公开(公告)号：JP2013136837A

公开(公告)日：2013-07-11

申请号：JP2012277657

申请日：2012-12-20

Applicant: United Technologies Corp ,  ユナイテッド テクノロジーズ コーポレイションUnited Technologies Corporation

Inventor： ZIMMERMAN BENJAMIN JOSEPH ,  MALONEY MICHAEL J

IPC: C22C19/05 ,  C23C4/06 ,  C23C30/00 ,  F01D5/28 ,  F01D25/00 ,  F02C7/00

CPC classification number: C23C30/00 ,  C22C19/05 ,  C22C19/058 ,  C23C4/073 ,  C23C14/16 ,  Y10T428/12931

Abstract: PROBLEM TO BE SOLVED: To provide a coating which is compatible with a substrate material in a turbine engine components.SOLUTION: A part 10, such as the turbine engine component, has a substrate 11 to which a coating 12 which imparts oxidation resistance to the part 10 is applied, the coating being compatible with the material forming the part. If desired, the coating 12 may be applied directly to a surface 14 of the substrate. The substrate 11 may be formed from a wide range of metallic materials including, but not limited to, nickel-based and cobalt-based superalloys. For example, the substrate 11 may be a single crystal nickel-based superalloy. The coating 12 comprises from 11 to 14 wt.% chromium, from 11 to 14 wt.% cobalt, from 7.5 to 9.5 wt.% aluminum, from 0.20 to 0.60 wt.% yttrium, from 0.10 to 0.50 wt.% hafnium, from 0.10 to 0.30 wt.% silicon, from 0.10 to 0.20 wt.% zirconium, and the balance comprising nickel.

Abstract translation: 要解决的问题：提供一种与涡轮发动机部件中的基板材料相容的涂层。解决方案：诸如涡轮发动机部件的部件10具有基板11，向基板11施加耐腐蚀性的涂层12 应用第10部分，涂层与形成部件的材料相容。 如果需要，涂层12可以直接施加到基底的表面14。 基板11可以由宽范围的金属材料形成，包括但不限于镍基和钴基超级合金。 例如，基板11可以是单晶镍基超级合金。 涂层12包含11至14重量％的铬，11至14重量％的钴，7.5至9.5重量％的铝，0.20至0.60重量％的钇，0.10至0.50重量％的铪，来自 0.10至0.30重量％的硅，0.10至0.20重量％的锆，余量包含镍。

公开(公告)号：JP2003268569A

公开(公告)日：2003-09-25

申请号：JP2003033955

申请日：2003-02-12

Applicant: UNITED TECHNOLOGIES CORP

Inventor： GUPTA DINESH ,  LAMBERT DAVID L ,  TRUBELJA MLADEN F ,  MALONEY MICHAEL J ,  ULION NICHOLAS E ,  LITTON DAVID A

IPC: C23C14/16 ,  C23C4/02 ,  C23C4/10 ,  C23C14/30 ,  C23C28/00 ,  C23C28/04 ,  C23C30/00 ,  F01D5/28

Abstract: PROBLEM TO BE SOLVED: To provide a superalloy article having a thermal barrier coating film. SOLUTION: The article comprises a superalloy substrate, an adherent alumina layer on the substrate, and a ceramic, thermally insulating layer on the alumina layer. The ceramic layer has an overall thickness and comprises relatively strain tolerant columnar grain ceramic on the alumina layer and relatively more thermally insulating ceramic on the columnar grain ceramic. The alumina layer may be formed using an alumina forming layer such as an overlay or aluminide bond coat, or the superalloy may be constituted of a material capable of forming an alumina layer. The ceramic layers may be formed of a stabilized zirconia or other suitable material and may have the same or different compositions. COPYRIGHT: (C)2003,JPO

公开(公告)号：JP2001225411A

公开(公告)日：2001-08-21

申请号：JP2000373775

申请日：2000-12-08

Applicant: UNITED TECHNOLOGIES CORP

Inventor： MALONEY MICHAEL J

IPC: F01D5/28 ,  B32B9/00 ,  B32B15/04 ,  C23C14/06 ,  C23C14/08 ,  C23C14/54 ,  F01D11/08 ,  F02C7/00 ,  F02C7/28

Abstract: PROBLEM TO BE SOLVED: To enhance heat insulating characteristics by correcting the intrinsic heat insulating characteristics of a ceramic coating for heat resistance, that is, the density thereof. SOLUTION: In a method for manufacturing the layered ceramic coating wherein some layers are porous, a heat protecting barrier wall is cyclycally inserted in the gap between a heat source and an evaporation source or external heater under different temperature conditions to be coated with different layers. As coating advances, some layers have a zone I structure and some layers have a zone II structure. In order to increase the porosity of the layers having the zone I structure, heat treatment can be also applied.

