公开(公告)号：EP1756658A4

公开(公告)日：2009-11-04

申请号：EP05724370

申请日：2005-03-01

Applicant: UNIV WASHINGTON

Inventor： LIU LU ,  XU CHUNYE ,  LEGENSKI SUSAN ,  TAYA MINORU

IPC: G02F1/15 ,  C08G61/12 ,  C09K9/02

CPC classification number: G02F1/15 ,  C08G61/124 ,  C08G61/126 ,  C09K9/02 ,  C09K2211/1458 ,  G02F1/155 ,  G02F2001/133374 ,  G02F2001/1515

公开(公告)号：WO2005084350A3

公开(公告)日：2007-03-01

申请号：PCT/US2005006806

申请日：2005-03-01

Applicant: UNIV WASHINGTON ,  LU LIU ,  XU CHUNYE ,  LEGENSKI SUSAN ,  TAYA MINORU

Inventor： LIU LU ,  XU CHUNYE ,  LEGENSKI SUSAN ,  TAYA MINORU

IPC: G02F1/15

CPC classification number: G02F1/15 ,  C08G61/124 ,  C08G61/126 ,  C09K9/02 ,  C09K2211/1458 ,  G02F1/155 ,  G02F2001/133374 ,  G02F2001/1515

Abstract: Syntheses of a new blue EC monomer (ProDOT-MePro), and a new red EC monomer (ProDOP-Et2) are described. Two additional new types of EC monomers (15) based on 3,4-alkylenedioxythiophene include fluorinated EC monomers (15) and an EC monomer including silicon. EC polymer devices having more than one different color EC polymer to enable additional colors to be provided using subtractive color mixing are also described, as well as EC polymer devices incorporating a logo, image, or text, are generally obscured when the device is colored, but become visible when the device is not colored. Also described are EC polymer devices that include a cathodic EC polymer layer, a gel electrolyte, a counter electrode, and reference electrode. Working prototypes of such devices exhibit significant increases in the speed of transition of the EC device from a colored state to a transparent state.

Abstract translation: 描述了新的蓝色EC单体（ProDOT-MePro）和新的红色EC单体（ProDOP-Et2）的合成。 基于3,4-亚烷基二氧噻吩的另外两种新型EC单体（15）包括氟化EC单体（15）和包含硅的EC单体。 还描述了具有多于一种不同颜色的EC聚合物的EC聚合物装置，以使得能够使用减色混合来提供附加的颜色，以及包含标志，图像或文本的EC聚合物装置在装置着色时通常是模糊的， 但当设备未着色时变得可见。 还描述了EC聚合物装置，其包括阴极EC聚合物层，凝胶电解质，对电极和参比电极。 这种装置的工作原型表现出EC装置从有色状态转变为透明状态的速度的显着增加。

公开(公告)号：WO2006029344A3

公开(公告)日：2007-04-05

申请号：PCT/US2005032211

申请日：2005-09-09

Applicant: UNIV WASHINGTON ,  LIU LU ,  XU CHUNYE ,  TAYA MINORU ,  NING DAI ,  KANEKO CALEN

Inventor： LIU LU ,  XU CHUNYE ,  TAYA MINORU ,  NING DAI ,  KANEKO CALEN

IPC: G02F1/15

CPC classification number: C09K9/02 ,  C07D495/04 ,  C09K2211/1051 ,  C09K2211/1092 ,  G03C1/73

Abstract: Three green EC materials based on thiophene, and a green EC material based on pyrazine are disclosed. A first thiophene derivative (2,3-Di-thiophen-2-yl-thieno[3,4-b]pyrazine), which was previously investigated as a nonlinear optical material, is here disclosed for its use as an EC material, and for its incorporation into an EC device. Synthesis of two new thiophene derivatives (2,5-di(thien-2-yl)-3,4-di(2,2,2-trifluoro-ethoxy)-thiophene and 2,5-(2,3-dihydro-thieno[3,4-b][1,4]dioxin-5-yl)-3,4-di(2,2,2-trifluoro-ethoxy)-thiophene), and a new pyrazine derivative (2,3-dibenzyl-5,7-di(thien-2-yl) thieno[3,4-b]pyrazine) are also disclosed, since these materials are all able to selectively change to a green color state, and can be polymerized to achieve a green EC polymer.

