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公开(公告)号:ES2535821T3
公开(公告)日:2015-05-18
申请号:ES05767314
申请日:2005-06-24
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: JORGENSEN ROBERT J , KINNAN MICHAEL A , TURNER MICHAEL D , WHITED STEPHANIE M , BAN LASZLO L , WAGNER BURKHARD E
IPC: C08F110/02 , C08F2/34 , C08F4/02 , C08F4/654 , C08F4/656 , C08F210/16
Abstract: Un método para la producción de una composición de procatalizador Ziegler-Natta en forma de partículas sólidas y que comprende fracciones de magnesio, haluro y metales de transición, teniendo dichas partículas un tamaño medio (D50) de entre 10 y 70 μm, y que comprende al menos un 5 por ciento de partículas que tienen un volumen interno hueco, sustancial o completamente encerrado por una capa superficial monolítica (recubrimiento), teniendo dicha capa una relación media grosor de recubrimiento / tamaño de partícula (relación de grosor), determinada por medio de técnicas de micrografía electrónica de barrido (SEM) para partículas que tienen un tamaño de partícula mayor que 30 μm, de más de 0,2, comprendiendo las etapas del método: a) proporcionar una composición líquida que comprenda i) un compuesto de haluro de magnesio, ii) un disolvente o diluyente, iii) un compuesto de metal de transición, en el que el compuesto de metal de transición es un haluro de titanio o un haloalcoholato de titanio que tiene de 1 a 8 átomos de carbono por cada grupo alcoholato, iv) opcionalmente un donador de electrones interno, y v) opcionalmente además un elemento de relleno; b) secar por pulverización la composición para formar una partícula secada por pulverización; y c) recoger las partículas sólidas resultantes, caracterizado por que la concentración del compuesto de haluro de magnesio está presente en una cantidad que es al menos el 90 por ciento de la concentración de saturación en el disolvente o diluyente.
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公开(公告)号:AU2005277920B2
公开(公告)日:2011-08-25
申请号:AU2005277920
申请日:2005-06-24
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: BAN LASZLO L , WAGNER BURKHARD E , WHITED STEPHANIE M , KINNAN MICHAEL A , JORGENSEN ROBERT J , TURNER MICHAEL D
Abstract: A Ziegler-Natta procatalyst composition in the form of solid particles and comprising magnesium, halide and transition metal moieties, said particles having an average size (D50) of from 10 to 70 µm, characterized in that at least 5 percent of the particles have internal void volume substantially or fully enclosed by a monolithic surface layer (shell), said layer being characterized by an average shell thickness/ particle size ratio (Thickness Ratio) determined by SEM techniques for particles having particle size greater than 30 µm of greater than 0.2.
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公开(公告)号:BR112012025954A2
公开(公告)日:2016-06-28
申请号:BR112012025954
申请日:2011-04-13
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: WAGNER BURKHARD E , JORGENSEN ROBERT JAMES
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公开(公告)号:SG184544A1
公开(公告)日:2012-11-29
申请号:SG2012075412
申请日:2011-04-13
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: JORGENSEN ROBERT JAMES , WAGNER BURKHARD E
Abstract: A process for making a Ziegler-Natta-type catalyst precursor including contacting a Group 4 metal compound with one or more Titanium compounds selected from the group of TiCl3 (A1-activated or hydrogen-reduced), and Ti(OR)4 where R is ethyl, isopropyl or butyl in the presence of an alcohol solution having at least one C2-C4 alcohol and at least one of MgCl2 and magnesium compounds which form MgCl2 in the presence of the alcohol solution to form a catalyst precursor solution is provided. Also provided are catalysts made from the precursors produced by the process. Also provided are polymers made using the catalysts.
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公开(公告)号:CA2793888A1
公开(公告)日:2011-10-20
申请号:CA2793888
申请日:2011-04-13
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: JORGENSEN ROBERT JAMES , WAGNER BURKHARD E
Abstract: A process for making a Ziegler-Natta-type catalyst precursor including contacting a Group 4 metal compound with one or more Titanium compounds selected from the group of TiCl3 (A1-activated or hydrogen-reduced), and Ti(OR)4 where R is ethyl, isopropyl or butyl in the presence of an alcohol solution having at least one C2-C4 alcohol and at least one of MgCl2 and magnesium compounds which form MgCl2 in the presence of the alcohol solution to form a catalyst precursor solution is provided. Also provided are catalysts made from the precursors produced by the process. Also provided are polymers made using the catalysts.
