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公开(公告)号：WO0001485A3
公开(公告)日：2001-09-20
申请号：PCT/US9915065
申请日：1999-07-02
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BILLIG ERNST , BRYANT DAVID ROBERT , BEASLEY CRAIG ALAN , MORRISON DONALD LEE , WARHOLIC MICHAEL DAVID , STOCKMAN KENNETH ELWOOD
CPC classification number: B01J31/185 , B01J31/24 , B01J31/2404 , B01J31/4015 , B01J31/4038 , B01J31/4053 , B01J2231/321 , B01J2531/822 , C07C45/50 , Y02P20/582 , Y02P20/584
Abstract: This invention relates to a method of stabilizing a metal-organophosphorus ligand complex catalyst against deactivation in a process which comprises reacting one or more reactants in the presence of a metal-organophosphorus ligand complex catalyst and optionally free organophosphorus ligand to produce a reaction product fluid comprising one or more products, and in which at least a portion of said process is conducted under separation conditions sufficient to effect at least some deactivation of the metal-organophophorus ligand complex catalyst, which method comprises conducting the portion of said process that occurs under separation conditions in the presence of one or more alkadienes sufficient to prevent and/or lessen deactivation of the metal-organophosphorus ligand complex catalyst.
Abstract translation: 本发明涉及在一种方法中稳定金属 - 有机磷配体配合物催化剂以防止失活的方法，该方法包括在金属 - 有机磷配体配合物催化剂和任选的游离有机磷配体的存在下使一种或多种反应物反应以产生反应产物流体， 一种或多种产物，并且其中所述方法的至少一部分在足以实现金属 - 有机磷配体配合物催化剂的至少一些失活的分离条件下进行，该方法包括进行在分离条件下发生的所述方法的部分 在一种或多种足以防止和/或减少金属 - 有机磷配体配合物催化剂失活的烯二烯存在下进行。
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公开(公告)号：MY133791A
公开(公告)日：2007-11-30
申请号：MYPI9900313
申请日：1999-01-29
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN N NMN , BRYANT DAVID ROBERT , MORRISON DONALD LEE , STOCKMAN KENNETH ELWOOD , ABATJOGLOU ANTHONY GEORGE
IPC: B01J31/18 , C07C45/50 , B01J31/40 , C07B63/00 , C07C45/80 , C07C49/92 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/50 , C07F9/655 , C07F9/6574
Abstract: THIS INVENTION RELATES TO A PROCESS FOR SEPARATING ONE OR MORE PRODUCTS FROM A REACTION PRODUCT FLUID COMPRISING A METAL-ORGANOPHOSPHORUS LIGAND COMPLEX CATALYST, OPTIONALLY FREE ORGANOPHOSPHORUS LIGAND, A POLAR SOLVENT AND SAID ONE OR MORE PRODUCTS, WHEREIN SAID PROCESS COMPRISES (1) MIXING SAID REACTION PRODUCT FLUID WITH A NONPOLAR SOLVENT TO OBTAIN BY PHASE SEPARATION A POLAR PHASE COMPRISING SAID METAL-ORGANOPHOSPHORUS LIGAND COMPLEX CATALYST, OPTIONALLY FREE ORGANOPHOSPHORUS LIGAND AND SAID POLAR SOLVENT AND A NONPOLAR PHASE COMPRISING SAID ONE OR MORE PRODUCTS AND NONPOLAR SOLVENT, AND (2) RECOVERING SAID NONPOLAR PHASE FROM SAID POLAR PHASE; WHEREIN SAID ORGANOPHOSPHORUS LIGAND HAS A PARTITION COEFFICIENT BETWEEN THE POLAR SOLVENT AND THE NONPOLAR SOLVENT OF GREATER THAN ABOUT 10, AND SAID ONE OR MORE PRODUCTS HAVE A PARTITION COEFFICIENT BETWEEN THE NONPOLAR SOLVENT AND THE POLAR SOLVENT OF GREATER THAN ABOUT 0.5.
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公开(公告)号：BR9908360A
公开(公告)日：2002-01-15
申请号：BR9908360
申请日：1999-02-01
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN N , BRYANT DAVID ROBERT , MORRISON DONALD LEE , STOCKMAN KENNETH ELWOOD , ABATJOGLOU ANTHONY GEORGE
IPC: B01J31/18 , B01J31/40 , C07B63/00 , C07C45/50 , C07C45/80 , C07C49/92 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/50 , C07F9/655 , C07F9/6574
Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a polar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a nonpolar solvent to obtain by phase separation a polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said polar solvent and a nonpolar phase comprising said one or more products and nonpolar solvent, and (2) recovering said nonpolar phase from said polar phase; wherein said organophosphorus ligand has a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 10, and said one or more products have a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 0.5.
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公开(公告)号：AT256097T
公开(公告)日：2003-12-15
申请号：AT99903511
申请日：1999-02-01
Applicant: UNION CARBIDE CHEM PLASTIC
IPC: B01J31/18 , B01J31/40 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/02 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/144 , C07F9/145 , C07F9/50 , C07F9/6574
Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a nonpolar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a polar solvent to obtain by phase separation a non-polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said nonpolar solvent and a polar phase comprising said one or more products and polar solvent, and (2) recovering said polar phase from said nonpolar phase; wherein said organophosphorus ligand has a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 5, and said one or more products have a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 0.5.
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公开(公告)号：CA2319801A1
公开(公告)日：1999-08-05
申请号：CA2319801
申请日：1999-02-01
Applicant: UNION CARBIDE CHEM PLASTIC
IPC: B01J31/18 , B01J31/40 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/02 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/144 , C07F9/145 , C07F9/50 , C07F9/6574
Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a nonpolar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a polar solvent to obtain by phase separation a nonpolar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said nonpolar solvent and a polar phase comprising said one or more products and polar solvent, and (2) recovering said polar phase from said nonpolar phase; wherein said organophosphorus ligand has a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 5, and said one or more products have a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 0.5.