公开(公告)号：JPH11264059A

公开(公告)日：1999-09-28

申请号：JP32621398

申请日：1998-11-17

Applicant: UNITED TECHNOLOGIES CORP

Inventor： MALONEY MICHAEL J

IPC: F01D5/28 ,  B21D39/00 ,  B32B3/26 ,  B32B18/00 ,  C04B38/00 ,  C23C4/04 ,  C23C14/06 ,  C23C14/08 ,  C23C16/00 ,  C23C28/00 ,  C23D5/04 ,  F02C7/00

Abstract: PROBLEM TO BE SOLVED: To reduce thermal conductivity and improve wear resistance by making at least one layer of a layer like ceramic coating applied on a base body of high density and making at least one of other layer low density. SOLUTION: At least one layer of a porous ceramic layer coated on a base body is a porous layer having at least a volume porosity rate of about 20%, and one of other layer is substantially a non porosity layer having a volume porosity rate of about 5%. The ceramic material on a base body is obtained so that plural ceramic layers are vapor deposited and heat treated under conditions consequentially that at least one layer has a micro structure of a band region I and at least one of other layer has a micro structure selected from band regions II, III and a group of these combinations. A porous layer preferably includes a layer made of celia for a base material and a layer made of zirconia for a base material.

公开(公告)号：JP2003201586A

公开(公告)日：2003-07-18

申请号：JP2002372750

申请日：2002-12-24

Applicant: UNITED TECHNOLOGIES CORP

Inventor： MALONEY MICHAEL J

IPC: B32B9/00 ,  C23C4/10 ,  C23C14/08 ,  C23C28/00 ,  C23C28/04 ,  C23C30/00 ,  F01D5/28 ,  F02K1/82 ,  F23R3/00

Abstract: PROBLEM TO BE SOLVED: To provide a ceramic material having particular utility as a thermal insulating or thermal barrier coating on metallic substrates. SOLUTION: The ceramic material 20 includes gadolinia and hafnia, preferably forming gadolinia-hafnia. This material 20 exhibits chemical stability, thermal stability and thermal insulating properties superior to those of currently used thermal barrier ceramics, and also provides resistance to sintering and erosion comparable to currently used ceramics. A preferred material has been about 3-70 mol.% hafnia, balance hafnia. COPYRIGHT: (C)2003,JPO

公开(公告)号：JP2001240473A

公开(公告)日：2001-09-04

申请号：JP2000388094

申请日：2000-12-21

Applicant: UNITED TECHNOLOGIES CORP

Inventor： MALONEY MICHAEL J ,  ANTON DONALD ,  SHAH DILIP

IPC: F01D5/28 ,  B32B15/01 ,  C04B35/58 ,  C04B41/85 ,  C22C27/04 ,  C22C29/18 ,  C23C30/00 ,  F02C7/00 ,  H05B3/14

Abstract: PROBLEM TO BE SOLVED: To obtain a molybdenum disilicide (MoSi2) material which is hardy pasting. SOLUTION: The MoSi2 alloy which is hardly pasting contains Re. When Re is added to the alloy, a thin protecting film is formed which suppresses the decomposition caused by pasting. The amount of Re necessary to eliminate the pasting is 2-50% of Mo+Re based on atomic reference system, preferably 5-40% of total of Mo+Re. A compositional formula explaining the wide range of composition of this invention is (MoaRebXc) (SidZc), wherein a: a+b+c=1, b: d+e=2, c: b=0.02-0.5, d: X is actually to be selected the group consisting of Cr, Ti, Fe, Co, Ni and their mixtures, e: c=0-0.2, f: Z is actually to be selected from the group consisting of B, Ge, Al, Ga, Sn, Sb, Bi and their mixtures, g: d=1.8-2.0, h:e=0-0.2.

公开(公告)号：JP2000160324A

公开(公告)日：2000-06-13

申请号：JP19250299

申请日：1999-07-07

Applicant: UNITED TECHNOLOGIES CORP

Inventor： MALONEY MICHAEL J

IPC: F02C7/00 ,  C23C14/08 ,  C23C14/24 ,  C23C14/30 ,  C23C14/32 ,  C23C14/34 ,  C23C28/00 ,  F01D5/28

Abstract: PROBLEM TO BE SOLVED: To produce a member having improved ceramic thermal barrier coating(TBC). SOLUTION: A member 10 contains a base material 12 of a superalloy and an adhesive alumina layer 16 formed on the surface of the base material. This member furthermore contains a ceramic layer, i.e., a thermal barrier coating 18 applied on the alumina layer 16 and forming columnar crystals. Desirably, the coating 18 is composed of a substantially uniform mixture of two materials, e.g. of yttria and ceria, wherein the content of yttria is controlled to at least about 5 wt.%, and ceria constitutes the rest. For increasing the adhesion of the thermal barrier coating 18, the member 10 may contain an intermediate bond coat 17 of ceramic such as yttria stabilized zirconia or the like.

