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公开(公告)号：WO0001485A3
公开(公告)日：2001-09-20
申请号：PCT/US9915065
申请日：1999-07-02
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BILLIG ERNST , BRYANT DAVID ROBERT , BEASLEY CRAIG ALAN , MORRISON DONALD LEE , WARHOLIC MICHAEL DAVID , STOCKMAN KENNETH ELWOOD
CPC classification number: B01J31/185 , B01J31/24 , B01J31/2404 , B01J31/4015 , B01J31/4038 , B01J31/4053 , B01J2231/321 , B01J2531/822 , C07C45/50 , Y02P20/582 , Y02P20/584
Abstract: This invention relates to a method of stabilizing a metal-organophosphorus ligand complex catalyst against deactivation in a process which comprises reacting one or more reactants in the presence of a metal-organophosphorus ligand complex catalyst and optionally free organophosphorus ligand to produce a reaction product fluid comprising one or more products, and in which at least a portion of said process is conducted under separation conditions sufficient to effect at least some deactivation of the metal-organophophorus ligand complex catalyst, which method comprises conducting the portion of said process that occurs under separation conditions in the presence of one or more alkadienes sufficient to prevent and/or lessen deactivation of the metal-organophosphorus ligand complex catalyst.
Abstract translation: 本发明涉及在一种方法中稳定金属 - 有机磷配体配合物催化剂以防止失活的方法，该方法包括在金属 - 有机磷配体配合物催化剂和任选的游离有机磷配体的存在下使一种或多种反应物反应以产生反应产物流体， 一种或多种产物，并且其中所述方法的至少一部分在足以实现金属 - 有机磷配体配合物催化剂的至少一些失活的分离条件下进行，该方法包括进行在分离条件下发生的所述方法的部分 在一种或多种足以防止和/或减少金属 - 有机磷配体配合物催化剂失活的烯二烯存在下进行。
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公开(公告)号：DE69611845T2
公开(公告)日：2001-09-13
申请号：DE69611845
申请日：1996-12-05
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BRYANT ROBERT , LEUNG WAI , BILLIG ERNST , EISENSCHMID CARL , NICHOLSON CLAIR
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公开(公告)号：DE69613858D1
公开(公告)日：2001-08-16
申请号：DE69613858
申请日：1996-12-05
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BRYANT ROBERT , NICHOLSON CLAIR , BILLIG ERNST
IPC: B01J19/18 , B01J27/18 , B01J31/02 , C07B61/00 , B01J31/18 , B01J31/22 , B01J31/40 , B01J38/74 , C07C45/49 , C07C45/50 , C07C47/02 , C07C51/00 , C07C51/255 , C07C51/265 , C07C51/42 , C07C51/43 , C07C63/00 , C07C63/15 , C07C63/26 , C07F9/02 , C07F9/141 , C07F9/145 , C07F9/50 , C07F9/6571 , C07F9/6574 , C07F15/00 , F04D25/08 , F04D29/28
Abstract: This invention relates to a process which comprises reacting one or more reactants in the presence of a metal-organophosphite ligand complex catalyst and dissolved water and optionally free organophosphite ligand to produce a reaction product fluid comprising one or more products, wherein said process is conducted in the presence of carbon dioxide in an amount sufficient not to effect substantial degradation of any said organophosphite ligand and/or substantial deactivation of said metal-organophosphite ligand complex catalyst.
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公开(公告)号：MX203409B
公开(公告)日：2001-08-01
申请号：MX9804489
申请日：1998-06-05
Applicant: UNION CARBIDE CHEM PLASTIC , CORP
Inventor： BRYANT DAVID ROBERT , NICHOLSON JAMES CLAIR , BILLIG ERNST
IPC: C07B61/00 , B01J19/18 , B01J27/18 , B01J31/02 , B01J31/18 , B01J31/22 , B01J31/40 , B01J38/74 , C07C45/49 , C07C45/50 , C07C47/02 , C07C51/00 , C07C51/255 , C07C51/265 , C07C51/42 , C07C51/43 , C07C63/00 , C07C63/15 , C07C63/26 , C07F9/02 , C07F9/141 , C07F9/145 , C07F9/50 , C07F9/6571 , C07F9/6574 , C07F15/00 , F04D25/08 , F04D29/28
Abstract: This invention relates to a process which comprises reacting one or more reactants in the presence of a metal-organophosphite ligand complex catalyst and dissolved water and optionally free organophosphite ligand to produce a reaction product fluid comprising one or more products, wherein said process is conducted in the presence of carbon dioxide in an amount sufficient not to effect substantial degradation of any said organophosphite ligand and/or substantial deactivation of said metal-organophosphite ligand complex catalyst.
