FLAME-RETARDANT POLYAMIDE RESIN COMPOSITION

    公开(公告)号:JPH05320503A

    公开(公告)日:1993-12-03

    申请号:JP12639092

    申请日:1992-05-19

    Abstract: PURPOSE:To provide a flame-retardant polyamide resin composition which comprises a specific crystalline polyamide resin, a specific polybrominated styrene and an auxiliary flame retardant thus shows excellent flame retardancy and heat resistance and gives moldings of good surface appearance. CONSTITUTION:The objective resin composition comprises (A) 100 pts.wt. of a crystalline polyamide resin which is constituted with the recurring units of formula I to formula III (R is an aliphatic group of 6 to 18C; R is an aliphatic group of 4 to 18C or m-phenylene group; (n) is an integer of 5 to 18) and contains the units of formula I or formulas I and II, as essential units, and has a melting point higher than 270 deg.C, (B) 0.5 to 60 pts.wt. of polybromostyrene which is prepared from brominated styrene, has the unit of formula IV as the major component, 1X10 to 30X10 number-average molecular weight and 2X10 to 120X10 weight-average molecular weight, and (C) 1 to 10 pts.wt. of an auxiliary flame retarant selected from antimont oxide, sodium antimonate, tin oxide, iron oxide, zinc oxide and zinc borate preferably anhydrous sodium antimonate, and, when needed, fillers.

    PRODUCTION OF POLYAMIDE RESIN
    5.
    发明专利

    公开(公告)号:JPH05230205A

    公开(公告)日:1993-09-07

    申请号:JP3107192

    申请日:1992-02-18

    Abstract: PURPOSE:To facilitate the formation of a specified crystalline copolyamide excellent in heat resistance, etc., and having low water absorptivity by forming a lower condensate under specified conditions and subjecting this condensate to a treatment for increasing its molecular weight. CONSTITUTION:A process for producing a crystalline copolyamide comprising hexamethylenephthalamide units (A) of formula I and hexamethyleneisophthalamide units (B) of formula II, hexamethyleneadipamide units (C) of formula III and capramide units (D) of formula IV in a comonomer ratio (by weight) of A/B, A/C or A/D in a specified range, which process comprises forming a lower condensate of a relative viscosity of 1.01-1.6 when measured in a 1% sulfuric acid solution at 25 deg.C at 150-300 deg.C and feeding a dicarboxylic acid component (e.g. terephthalic acid) in an amount 0.3-10mol%- excess over the amount which is the total of the numbers of moles of monomers of A-D, the number of moles of the dicarboxylic acid component in the form of a salt and the number of moles of the diamine component.

    POLYAMIDE FILM
    6.
    发明专利

    公开(公告)号:JPH04314741A

    公开(公告)日:1992-11-05

    申请号:JP8215391

    申请日:1991-04-15

    Abstract: PURPOSE:To prevent the formation of pinholes and improve flexibility, transparency, and strengths by forming a compsn. comprising a polyamide and a specific polyetheresteramide elastomer into film. CONSTITUTION:10-80wt.% 6-12C lactam or aminocarboxylic acid, a polyoxytetramethylene glycol having a number-average mol.wt. of 600-2500, and an aliph., alicyclic, and/or arom. dicarboxylic acid in a molar ratio of OH of the glycol to COOH of the dicarboxylic acid of 0.9-1.1 are copolymerized to give a polyetheresteramide elastomer having a relatie viscosity of 1.2-5.0. 99.5-91wt.% polyamide is melt mixed with 0.5-9wt.% the elastomer, formed into film, biaxially oriented succesively, and thermally treated to give a 1-50mum- thick polyamide film.

    RESIN COMPOSITION
    7.
    发明专利

    公开(公告)号:JPH04178447A

    公开(公告)日:1992-06-25

    申请号:JP30444490

    申请日:1990-11-09

    Abstract: PURPOSE:To obtain a composition suitable for continuously molding packaging materials, having excellent drawing properties, gas barrier properties, hot-water resistance, oil resistance, etc., comprising a saponified ethylene-vinyl alcohol copolymer and a specific polyamide. CONSTITUTION:(A) 60-95wt.% saponified ethylene-vinyl alcohol copolymer having 25-60mol%, especially 25-50mol% ethylene content is blended with (B) 5-40wt.% polyamide having 160-215 deg.C melting point, which is an aliphatic polyamide comprising capramide as a main constituent unit, having a ratio of number of methylene groups and number of amide groups satisfying formula I, wherein an end carboxyl group content X and an end amino group content Y are adjusted to satisfy formula II by using an end modifying agent. The ratio of capramide unit in the component B is 95-55wt.%, especially 90-65wt.%.

    FLAME-RETARDANT NYLON RESIN COMPOSITION

    公开(公告)号:JPH03239755A

    公开(公告)日:1991-10-25

    申请号:JP3799890

    申请日:1990-02-19

    Abstract: PURPOSE:To prepare the title compsn. excellent in flame retardance, heat resistance, and molded appearance by compounding a specific copolymer nylon, a specific flame retardant, and a specific flame retardant aid, each in a specified amt. CONSTITUTION:The title compsn. is prepd. by compounding: 30-90wt.% copolymer nylon comprising 80-20wt.% hexamethyleneterephthalamide units and 20-80wt.% hexamethyleneadipamide or -caproamide units; 5-35wt.% flame retardant contg. a halogenated polystyrene or a halogenated polyphenylene ether having a halogen content of 50-70wt.% and wt.-average mol.wt. of 5000 or higher; 1-10wt.% at least one flame retardant aid selected from the group consisting of Sb2O3, sodium antimonate, tin oxide, iron oxide, and zinc oxide; and, as an optional component, 50wt.% or lower inorg. reinforcement (e.g. glass fiber).

    PHOTOSENSITIVE POLYAMIDE RESIN COMPOSITION

    公开(公告)号:JPS5990845A

    公开(公告)日:1984-05-25

    申请号:JP20038482

    申请日:1982-11-17

    Abstract: PURPOSE:To obtain a titled photosensitive composition having improved water developing characteristics by blending water-soluble polyamide, specified polyether and an unsaturated compd. having an ethylenic double bond. CONSTITUTION:(A) 100pts.wt. water-soluble (or water-dispersible) polyamide (preferably a polyamide copolymer having 30-70wt% structural unit consisting of polyoxyethylene with a terminal amino group whose polyether segment part has 150-1,500mol.wt. and of an aliphatic dicarboxylic acid), (B) 0.5-50pts.wt. polyoxyethylene (polyoxypropylene may also be used) having 200-5,000mol.wt. and (C) 20-200pts.wt. unsaturated compd. having an ethylenic double bond such as 2-hydroxyethyl (meth)acrylate, are dissolved in a mixed solvent of alcohol and water under heating.

    PRODUCTION OF LIQUID CRYSTAL POLYESTER

    公开(公告)号:JPH1017659A

    公开(公告)日:1998-01-20

    申请号:JP17691696

    申请日:1996-07-05

    Abstract: PROBLEM TO BE SOLVED: To provide a process whereby the cycle of washing the inside of a reactor for the production of a liquid crystal polyester can be prolonged, the productivity can be therefore improved, and a high-quality polyester having excellent heat resistance can be produced. SOLUTION: This process comprises reacting a liquid-crystal-polyester-forming material containing polyester polymer pellets prepared by condensing an aromatic dicarboxylic acid with an alkylene glycol and having a logarithmic viscosity of 0.8dl/g or below and a particle diameter of 2,000μm or below. In this process, the reaction mixture is agitated so that the shear rate may be 150-1,000 (1/sec).

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