公开(公告)号：DE2707275A1

公开(公告)日：1977-08-25

申请号：DE2707275

申请日：1977-02-19

Applicant: TORAY INDUSTRIES

Inventor： TANAKA HIROYOSHI ,  KOSEKI TERUO ,  FUJII SHIGERU

IPC: A41B17/00 ,  A41D31/00 ,  C08L33/00 ,  C08L33/02 ,  C08L33/18 ,  C08L67/00 ,  D01F1/09 ,  D01F6/18 ,  D01F6/54 ,  D03D15/00 ,  H05F1/00 ,  D01F6/40 ,  D01F6/86

Abstract: An antistatic acrylic fiber having an electrical resistivity of about 108 OMEGA centimeters or less. The fiber comprises (A) an acrylonitrile homopolymer or copolymer and (B) an antistatic polymer comprising a plurality of polyether segments disposed in said polymer (A), and wherein electrically conductive carbon black is dispersed in antistatic polymer (B). Preferably antistatic polymer (B) extends in the form of long and slender stripes in the polymer (A).

公开(公告)号：DE2814665C2

公开(公告)日：1994-05-05

申请号：DE2814665

申请日：1978-04-05

Applicant: TORAY INDUSTRIES

Inventor： HIRAMATSU TORU ,  KOSEKI TERUO ,  HAMADA SATOSI ,  SUMIDA ATSUSHI

IPC: D01F9/22

公开(公告)号：DE2814665A1

公开(公告)日：1978-10-12

申请号：DE2814665

申请日：1978-04-05

Applicant: TORAY INDUSTRIES

Inventor： HIRAMATSU TORU ,  KOSEKI TERUO ,  HAMADA SATOSI ,  SUMIDA ATSUSHI

IPC: D01F9/22 ,  D01F9/20

公开(公告)号：AU2264877A

公开(公告)日：1978-08-31

申请号：AU2264877

申请日：1977-02-24

Applicant: TORAY INDUSTRIES

Inventor： TANAKA HIROYOSHI ,  KOSEKI TERUO ,  FUJII SHIGERU

IPC: A41B17/00 ,  A41D31/00 ,  C08L33/00 ,  C08L33/02 ,  C08L33/18 ,  C08L67/00 ,  D01F1/09 ,  D01F6/18 ,  D01F6/54 ,  D03D15/00 ,  H05F1/00

Abstract: An antistatic acrylic fiber having an electrical resistivity of about 108 OMEGA centimeters or less. The fiber comprises (A) an acrylonitrile homopolymer or copolymer and (B) an antistatic polymer comprising a plurality of polyether segments disposed in said polymer (A), and wherein electrically conductive carbon black is dispersed in antistatic polymer (B). Preferably antistatic polymer (B) extends in the form of long and slender stripes in the polymer (A).

公开(公告)号：JPS5184927A

公开(公告)日：1976-07-24

申请号：JP931875

申请日：1975-01-23

Applicant: TORAY INDUSTRIES

Inventor： KOSEKI TERUO ,  TANAKA HIROYASU ,  FUJII SHIGERU

IPC: C08L33/00 ,  C08L33/02 ,  C08L33/18 ,  C08L33/20 ,  C08L67/00 ,  D01F6/54

公开(公告)号：JPS5421479A

公开(公告)日：1979-02-17

申请号：JP8626277

申请日：1977-07-19

Applicant: TORAY INDUSTRIES

Inventor： MAEDA KATSUNOSUKE ,  SAKAI HIROSHI ,  KOSEKI TERUO ,  NAKAHAMA FUROU ,  SHIOZUKA HIDETOSHI

IPC: C08F2/00 ,  C08F2/06

Abstract: PURPOSE:In the polymerization of a vinyl monomer using a plurality of connected polymerizers, while one polymerizer is washed, the polymerization is continued using other polymerizers thus permitting continuous polymerization without gelation.

公开(公告)号：JPS51144450A

公开(公告)日：1976-12-11

申请号：JP6753775

申请日：1975-06-06

Applicant: TORAY INDUSTRIES

Inventor： KOSEKI TERUO ,  TANAKA HIROYASU ,  TAKAMOTO ISAO ,  FUJII SHIGERU

IPC: C08L33/00 ,  C08L1/00 ,  C08L27/00 ,  C08L29/02 ,  C08L33/02 ,  C08L33/18 ,  C08L33/20 ,  C08L51/00 ,  C08L51/02 ,  C08L77/00 ,  D01F6/54 ,  D01F8/10

Abstract: PURPOSE:Polyacrylonitrile (PAN) compn. with less tendency of losing transparency for fiber and film apication containing an acrylinitrile (AN)-polyvinyl alcohol (PVA) graft copolymer.

公开(公告)号：JPH032457B2

公开(公告)日：1991-01-16

申请号：JP32929087

申请日：1987-12-24

Applicant: TORAY INDUSTRIES

Inventor： AKAO KENICHI ,  KOSEKI TERUO

IPC: C08L33/20 ,  C08K5/16 ,  C08L33/18

公开(公告)号：JPH01168750A

公开(公告)日：1989-07-04

申请号：JP32929087

申请日：1987-12-24

Applicant: TORAY INDUSTRIES

Inventor： AKAO KENICHI ,  KOSEKI TERUO

IPC: C08L33/20 ,  C08K5/16 ,  C08L33/18

Abstract: PURPOSE:To obtain the title polymer solution decreased in microgel formed and improved in moldability, by adding a radical polymerization inhibitor to a specified acrylonitrile polymer solution after conducting a derived polymerization. CONSTITUTION:Acrylonitrile and 0-10mol% vinyl monomer copolymerizable therewith (e.g., acrylic acid) are subjected to a solution polymerization at 40-90 deg.C in an inorganic or organic solvent in the presence of a radical polymerization initiator (e.g., azobisisobutyronitrile) and a chain transfer agent (e.g., dodecyl mercaptan) to obtain an acrylonitrile polymer solution (A) for the production of an acrylonitrile molding. Component A is mixed with at least one radical polymerization inhibitor selected from among (B) an N-nitrosophenyl compound, a hydrazine compound, an aldoxime compound and a mixture of an N-nitrosophenyl compound with a phenyl compound in an amount of at least 1/2mol per mol of the radical polymerization initiator remaining in the acrylonitrile polymer.

公开(公告)号：JPS6426615A

公开(公告)日：1989-01-27

申请号：JP18450987

申请日：1987-07-22

Applicant: TORAY INDUSTRIES

Inventor： AKAO KENICHI ,  KOSEKI TERUO

IPC: C08F2/00 ,  C08F2/38 ,  C08F20/44 ,  C08F220/00 ,  C08F220/42 ,  C08F220/46

Abstract: PURPOSE:To obtain the titled solution having remarkably decreased amount of microgel in the polymer and giving reduced load in maintenance of a filter, by controlling the amount and charging order of each raw material compound in the solution polymerization in a batch polymerization reactor by continuous operation. CONSTITUTION:A batch polymerization reactor is charged with (A) acrylonitrile. Prior to the charge of 50wt.% of the acrylonitrile based on the whole amount to be charged, the reactor is charged with (B) a vinyl compound having destructive chain-transfer action (e.g. acrylic acid) or (C) a chain-transfer agent (e.g. hypophosphorous acid) in amounts corresponding to >=10wt.% of the charging amount of each component. After completing the charge of the entire amount of the components A, B and C according to conventional process, the batch polymerization reactor is continuously operated to effect the solution polymerization of the components A and B in the presence of the component C to obtain the objective solution. The polymerization initiator is preferably charged first at the stage when the charge of the components A, B and C are completed.