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公开(公告)号:DE69822353T2
公开(公告)日:2005-02-17
申请号:DE69822353
申请日:1998-03-31
Applicant: TORAY INDUSTRIES
Inventor: OHME HIROYUKI , HIRATSUKA MOTOKI , NOGAMI KATSUO
Abstract: A method for producing polybutylene terephthalate comprises continuously esterifying a dicarboxylic acid component comprising terephthalic acid with a diol component comprising 1,4-butanediol followed by polycondensing the resulting oligomer, wherein the esterification is effected in a molar ratio, P, of the diol component to the dicarboxylic acid component to fall between 1.1 and 1.6, in the presence of a combination of an organic titanium compound and an organic tin compound that satisfies the following requirement: where P = molar ratio of diol component to dicarboxylic acid component, and is followed by the polycondensation.e
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公开(公告)号:DE69822353D1
公开(公告)日:2004-04-22
申请号:DE69822353
申请日:1998-03-31
Applicant: TORAY INDUSTRIES
Inventor: OHME HIROYUKI , HIRATSUKA MOTOKI , NOGAMI KATSUO
Abstract: A method for producing polybutylene terephthalate comprises continuously esterifying a dicarboxylic acid component comprising terephthalic acid with a diol component comprising 1,4-butanediol followed by polycondensing the resulting oligomer, wherein the esterification is effected in a molar ratio, P, of the diol component to the dicarboxylic acid component to fall between 1.1 and 1.6, in the presence of a combination of an organic titanium compound and an organic tin compound that satisfies the following requirement: where P = molar ratio of diol component to dicarboxylic acid component, and is followed by the polycondensation.e
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公开(公告)号:MY127879A
公开(公告)日:2006-12-29
申请号:MYPI9801397
申请日:1998-03-30
Applicant: TORAY INDUSTRIES
Inventor: OHME HIROYUKI , HIRATSUKA MOTOKI , NOGAMI KATSUO
Abstract: A METHOD FOR PRODUCING POLYBUTYLENE TEREPHTHALATE COMPRISING CONTINUOUSLY ESTERIFYING A DICARBOXYLIC ACID COMPONENT CONSISTING ESSENTAILLY OF TEREPHTHALIC ACID WITH A DIOL COMPONENT CONSISTING ESSENTIALLY OF 1,4-BUTANEDIOL FOLLOWED BY POLYCONDENSING THE RESULTING OLIGOMER, WHEREIN THE ESTERIFICATION IS EFFECTED IN A MOLAR RATIO, P, OF THE DIOL COMPONENT TO THE DICARBOXYLIC ACID COMPONENT TO FALL BETWEEN 1.1 AND 1.6, IN THE PRESENCE OF A COMBINATION OF AN ORGANIC TITANIUM COMPOUND AND AN ORGANIC TIN COMPOUND THAT SATISFIES THE FOLLOWING REQUIREMENT:AMOUNT OF ORGANIC TITANIUM COMPOUND (MOL%)
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公开(公告)号:ID20093A
公开(公告)日:1998-10-01
申请号:ID980480
申请日:1998-03-31
Applicant: TORAY INDUSTRIES
Inventor: OHME HIROYUKI , HIRATSUKA MOTOKI , NOGAMI KATSUO
Abstract: A method for producing polybutylene terephthalate comprises continuously esterifying a dicarboxylic acid component comprising terephthalic acid with a diol component comprising 1,4-butanediol followed by polycondensing the resulting oligomer, wherein the esterification is effected in a molar ratio, P, of the diol component to the dicarboxylic acid component to fall between 1.1 and 1.6, in the presence of a combination of an organic titanium compound and an organic tin compound that satisfies the following requirement: where P = molar ratio of diol component to dicarboxylic acid component, and is followed by the polycondensation.e
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公开(公告)号:JP2003247121A
公开(公告)日:2003-09-05
申请号:JP2002046201
申请日:2002-02-22
Applicant: TORAY INDUSTRIES
Inventor: SUGIMOTO TAKESHI , NOGAMI KATSUO , KAMATA SHIGEYOSHI
Abstract: PROBLEM TO BE SOLVED: To provide a hot-melt adhesive polyester fiber used for heat resistant cushioning materials in applications exposed to relatively high temperature environment such as vehicle, and provide the cushioning material. SOLUTION: The hot-melt adhesive polyester fiber is constituted by using a polymer prepared by melting and mixing a modified polybutylene terephthalate (polyester A) having 180-220°C melting point and a polyester B having ≤180°C melting point in a weight mixing rate A/B=10/90-80/20. The cushioning material is constituted by adhering a basic fabric with the hot-melt adhesive fiber. COPYRIGHT: (C)2003,JPO
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公开(公告)号:JP2001279529A
公开(公告)日:2001-10-10
申请号:JP2000090642
申请日:2000-03-29
Applicant: TORAY INDUSTRIES
Inventor: NOGAMI KATSUO , SUGIMOTO TAKESHI , KOMITSU NAOKATA
