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1.
公开(公告)号:CA2111794C
公开(公告)日:1999-01-19
申请号:CA2111794
申请日:1993-12-17
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: NIELSEN KENNETH A , BUSBY DAVID C , DONOHUE MARC D , GLANCY CHARLES W
Abstract: Methods are presented by which polymeric compositions, such as coating compositions, can be sprayed with compressed fluids, such as carbon dioxide, nitrous oxide, or ethane, at higher solids levels and with finer atomization to give improved spray application quality with reduced emission of solvent.
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2.
公开(公告)号:CA2111794A1
公开(公告)日:1994-06-19
申请号:CA2111794
申请日:1993-12-17
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: NIELSEN KENNETH A , BUSBY DAVID C , DONOHUE MARC D , GLANCY CHARLES W
Abstract: A process of spraying a polymeric compsn. to form a spray of finely atomised liq. droplets comprises (1) forming in a closed system a liq. mixt. a temp. T0 comprising: (a) a non-volatile fraction contg. at least one polymer that is cable of being sprayed; and (b) a solvent fraction that is partially miscible with (a) and contains an amt. of at least one compressed fluid sufficient, when it is added to (a); (i) to make the viscosity of the mixt. suitable for spraying; and (ii) to let the liq. mixt. form a liq. compressed fluid phase at temp. T0 the compressed fluid being a gas at 0 deg. C and 1 atmos. pressure; and (2) spraying the liq. mixt. by passing it at temp. T0 and spray pressure P, into an orifice, through which the mixt. flows to form a liq. spray, where spray pressure P1 is above the min. pressure P2 at which the liq. mixt. forms a liq. compressed fluid phase at temp. T0, thus passing the liq. mixt. through the liq.-liq. region of the polymer compsn. and compressed fluid during depressurisation.
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3.
公开(公告)号:CA2012698A1
公开(公告)日:1990-09-22
申请号:CA2012698
申请日:1990-03-21
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: NIELSEN KENNETH A , GLANCY CHARLES W
Abstract: Disclosed are precursor coating compositions which are particularly suitable for being admixed with at least one supercritical fluid used as a viscosity reduction diluent and then spraying this resultant liquid mixture of supercritical fluid and precursor coating composition onto a substrate to be coated.
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公开(公告)号:CA2044892C
公开(公告)日:1998-08-18
申请号:CA2044892
申请日:1991-06-18
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: GILES FREDERICK A JR , GLANCY CHARLES W
IPC: C08K5/21 , C08K5/3445 , C09D7/12 , C09D201/00 , C09D7/00
Abstract: Coating compositions which provide coatings having enhanced properties, e.g., gloss, are disclosed. The coating compositions may be water-borne compositions, or may be water-reducible or water-dispersible compositions including a thermoplastic resin component. Such compositions include a gloss enhancing amount of a nitrogen-containing component selected from compounds having the formula and mixtures thereof, wherein each R is independently selected from the group consisting of H, monovalent hydrocarbyl radicals having 1 to about 4 carbon atoms, and divalent hydrocarbyl radicals having 1 to about 2 carbon atoms, R'OH wherein R' is a divalent hydrocarbyl radical having 1 to about 4 carbon atoms, provided that the compound includes at least one hydroxyl group and if one R is a divalent radical then another R is a bond in the divalent radical or is another divalent radical.
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公开(公告)号:CA2051996A1
公开(公告)日:1992-03-22
申请号:CA2051996
申请日:1991-09-20
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: BOK HENDRIK F , GLANCY CHARLES W , HOY KENNETH L , LEE CHINSOO , NIELSEN KENNETH A
IPC: B01F5/00 , B01F5/06 , B05B1/24 , B05B1/30 , B05B7/16 , B05B7/24 , B05D1/02 , B05B7/04 , B05B7/26
Abstract: APPARATUS AND METHODS FOR APPLICATION OF COATINGS WITH SUPERCRITICAL FLUIDS AS DILUENTS BY SPRAYING FROM AN ORIFICE This invention is directed to improved spraying apparatus for coating substrates with a coating material and supercritical fluid which apparatus is provided with various features, either alone or in combination, to prevent undesirable premature cooling of the coating mixture which might detrimentally affect the final coating on the substrate; to prevent undesirable depressurization of supercritical fluid contained in the coating mixture which remains in the spray gun after spraying has been stopped; and/or to desirably provide the ability to mix the components of the coating mixture directly in the spray gun. Methods for utilizing these features in the spraying apparatus of the present invention are also disclosed. D-16,455
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公开(公告)号:CA2044892A1
公开(公告)日:1991-12-20
申请号:CA2044892
申请日:1991-06-18
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: GILES FREDERICK A JR , GLANCY CHARLES W
IPC: C08K5/21 , C08K5/3445 , C09D7/12
Abstract: Coating compositions which provide coatings having enhanced properties, e.g., gloss, are disclosed. The coating compositions may be water-borne compositions, or may be water-reducible or water-dispersible compositions including a thermoplastic resin component. Such compositions include a gloss enhancing amount of a nitrogen-containing component selected from compounds having the formula and mixtures thereof, wherein each R is independently selected from the group consisting of H, monovalent hydrocarbyl radicals having 1 to about 4 carbon atoms, and divalent hydrocarbyl radicals having 1 to about 2 carbon atoms, R'OH wherein R' is a divalent hydrocarbyl radical having 1 to about 4 carbon atoms, provided that the compound includes at least one hydroxyl group and if one R is a divalent radical then another R is a bond in the divalent radical or is another divalent radical.
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公开(公告)号:CA2012706A1
公开(公告)日:1990-09-22
申请号:CA2012706
申请日:1990-03-21
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: GLANCY CHARLES W , BUSBY DAVID C
IPC: B05D1/02 , B05D1/04 , C09D7/00 , C09D7/12 , C09D101/08 , C09D193/00 , C09D201/00
Abstract: PRECURSOR COATING COMPOSITIONS CONTAINING WATER AND AN ORGANIC COUPLING SOLVENT SUITABLE FOR SPRAYING WITH SUPERCRITICAL FLUIDS AS DILUENTS The present invention relates to precursor coating compositions containing water and at least one organic solvent which are particularly suitable for being admixed with at least one supercritical fluid used as a viscosity reduction diluent and then spraying this resultant liquid mixture of supercritical fluid and precursor coating composition onto a substrate to be coated. Processes for spraying this precursor mixture are also disclosed. D-16,159
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