 with tetraoxymethylene and/or trioxan, melt-spinning the mixture to yield fibres and then curing in the presence of an acid catalyst preferably at a temperature of 0-150‹ C., preferably followed by a heat treatment, at 70-250‹ C. The phenolic component of the resin is preferably phenol or bisphenol A. Suitable acid catalysts include mineral acids, Lewis' acids, sulphonic acids, organic carboxylic acids, acid precursors and acid salts. The catalyst may be used in conjunction with formaldehyde and/or a compound producing formaldehyde. The fibre may be modified by reaction with a compound other than HCHO during or after the curing process to block and/or cross-link the phenolic hydroxy groups. The modifying compound may be the same as the acid catalyst. Suitable modifying compounds include acid halides ; acid anhydrides; a compound of the formula R-(COX) n wherein R represents a C-C bond, a di-, tri- or quadrivalent acyclic hydrocarbon or an aromatic radical, n = 2-4 and X is a halogen atom; a compound of the formula R-(X) n wherein R represents -CO-, -Si(R 1 ) 2 -, -P(R 1 )-, -P(O)R 1 )-, -O 2 S-R 2 -SO 2 -, -P-(-R 1 ) 3 - or wherein R 1 is a halogen atom or an organic group such as alkyl, phenyl, alkoxy or phenoxy, n > 2, and X is a halogen atom, and R 2 is phenylene, where Z is -O-, -S-, -CH 2 -, -CO-, When the modification treatment is effected with an halogenated phosphorus compound the fibres are subsequently stabilized by reaction with an epoxy compound such as propylene oxide. In Examples 1 and 2 fibres prepared from a mixture of a phenol-HCHO novolac resin and 10% wt. tetraoxymethylene or trioxan are cured by heating in the presence of one of the following acid catalysts: H 2 SO 4 , PCl 3 , p-toluenesulphonic chloride, oxalic acid, acetyl chloride both in the presence and absence of HCHO. In Example 5 cross-linked fibres are prepared from novolac resins prepared from formaldehyde and (i) a mixture of phenol and p-cresol, (ii) bisphenol A, (iii) phenol, aniline, (iv) phenol, nylon 6 by melt spinning the resins with 10% wt. tetraoxymethylene and then curing the fibres in the presence of p-toluene sulphonic acid. In Example 6 fibres melt spun from a phenol-HCHO novolac and 10% wt. tetraoxymethylene mixture are cured in the presence of HCl and HCHO and then heat treated in the presence of acetic anhydride and one of the following catalysts: p-toluene sulphonic acid, HCl, BF 3 etherate, acetyl chloride, dimethyl formamide hydrochloride, and oxalic acid. In Example 7 fibres prepared from the resin of Example 1 are cured in the presence of various acid chlorides and subsequently heat-treated. In Example 8 fibres are melt spun from the resin mixtures of Example 5 and cured in the presence of one of the following modifying compounds: succinyl dichloride, fumaric acid dichloride, butenetetracarboxylic acid tetrachloride, benzophenonetetracarboxylic acid tetrachloride, naphthalene - 1 - 5 - dicarboxylic acid dichloride, oxalyl chloride, butenetricarboxylic acid trichloride, maleic acid dichloride, isophthalic acid dichloride. In Example 9 fibres melt spun from a mixture of a phenol- HCHO novolac resin and 10% wt. tetraoxymethylene are reacted with various halogenated phosphorus compounds and subsequently stabilized by reaction with propylene oxide.

    PROCESS FOR PREPARING ALPHA,OMEGA-BIS(2-CHLOROPHENOXY)-ALKANE-4,4'-DICARBOXYLIC ACID OR ITS LOWER ALKYL ESTER
    8.
    发明专利
    PROCESS FOR PREPARING ALPHA,OMEGA-BIS(2-CHLOROPHENOXY)-ALKANE-4,4'-DICARBOXYLIC ACID OR ITS LOWER ALKYL ESTER 未知

    公开(公告)号：DE3362750D1

    公开(公告)日：1986-05-07

    申请号：DE3362750

    申请日：1983-01-28

    Applicant: TORAY INDUSTRIES

    Inventor： INOUE TOSHIHIDE ,  KOMATSU HIDEO

    IPC: C07C51/363 ,  C07C65/24 ,  C07C67/307 ,  C07C69/92

    Abstract: PCT No. PCT/JP83/00024 Sec. 371 Date Sep. 12, 1983 Sec. 102(e) Date Sep. 12, 1983 PCT Filed Jan. 28, 1983 PCT Pub. No. WO83/02609 PCT Pub. Date Aug. 4, 1983.A process for producing an alpha , omega -bis(2-chlorophenoxy)alkane-4,4'-dicarboxylic acid or its ester, that has a high Young's modulus and that is useful as a material for polyesters capable to form self-extinguishing fibers and films. Thus alpha , omega -bis(2-chlorophenoxy)alkane-4,4'-dicarboxylic acid or its ester is obtained by reacting alpha , omega -bis(phenoxy)alkane-4,4'-dicarboxylic acid or its ester with chlorine in the presence of a solvent selected from the group consisting of lower fatty acid having 2 to 6 carbon atoms, hydrocarbon chloride having 1 to 8 carbon atoms, and carbon chloride having 1 to 2 carbon atoms, in high yield.

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