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公开(公告)号：ES2156306T3
公开(公告)日：2001-06-16
申请号：ES96942897
申请日：1996-12-05
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BRYANT DAVID ROBERT , LEUNG TAK WAI , BILLIG ERNST , EISENSCHMID THOMAS CARL , NICHOLSON JAMES CLAIR
IPC: B01J19/18 , B01J27/18 , B01J31/02 , C07B61/00 , B01J31/18 , B01J31/22 , B01J31/40 , B01J38/74 , C07C45/49 , C07C45/50 , C07C47/02 , C07C51/00 , C07C51/255 , C07C51/265 , C07C51/42 , C07C51/43 , C07C63/00 , C07C63/15 , C07C63/26 , C07F9/02 , C07F9/141 , C07F9/145 , C07F9/50 , C07F9/6571 , C07F9/6574 , C07F15/00 , F04D25/08 , F04D29/28
Abstract: This invention relates to a process which comprises reacting one or more reactants in the presence of a metal-organophosphite ligand complex catalyst and dissolved water and optionally free organophosphite ligand to produce a reaction product fluid comprising one or more products, wherein said process is conducted in the presence of carbon dioxide in an amount sufficient not to effect substantial degradation of any said organophosphite ligand and/or substantial deactivation of said metal-organophosphite ligand complex catalyst.
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Patent Agency Ranking
公开(公告)号：SK69298A3
公开(公告)日：1999-03-10
申请号：SK69298
申请日：1996-12-05
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BILLIG ERNST , BRYANT DAVID R
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公开(公告)号：MX9804284A
公开(公告)日：1998-10-31
申请号：MX9804284
申请日：1998-05-29
Applicant: UNION CARBIDE CHEM PLASTIC , CORP
Inventor： BECKER MICHAEL CARL , BRYANT DAVID ROBERT , BUNNING DONALD LEROY , NICHOLSON JAMES CLAIR , BILLIG ERNST
IPC: B01J19/18 , B01J27/18 , C07B61/00 , B01J31/02 , B01J31/18 , B01J31/22 , B01J31/40 , B01J38/74 , C07C45/49 , C07C45/50 , C07C47/02 , C07C51/00 , C07C51/255 , C07C51/265 , C07C51/42 , C07C51/43 , C07C63/00 , C07C63/15 , C07C63/26 , C07F9/02 , C07F9/141 , C07F9/145 , C07F9/50 , C07F9/6571 , C07F9/6574 , C07F15/00 , F04D25/08 , F04D29/28
Abstract: Esta invencion se refiere a un proceso para la produccion de uno o varios productos en un reactor de etapas multiples que tiene más de una etapa de reaccion donde el proceso comprende la reaccion en dicho reactor de etapas multiples de uno o varios reactivos con monoxido de carbono en presencia de un catalizador de complejo metal-ligando de organofosforo y opcionalmente ligando de organofosforo libre para producir dicho producto o dichos productos, donde dicho catalizador de complejo metal-ligando de organofosforo no se somete a una desactivacion sustancial en presencia de solamente monoxido de carbono y/o efectua un cambio de selectividad de producto normal de menos del 0.2% del producto normal bajo una presion parcial de monoxido de carbono de 1 libra por pulgada cuadrada y/o efectua cambio en la tasa de reaccion de menos del 2% bajo una presion parcial de monoxido de carbono de 1 libra por pulgada cuadrada.
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公开(公告)号：CZ9801751A3
公开(公告)日：1998-10-14
申请号：CZ175198
申请日：1996-12-05
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BRYANT DAVID ROBERT , NICHOLSON JAMES CLAIR , BILLIG ERNST
CPC classification number: Y02P20/584
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公开(公告)号：MX9804076A
公开(公告)日：1998-09-30
申请号：MX9804076
申请日：1998-05-22
Applicant: UNION CARBIDE CHEM PLASTIC , CORP
Inventor： BILLIG ERNST , BRYANT DAVID ROBERT
IPC: B01J31/22 , B01J31/02 , B01J31/18 , B01J31/40 , C07B61/00 , C07C37/02 , C07C45/50 , C07C47/02 , C07F9/02 , C07F9/6574
Abstract: Esta invencion se refiere a un proceso para que comprende la reaccion de uno o varios reactivos en presencia de un catalizador complejo de metal-ligando de organopolifosfito para producir un fluido producto de la reaccion que comprende uno o varios productos, donde dicho proceso se lleva a cabo en una concentracion de ligando de organopolifosfito libre suficiente para evitar y/o aminorar la degradacion hidrolítica del ligando de organopolifosfito y la desactivacion del catalizador complejo de metal-ligando de organopolifosfito.
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公开(公告)号：ZA9610306B
公开(公告)日：1998-09-07
申请号：ZA9610306
申请日：1996-12-06
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BECKER MICHAEL CARL , BUNNING DONALD LEROY , BILLIG ERNST , BRYANT DAVID ROBERT , NICHOLSON JAMES CLAIR
IPC: B01J19/18 , B01J27/18 , C07B61/00 , B01J31/02 , B01J31/18 , B01J31/22 , B01J31/40 , B01J38/74 , C07C45/49 , C07C45/50 , C07C47/02 , C07C51/00 , C07C51/255 , C07C51/265 , C07C51/42 , C07C51/43 , C07C63/00 , C07C63/15 , C07C63/26 , C07F9/02 , C07F9/141 , C07F9/145 , C07F9/50 , C07F9/6571 , C07F9/6574 , C07F15/00 , F04D25/08 , F04D29/28 , B01J , C07C
Abstract: This invention relates to a process which comprises reacting one or more reactants in the presence of a metal-organophosphite ligand complex catalyst and dissolved water and optionally free organophosphite ligand to produce a reaction product fluid comprising one or more products, wherein said process is conducted in the presence of carbon dioxide in an amount sufficient not to effect substantial degradation of any said organophosphite ligand and/or substantial deactivation of said metal-organophosphite ligand complex catalyst.
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