Abstract translation: 公开了基于噻吩的三种绿色EC材料和基于吡嗪的绿色EC材料。 作为非线性光学材料，先前研究过的第一噻吩衍生物（2,3-二噻吩-2-基 - 噻吩并[3,4-b]吡嗪）在此被公开用于EC材料，以及 将其并入EC设备。 合成两种新的噻吩衍生物（2,5-二（噻吩-2-基）-3,4-二（2,2,2-三氟 - 乙氧基） - 噻吩和2,5-（2,3-二氢 - 噻吩并[3,4-b] [1,4]二恶英-5-基）-3,4-二（2,2,2-三氟 - 乙氧基） - 噻吩）和新的吡嗪衍生物 还公开了二苄基-5,7-二（噻吩-2-基）噻吩并[3,4-b]吡嗪），因为这些材料都能够选择性地变为绿色状态，并且可以聚合以实现 绿色EC聚合物。

公开(公告)号：WO2005050294A3

公开(公告)日：2006-04-06

申请号：PCT/US2004038888

申请日：2004-11-18

Applicant: UNIV WASHINGTON ,  XU CHUNYE ,  LIU LU ,  TAYA MINORU

Inventor： XU CHUNYE ,  LIU LU ,  TAYA MINORU

IPC: C09K9/02 ,  G02F20060101 ,  G02F1/15

CPC classification number: C09K9/02 ,  C08G61/123 ,  C08G61/124 ,  C08G61/126 ,  C09K2211/1029 ,  C09K2211/1096 ,  C09K2211/1458 ,  C09K2211/1466 ,  C09K2211/1491 ,  G01N21/553 ,  G02F1/155 ,  G02F2001/1515 ,  G02F2001/1555

Abstract: Electropolymerization of EC monomers is employed to obtain an EC polymer film deposited on a substrate. A first embodiment of a method to produce the film employs cyclic voltammetry alone, while a second embodiment (212) deposits a very thin homogeneous layer using chronoamperometry (216), and then cyclic voltammetry is employed to increase the density of the film (218). Another aspect of the present invention is directed to specific web like configurations for a grid of conductive material deposited onto a transparent substrate. The web like configuration is based either on concentric circles, or on concentric ellipses. Yet another aspect of the present invention is directed to an imaging system including a digital window that is disposed between a prism and a patterned analytic layer.

Abstract translation: 使用EC单体的电聚合来获得沉积在基底上的EC聚合物膜。 制造薄膜的方法的第一实施例单独使用循环伏安法，而第二实施例（212）使用计时电流法（216）沉积非常薄的均匀层，然后使用循环伏安法来增加膜（218）的密度， 。 本发明的另一方面涉及沉积在透明基底上的导电材料格栅的具体网状结构。 网状配置基于同心圆或同心椭圆。 本发明的另一方面涉及一种成像系统，其包括设置在棱镜和图案化分析层之间的数字窗口。

公开(公告)号：CA2549705A1

公开(公告)日：2005-09-15

申请号：CA2549705

申请日：2005-03-01

Applicant: UNIV WASHINGTON

Inventor： LEGENSKI SUSAN ,  LIU LU ,  TAYA MINORU ,  XU CHUNYE

IPC: C07D495/04 ,  C07D491/044 ,  C07F7/08 ,  G02F1/15 ,  G02F1/153

Abstract: Syntheses of a new blue EC monomer (ProDOT-MePro), and a new red EC monomer (ProDOP-Et2) are described. Two additional new types of EC monomers based on 3, 4-alkylenedioxythiophene include fluorinated EC monomers and an EC monome r including silicon. EC polymer devices having more than one different color E C polymer to enable additional colors to be provided using subtractive color mixing are also described, as well as EC polymer devices incorporating a log o, image, or text, are generally obscured when the device is colored, but becom e visible when the device is not colored. Also described are EC polymer device s that include a cathodic EC polymer layer, a gel electrolyte, a counter electrode, and a reference electrode. Working prototypes of such devices exhibit significant increases in the speed of transition of the EC device fr om a colored state to a transparent state.