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公开(公告)号:RU2377256C2
公开(公告)日:2009-12-27
申请号:RU2007108542
申请日:2005-06-24
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: BAN LASZLO L , WAGNER BURKHARD E , WHITED STEPHANIE M , KINNAN MICHAEL A , JORGENSEN ROBERT J , TURNER MICHAEL D
Abstract: Изобретениеотноситсяк композициипрокатализатора, способамполучениятакихкомпозицийи кспособамприменениятакихкомпозицийдляполученияполимеров. КомпозицияпрокатализатораЦиглера-Натта, предназначеннаядляполимеризацииолефиновв видетвердыхчастиц, включаетв качествекомпонентовмагний, галогениди переходнойметалл, причемуказанныечастицыимеютсреднийразмер (D50) от 10 до 70 мкм, иотличаетсятем, чтопоменьшеймере 5 процентовчастицимеютвнутренниепустоты, посуществуилиполностьюокруженныемонолитнымповерхностнымслоем (оболочкой), причемуказанныйслойотличаетсясреднимотношениемтолщиныоболочкик размеручастиц (относительнаятолщинапрофиля), определяемымметодомсканирующейэлектронноймикроскопии (СЭМ), котороедлячастицразмеромбольше 30 мкмпревышает 0,2. Способполучениявышеуказаннойкомпозициипрокатализаторавключаетэтапы: а) получениежидкойкомпозиции, содержащей i) галогенидноесоединениемагния, ii) растворительилиразбавитель, iii) соединениепереходногометалла, причемпереходнойметаллвыбранизметалловгрупп 3-10 Периодическойсистемыэлементови лантанидов, iv) необязательновнутреннийэлектронодонори v) такженеобязательнонаполнитель; b) распылительнуюсушкукомпозиции, чтобыполучитьвысушенныераспылениемчастицы; ис) сборполученныхтвердыхчастиц, иотличаетсятем, чтогалогенидноесоединениемагнияобразуетв растворителеилиразбавителепосуществунасыщенныйраствор, итем, чтодляполучениянастадии b) высушенныхраспылениемчастицопределенногов п.1 размерауказаннаяраспылительнаясушкаосуществляетсяпосредствомпропусканияжидкойкомпози
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公开(公告)号:MX2007001644A
公开(公告)日:2007-04-23
申请号:MX2007001644
申请日:2005-06-24
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: BAN LASZLO L , WAGNER BURKHARD E , WHITED STEPHANIE M , KINNAN MICHAEL A , JORGENSEN ROBERT J , TURNER MICHAEL D
Abstract: Se describe una composicion de procatalizador de Ziegler-Natta en la forma de particulas solidas y que comprende magnesio, haluro y porciones de metales de transicion, tales particulas tienen un tamano promedio (D50) desde 10 hasta 70 ?m, caracterizada porque al menos 5 por ciento de las particulas tienen volumen hueco interno sustancial o completamente encerrado por una capa de superficie monolitica (coraza), caracterizandose la capa por una proporcion de espesor de coraza/tamano de particula promedio (Proporcion de espesor) determinada mediante tecnicas de SEM para particulas con un tamano de `particula mayor que 30 ?m de mas de 0.2.
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公开(公告)号:CA2141474A1
公开(公告)日:1996-01-07
申请号:CA2141474
申请日:1995-01-31
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: DANIELL PAUL T , TILSTON MICHAEL W , SPRIGGS THOMAS E , WAGNER BURKHARD E , RAMAMURTHY ARAKALGUD V
IPC: C08J5/18 , C08F2/00 , C08F2/34 , C08F4/60 , C08F4/654 , C08F10/00 , C08F210/02 , C08F297/08 , C08L23/08 , C08L23/16 , C08F210/16 , C08F4/646
Abstract: A gas phase process for the production of a polyethylene blend comprising contacting ethylene and at least one alpha-olefin comonomer having 3 to 8 carbon atoms with a magnesium/titanium based catalyst system including an activator and a cocatalyst in each of two fluidized bed reactors connected in series, under polymerization conditions, with the provisos that: (a) the mixture of ethylene copolymer matrix and active catalyst formed in the first reactor in the series is transferred to the second reactor in the series; (b) other than the active catalyst referred to in proviso (a) and the cocatalyst referred to in proviso (e), no additional catalyst is introduced into the second reactor; (c) in the first reactor in which a low melt index copolymer is made: (1) the alpha-olefin is present in a ratio of about 0.01 to about 0.4 mole of alpha-olefin per mole of ethylene; (2) optionally, hydrogen is present in a ratio of about 0.001 to about 0.3 moles of hydrogen per mole of ethylene; and (3) the ethylene partial pressure is at least about 40 pounds per square inch; and (d) in the second reactor in which a high melt index copolymer is made: (1) the alpha-olefin is present in a ratio of about 0.01 to about 0.6 mole of alpha-olefin per mole of ethylene; (2) hydrogen is present in a ratio of about 1 to about 2.5 moles of hydrogen per mole of ethylene; and (3) diethyl zinc is added in an amount of about 2 to about 40 moles of diethyl zinc per mole of titanium; and (e) additional hydrocarbyl aluminum cocatalyst is introduced into the second reactor in an amount sufficient to restore the level of activity of the catalyst transferred from the first reactor to about the initial level of activity in the first reactor.
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公开(公告)号:CA2046023A1
公开(公告)日:1992-01-03
申请号:CA2046023
申请日:1991-07-02
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: WAGNER BURKHARD E , SAMUELS SARI-BETH , FREDERICK JOHN K
Abstract: D-16067 An improved ethylene polymerization process and catalyst system based on the use of a siliceous containing supported precursor of vanadium halide/electron donor complex, which utilizes chemisorption, as well as physisorption, of the catalyst to the support. This is effected by fixing the vanadium halide/electron donor complex in the support with a zinc alkyl compound that is chemisorbed to the support.
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公开(公告)号:MY142650A
公开(公告)日:2010-12-15
申请号:MYPI20044732
申请日:2004-11-12
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: ZOECKLER MARY T , KAO SUN-CHUEH , WAGNER BURKHARD E
IPC: C08F4/06 , C08F10/00 , C08F210/16
Abstract: A ZIEGLER-NATTA CATALYST COMPOSITION COMPRISING A SOLID MIXTURE FORMED BY HALOGENATION OF:@ A1) A SPRAY-DRIED CATALYST PRECURSOR COMPRISING THE REACTION PRODUCT OF A MAGNESIUM COMPOUND, A NON-METALLOCENE TITANIUM COMPOUND, AND AT LEAST ONE NON-METALLOCENE COMPOUND OF A TRANSITION METAL OTHER THAN TITANIUM, WITH@ A2) AN ORGANOALUMINIUM HALIDE HALOGENATING AGENT, A METHOD OF PREPARING, PRECURSORS FOR USE THEREIN, AND OLEFIN POLYMERIZATION PROCESSES USING THE SAME.
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