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公开(公告)号：WO0001485A3
公开(公告)日：2001-09-20
申请号：PCT/US9915065
申请日：1999-07-02
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BILLIG ERNST , BRYANT DAVID ROBERT , BEASLEY CRAIG ALAN , MORRISON DONALD LEE , WARHOLIC MICHAEL DAVID , STOCKMAN KENNETH ELWOOD
CPC classification number: B01J31/185 , B01J31/24 , B01J31/2404 , B01J31/4015 , B01J31/4038 , B01J31/4053 , B01J2231/321 , B01J2531/822 , C07C45/50 , Y02P20/582 , Y02P20/584
Abstract: This invention relates to a method of stabilizing a metal-organophosphorus ligand complex catalyst against deactivation in a process which comprises reacting one or more reactants in the presence of a metal-organophosphorus ligand complex catalyst and optionally free organophosphorus ligand to produce a reaction product fluid comprising one or more products, and in which at least a portion of said process is conducted under separation conditions sufficient to effect at least some deactivation of the metal-organophophorus ligand complex catalyst, which method comprises conducting the portion of said process that occurs under separation conditions in the presence of one or more alkadienes sufficient to prevent and/or lessen deactivation of the metal-organophosphorus ligand complex catalyst.
Abstract translation: 本发明涉及在一种方法中稳定金属 - 有机磷配体配合物催化剂以防止失活的方法，该方法包括在金属 - 有机磷配体配合物催化剂和任选的游离有机磷配体的存在下使一种或多种反应物反应以产生反应产物流体， 一种或多种产物，并且其中所述方法的至少一部分在足以实现金属 - 有机磷配体配合物催化剂的至少一些失活的分离条件下进行，该方法包括进行在分离条件下发生的所述方法的部分 在一种或多种足以防止和/或减少金属 - 有机磷配体配合物催化剂失活的烯二烯存在下进行。
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公开(公告)号：WO0168252A3
公开(公告)日：2003-09-04
申请号：PCT/US0108181
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT
IPC: B01J31/40 , B01J31/00 , B01J38/00 , C07B61/00 , C07B63/00 , C07C29/136 , C07C31/20 , C07C67/31 , C07C67/313 , C07C67/58 , C07C69/675 , C07C69/716 , C07C227/02 , C07C227/08 , C07C229/08 , C07C45/50
CPC classification number: C07B63/00 , C07C67/58 , Y02P20/582 , C07C69/716
Abstract: This invention relates to a process for separating one or more orgnnophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ration Ef3 which is a value greater than about 2.5.
Abstract translation: 本发明涉及一种从包含一种或多种未反应的不饱和酯反应物，金属 - 有机磷配位体配合物催化剂，任选地，一种或多种反应产物流体的反应产物流体中分离一种或多种磷配体降解产物，一种或多种反应副产物和一种或多种甲酰酯产物的方法 所述一种或多种有机磷配体降解产物，所述一种或多种反应副产物，所述一种或多种产物，极性溶剂和非极性溶剂通过相分离，其中（i）极性相对于有机磷配体的选择性 对于一种或多种产物，由分配系数比Ef1表示，该分配系数比Ef1大于约2.5，（ii）极性相对于一种或多种有机磷配体降解产物的有机磷配体的选择性为 由大于约2.5的值的分配系数比Ef2表示，a （iii）相对于一种或多种反应副产物，极性相对有机磷配体的选择性由分配系数比例Ef3表示，该分配系数比值大于约2.5。
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公开(公告)号：WO0168249A3
公开(公告)日：2002-03-28
申请号：PCT/US0108156
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAY MIN , MAHER JOHN MICHAEL
CPC classification number: C07C45/50 , C07B63/00 , Y02P20/582 , C07C47/02
Abstract: This invention relates to a process for separating one or moer organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphous ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more polar solvents and one or more nonpolar solvent by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Efl which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
Abstract translation: 本发明涉及一种从连续生成的反应产物流体中分离一种或更多的有机磷配体降解产物，一种或多种反应副产物和一种或多种产物的方法，所述反应产物流体包含一种或多种未反应的反应物，金属有机磷配体络合物催化剂， 有机磷配体，所述一种或多种有机磷配体降解产物，所述一种或多种反应副产物，所述一种或多种产物，一种或多种极性溶剂和一种或多种非极性溶剂通过相分离，其中（i）极性相的选择性为 有机磷配体相对于一种或多种产物的分配系数比Efl表示为大于约2.5的值，（ii）极性相对于有机磷配体相对于一种或多种有机磷配体的选择性 降解产物由大于的值的分配系数比Ef2表示 约为2.5，（iii）相对于一种或多种反应副产物，极性相对有机磷配体的选择性由分配系数比Ef3表示，该分配系数比Ef3是大于约2.5的值。
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公开(公告)号：WO0168250A3
公开(公告)日：2002-01-31
申请号：PCT/US0108173
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
IPC: B01D11/04 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02
CPC classification number: C07C45/50 , C07B63/00 , Y02P20/582 , C07C47/02
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organosphosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
Abstract translation: 本发明涉及从连续生成的反应产物流体中分离一种或多种有机磷配体降解产物，一种或多种反应副产物和一种或多种产物，所述反应产物流体包含一种或多种未反应的反应物，金属 - 有机磷配体络合物催化剂， 有机磷配体，所述一种或多种有机磷配体降解产物，所述一种或多种反应副产物，所述一种或多种产物，一种或多种非极性溶剂和一种或多种极性溶剂通过相分离，其中（i）非极性相的选择性为 相对于一种或多种产物的有机磷配体由分配系数比Ef1表示，分配系数比Ef1是大于约2.5的值，（ii）非极性相对有机磷配体相对于一种或多种有机磷配体的选择性 降解产物由分配系数比Ef2表示，分配系数比Ef2是值gre 高于约2.5，以及（iii）非极性相对于一种或多种反应副产物的有机磷配体的选择性由大于约2.5的值的分配系数比Ef3表示。
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公开(公告)号：CA2319801C
公开(公告)日：2006-10-03
申请号：CA2319801
申请日：1999-02-01
Applicant: UNION CARBIDE CHEM PLASTIC
IPC: B01J31/18 , C07C45/50 , B01J31/40 , C07B63/00 , C07C45/80 , C07C47/02 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/144 , C07F9/145 , C07F9/50 , C07F9/6574
Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a nonpolar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a polar solvent to obtain by phase separation a nonpolar phase comprising said metal-organophosphorus ligand complex catalys t, optionally free organophosphorus ligand and said nonpolar solvent and a polar phase comprising said one or more products and polar solvent, and (2) recovering said polar phase from said nonpolar phase; wherein said organophosphorus ligand has a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 5, and said one or more products have a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 0.5.