Abstract: PROBLEM TO BE SOLVED: To provide a polyester staple fiber and a fabric composed of the staple having a high fiber strength originally hard to generate a pilling exactly differing from conventional anti-pilling manifestation such as generation of pilling and dropping out. SOLUTION: This is a polyester hollow staple fiber obtained by melt blend spinning of two or more polyesters having different melting points measured by DSC (differential scanning calorimetry). The polyester hollow staple fiber has two or more melting point peaks obtained by temperature increasing method of DSC, and a ratio of areas of the largest melting point peak area (D1) and the second layer melting point peak area (D2) satisfies the relation, 0.3
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公开(公告)号:JPH10330468A
公开(公告)日:1998-12-15
申请号:JP3520298
申请日:1998-02-17
Applicant: TORAY INDUSTRIES
Inventor: OOME HIROKAZU , HIRATSUKA MOTONORI , NOGAMI KATSUO
IPC: C08G63/183 , C08G63/78 , C08G63/85
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a polybutylene terephthalate excellent in quality by a method using a continuous direct esterification while suppressing side reactions. SOLUTION: This method for producing a polybutylene terephthalate obtained by performing the esterification of dicarboxylic acids consisting mainly of terephthalic acid with diols consisting mainly of 1,4-butane diol, and then performing a polycondensation reaction of the obtained ester, is to perform a first step of the esterification reaction in the presence of an organic tin compound and substantially without the presence of an organic titanium compound until attaining >=80% rate of the esterification reaction, then a second step of the esterification reaction by adding an organic titanium compound and then the polycondensation reaction of the obtained ester.
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公开(公告)号:JPH09241367A
公开(公告)日:1997-09-16
申请号:JP5442496
申请日:1996-03-12
Applicant: TORAY INDUSTRIES
Inventor: NOGAMI KATSUO , ITO SHIN , KONDO KAZUYUKI
IPC: C08G63/183 , C08G63/181 , C08G63/78
Abstract: PROBLEM TO BE SOLVED: To prepare a polyester in a shortened esterification reaction time by adding an esterification catalyst to a dicarboxylic acid and a glycol to initiate an esterification reaction, and then adding thereto a glycol contg. an esterification catalyst to effect a polycondensation reaction. SOLUTION: The esterification reaction of 1mol of a dicarboxylic acid contg. at least 50mol% terephthalic acid with 0.4-1.2mol of a glycol contg. at least 70mol% 1,4-butanediol is initiated in the presence of an esterification catalyst. At least 15 minutes after the initiation of the esterification reaction, a mixture of a glycol with an esterfication catalyst is added in an amt. of 0.1 to 1.0mol per mol of the dicarboxylic acid in the reaction system to complete a polycondensation reaction while recovering the glycol.
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公开(公告)号:JP2003253528A
公开(公告)日:2003-09-10
申请号:JP2002057263
申请日:2002-03-04
Applicant: TORAY INDUSTRIES
Inventor: SUGIMURA SHOICHI , NOGAMI KATSUO , KAMATA SHIGEYOSHI
Abstract: PROBLEM TO BE SOLVED: To provide a polyester hot-bonding fiber which is used for heat- resistant cushion materials useful for uses often exposed to relatively high temperature environments, such as uses for vehicles, and to provide the cushion material. SOLUTION: This polyester hot-bonding fiber is characterized by being formed from a polymer composition obtained by melt-blending a (polymer A) polyetherester block copolymer having a melting temperature of 180 to 220°C with a (polymer B) polyester having a melting point of ≤180°C in an A/B weight mixing ratio of 10/90 to 80/20, and the cushion material is produced by bonding matrix fibers with the hot-bonding fibers. COPYRIGHT: (C)2003,JPO
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公开(公告)号:JP2001254270A
公开(公告)日:2001-09-21
申请号:JP2000060254
申请日:2000-03-06
Applicant: TORAY INDUSTRIES
Inventor: SANO SHINJI , NOGAMI KATSUO , HONDA HIDENOBU
IPC: A47C27/12 , D06M11/00 , D06M11/79 , D06M15/256 , D06M15/277 , D06M15/643
Abstract: PROBLEM TO BE SOLVED: To provide a raw material for wadding, capable of achieving the wadding having excellent functionality simultaneously having odorization- preventing deodorant properties with durability, antibacterial properties, mildewproofing properties and antifouling properties. SOLUTION: This raw material for the wadding, comprising fibers as an essential constitutional material is characterized in that the raw material has at least one of binder selected from alkyl silicate-based resins, silicone-based resins and fluororesins, and a photocatalyst on the surface of the fiber.
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