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Patent Agency Ranking
公开(公告)号：CA2319801C
公开(公告)日：2006-10-03
申请号：CA2319801
申请日：1999-02-01
Applicant: UNION CARBIDE CHEM PLASTIC
IPC: B01J31/18 , C07C45/50 , B01J31/40 , C07B63/00 , C07C45/80 , C07C47/02 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/144 , C07F9/145 , C07F9/50 , C07F9/6574
Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a nonpolar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a polar solvent to obtain by phase separation a nonpolar phase comprising said metal-organophosphorus ligand complex catalys t, optionally free organophosphorus ligand and said nonpolar solvent and a polar phase comprising said one or more products and polar solvent, and (2) recovering said polar phase from said nonpolar phase; wherein said organophosphorus ligand has a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 5, and said one or more products have a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 0.5.
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公开(公告)号：MX221001B
公开(公告)日：2004-06-17
申请号：MXPA00007524
申请日：1999-02-01
Applicant: UNION CARBIDE CHEM PLASTIC
IPC: B01J31/18 , B01J31/40 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/02 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/144 , C07F9/145 , C07F9/50 , C07F9/6574
Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a nonpolar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a polar solvent to obtain by phase separation a non-polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said nonpolar solvent and a polar phase comprising said one or more products and polar solvent, and (2) recovering said polar phase from said nonpolar phase; wherein said organophosphorus ligand has a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 5, and said one or more products have a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 0.5.
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公开(公告)号：MY116785A
公开(公告)日：2004-03-31
申请号：MYPI9900319
申请日：1999-01-29
Applicant: UNION CARBIDE CHEM PLASTIC
IPC: B01J31/18 , C07C45/50 , B01J31/40 , C07B63/00 , C07C45/80 , C07C47/02 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/144 , C07F9/145 , C07F9/50 , C07F9/6574
Abstract: THIS INVENTION RELATES TO A PROCESS FOR SEPARATING ONE OR MORE PRODUCTS FROM A REACTION PRODUCT FLUID COMPRISING A METAL. ORGANOPHOSPHORUS LIGAND COMPLEX CATALYST, OPTIONALLY FREE ORGANOPHOSPHORUS LIGAND, A NONPOLAR SOLVENT AND SAID ONE OR MORE PRODUCTS, WHEREIN SAID PROCESS COMPRISES (1) MIXING SAID REACTION PRODUCT FLUID WITH A POLAR SOLVENT TO OBTAIN BY PHASE SEPARATION A NON- POLAR PHASE COMPRISING SAID METAL-ORGANOPHOSPHORUS LIGAND COMPLEX CATALYST, OPTIONALLY FI''EE ORGANOPHOSPHORUS LIGAND AND SAID NONPOLAR SOLVENT AND A POLAR PHASE COMPRISING SAID ONE OR MORE PRODUCTS AND POLAR SOLVENT, AND (2) RECOVERING SAID POLAR PHASE FROM SAID NONPOLAR PHASE; WHEREIN SAID ORGANOPHOSPHORUS LIGAND HAS A PARTITION COEFFICIENT BETWEEN THE NONPOLAR SOLVENT AND THE POLAR SOLVENT OF GREATER THAN ABOUT 5, AND SAID ONE OR MORE PRODUCTS HAVE A PARTITION COEFFICIENT BETWEEN THE POLAR SOLVENT AND THE NONPOLAR SOLVENT OF GREATER THAN ABOUT 0.5.
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公开(公告)号：PL349100A1
公开(公告)日：2002-07-01
申请号：PL34910099
申请日：1999-07-02
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BILLIG ERNST , BRYANT DAVID ROBERT , BEASLEY CRAIG ALAN , MORRISON DONALD LEE , WARHOLIC MICHAEL DAVID , STOCKMAN KENNETH ELWOOD
Abstract: This invention relates to a method of stabilizing a metal-organophosphorus ligand complex catalyst against deactivation in a process which comprises reacting one or more reactants in the presence of a metal-organophosphorus ligand complex catalyst and optionally free organophosphorus ligand to produce a reaction product fluid comprising one or more products, and in which at least a portion of said process is conducted under separation conditions sufficient to effect at least some deactivation of the metal-organophosphorus ligand complex catalyst, which method comprises conducting the portion of said process that occurs under separation conditions in the presence of one or more alkadienes sufficient to prevent and/or lessen deactivation of the metal-organophosphorus ligand complex catalyst.
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公开(公告)号：BR9911830A
公开(公告)日：2001-10-16
申请号：BR9911830
申请日：1999-07-02
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BILLIG ERNST , BRYANT DAVID ROBERT , BEASLEY CRAIG ALAN , MORRISON DONALD LEE , WARHOLIC MICHAEL DAVID , STOCKMAN KENNETH ELWOOD
Abstract: This invention relates to a method of stabilizing a metal-organophosphorus ligand complex catalyst against deactivation in a process which comprises reacting one or more reactants in the presence of a metal-organophosphorus ligand complex catalyst and optionally free organophosphorus ligand to produce a reaction product fluid comprising one or more products, and in which at least a portion of said process is conducted under separation conditions sufficient to effect at least some deactivation of the metal-organophosphorus ligand complex catalyst, which method comprises conducting the portion of said process that occurs under separation conditions in the presence of one or more alkadienes sufficient to prevent and/or lessen deactivation of the metal-organophosphorus ligand complex catalyst.
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