公开(公告)号：JP2000144388A

公开(公告)日：2000-05-26

申请号：JP20400699

申请日：1999-07-19

Applicant: UNITED TECHNOLOGIES CORP

Inventor： MALONEY MICHAEL J

IPC: F02C7/00 ,  C23C14/08 ,  C23C14/24 ,  C23C14/30 ,  C23C14/32 ,  C23C14/34 ,  C23C28/00 ,  F01D5/28

Abstract: PROBLEM TO BE SOLVED: To provide a member having a ceramic TBC(thermal barrier coating) of low thermal conductivity. SOLUTION: A member 10 contains a base material 12 composed of a superalloy and an adhesive alumina layer 16 formed on the surface of the base material 12. The member 10 also contains a ceramic layer, that is, a thermal barrier coating 18 forming columnar crystals and applied to the alumina layer 16. The coating 18 is constituted of a practically uniform mixture of two materials, e.g. yttria and ceria, and it is desirable that this coating 18 has a composition consisting of at least about 5 wt.% of yttria and the balance ceria. Further, this member 10 can also contain an intermediate bond coat 17 composed of ceramics such as yttria-strengthened zirconia in order to improve the adhesion of the thermal barrier coating 18.

公开(公告)号：JP2000119870A

公开(公告)日：2000-04-25

申请号：JP28166599

申请日：1999-10-01

Applicant: UNITED TECHNOLOGIES CORP

Inventor： MALONEY MICHAEL J

IPC: C23C4/00 ,  C01B13/14 ,  C23C4/10 ,  C23C14/08 ,  C23C16/00 ,  C23C28/00 ,  C23C28/04 ,  C23C30/00 ,  F01D5/28 ,  F02K1/82 ,  F23R3/00

Abstract: PROBLEM TO BE SOLVED: To improve the heat insulating properties per unit coating density in a member by incorporating gadolinia and zirconia into ceramic coating on the surface of a substrate made of metal and allowing it to have cubic crystals. SOLUTION: On the outside surface of a superalloy substrate 10, heat insulating coating composed of a pyrochlore top coat 20 is formed. This pyrochlore top coat 20 is composed of about 5 to 60 mol% gadolinia, and the balance gadolinia zirconia oxide containing zirconia and has cubic crystals. In the case of use for a turbine engine, the opposite side face 11 of the superalloy substrate 10 is cooled by cooling air, the outside surface 21 (exposed face) of the pyrochlore structural body is exposed to a high temp., plural holes communicating the outside surface 21 with the opposite side face 11 are provided, and the cooling air is allowed to flow from the oposite side face 11 to the outside surface 21. The substrate made of a metal is selected from the groups consisting of steel, superalloys, titanium alloys and copper alloys.

公开(公告)号：WO2014144189A1

公开(公告)日：2014-09-18

申请号：PCT/US2014028489

申请日：2014-03-14

Applicant: UNITED TECHNOLOGIES CORP

Inventor： HAZEL BRIAN T ,  MALONEY MICHAEL J ,  NEAL JAMES W ,  LITTON DAVID A

IPC: C23C14/22

CPC classification number: C23C14/30 ,  C23C14/228 ,  C23C14/243 ,  C23C14/246 ,  C23C14/505

Abstract: A deposition apparatus (20) comprising: a chamber (22); a process gas source (62) coupled to the chamber; a vacuum pump (52) coupled to the chamber; at least two electron guns (26); one or more power supplies (30) coupled to the electron guns; a plurality of crucibles (32,33,34) positioned or positionable in an operative position within a field of view of at least one said electron gun; and a part holder (170) having at least one operative position for holding parts spaced above the crucibles by a standoff height H. The standoff height H is adjustable in a range including at least 22 inches.

Abstract translation: 一种沉积设备（20），包括：腔室（22）; 耦合到所述室的处理气体源（62）; 耦合到所述室的真空泵（52）; 至少两个电子枪（26）; 耦合到电子枪的一个或多个电源（30）; 多个坩埚（32,33,34），其定位或定位在至少一个所述电子枪的视场内的操作位置; 以及具有至少一个操作位置的部件保持器（170），用于将间隔在坩埚上方的部件保持在间隔高度H上。间隔高度H在包括至少22英寸的范围内是可调节的。