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Patent Agency Ranking
公开(公告)号：AT314335T
公开(公告)日：2006-01-15
申请号：AT01922386
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more polar solvents and one or more nonpolar solvents by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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公开(公告)号：ES2227625T3
公开(公告)日：2005-04-01
申请号：ES96944748
申请日：1996-12-05
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BRYANT DAVID ROBERT , NICHOLSON JAMES CLAIR , BUNNING DONALD LEROY , EISENSCHMID THOMAS CARL , MORRISON DONALD LEE
IPC: B01J19/18 , B01J27/18 , C07B61/00 , B01J31/02 , B01J31/18 , B01J31/22 , B01J31/40 , B01J38/74 , C07C45/49 , C07C45/50 , C07C47/02 , C07C51/00 , C07C51/255 , C07C51/265 , C07C51/42 , C07C51/43 , C07C63/00 , C07C63/15 , C07C63/26 , C07F9/02 , C07F9/141 , C07F9/145 , C07F9/50 , C07F9/6571 , C07F9/6574 , C07F15/00 , F04D25/08 , F04D29/28
Abstract: Un procedimento de hidroformilación, hidroacilación (intramolecular e intermolecular), hidroamidación, hidroesterificación o carbonilación que comprende hacer reaccionar uno o más reactivos en presencia de un catalizador de un complejo de metal-ligando organofosfito y agua disuelta y, opcionalmente, un ligando organofosfito libre para producir un fluido producto de reacción que comprende uno o más productos, procedimiento que se realiza en presencia de dióxido de carbono en una cantidad de 5 por ciento en moles a 70 por ciento en moles en relación a la mezcla total de gases.
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公开(公告)号：MX221001B
公开(公告)日：2004-06-17
申请号：MXPA00007524
申请日：1999-02-01
Applicant: UNION CARBIDE CHEM PLASTIC
IPC: B01J31/18 , B01J31/40 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/02 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/144 , C07F9/145 , C07F9/50 , C07F9/6574
Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a nonpolar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a polar solvent to obtain by phase separation a non-polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said nonpolar solvent and a polar phase comprising said one or more products and polar solvent, and (2) recovering said polar phase from said nonpolar phase; wherein said organophosphorus ligand has a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 5, and said one or more products have a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 0.5.
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公开(公告)号：MY116785A
公开(公告)日：2004-03-31
申请号：MYPI9900319
申请日：1999-01-29
Applicant: UNION CARBIDE CHEM PLASTIC
IPC: B01J31/18 , C07C45/50 , B01J31/40 , C07B63/00 , C07C45/80 , C07C47/02 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/144 , C07F9/145 , C07F9/50 , C07F9/6574
Abstract: THIS INVENTION RELATES TO A PROCESS FOR SEPARATING ONE OR MORE PRODUCTS FROM A REACTION PRODUCT FLUID COMPRISING A METAL. ORGANOPHOSPHORUS LIGAND COMPLEX CATALYST, OPTIONALLY FREE ORGANOPHOSPHORUS LIGAND, A NONPOLAR SOLVENT AND SAID ONE OR MORE PRODUCTS, WHEREIN SAID PROCESS COMPRISES (1) MIXING SAID REACTION PRODUCT FLUID WITH A POLAR SOLVENT TO OBTAIN BY PHASE SEPARATION A NON- POLAR PHASE COMPRISING SAID METAL-ORGANOPHOSPHORUS LIGAND COMPLEX CATALYST, OPTIONALLY FI''EE ORGANOPHOSPHORUS LIGAND AND SAID NONPOLAR SOLVENT AND A POLAR PHASE COMPRISING SAID ONE OR MORE PRODUCTS AND POLAR SOLVENT, AND (2) RECOVERING SAID POLAR PHASE FROM SAID NONPOLAR PHASE; WHEREIN SAID ORGANOPHOSPHORUS LIGAND HAS A PARTITION COEFFICIENT BETWEEN THE NONPOLAR SOLVENT AND THE POLAR SOLVENT OF GREATER THAN ABOUT 5, AND SAID ONE OR MORE PRODUCTS HAVE A PARTITION COEFFICIENT BETWEEN THE POLAR SOLVENT AND THE NONPOLAR SOLVENT OF GREATER THAN ABOUT 0.5.
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公开(公告)号：BR0109217A
公开(公告)日：2004-03-30
申请号：BR0109217
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT
IPC: B01J31/40 , B01J31/00 , B01J38/00 , C07B61/00 , C07B63/00 , C07C29/136 , C07C31/20 , C07C67/31 , C07C67/313 , C07C67/58 , C07C69/675 , C07C69/716 , C07C227/02 , C07C227/08 , C07C229/08
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein(i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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