Abstract:
A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron sulfide crystallites have diameters in the nanometer range.
Abstract:
A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron oxide and alumina catalyst does not require as much iron content relative to non-gaseous material in the reactor to obtain useable products.
Abstract:
The invention relates to a process for converting heavy hydrocarbonaceous feedstocks carried out in a slurry reactor in the presence of hydrogen and in the presence of a catalytic composition obtained by: injecting a catalytic precursor of at least one metal of Group VIB and/or Group VIII in at least part of the feedstock to be treated in the absence of an oxide substrate, thermal treatment at a temperature of 400° C. or below, in the presence of H2S so as to form the dispersed sulphur-containing catalyst, bringing said catalyst into contact with particles of alumina oxide free from silica, said oxide particles having a polymodal porous structure composed of a plurality of juxtaposed agglomerates and each formed from a plurality of acicular platelets, the platelets of each agglomerate being oriented radially in relation to one another and relative to the centre of the agglomerate, said particles having an irregular non-spherical shape and being mainly in the form of fragments obtained by crushing with alumina balls, introducing the catalyst composition obtained into the reactor.
Abstract translation:本发明涉及一种在氢气存在下,在淤浆反应器中进行的重质烃类原料的转化和催化剂组合物的存在下进行转化的方法,所述催化组合物通过以下方法获得:注入至少一种VIB族金属和/或VIII族金属的催化前体 在不存在氧化物衬底的待处理的原料的至少一部分中,在H 2 S 2 S的存在下在400℃或更低的温度下进行热处理,以形成 分散的含硫催化剂,使所述催化剂与不含二氧化硅的氧化铝颗粒接触,所述氧化物颗粒具有由多个并置的附聚物组成的多晶型多孔结构,并且各自由多个针状血小板形成,每个附聚物的血小板 相对于彼此并且相对于附聚物的中心径向取向,所述颗粒具有不规则的非球形并且主要以碎屑形式 通过用氧化铝球破碎获得的,将所得催化剂组合物引入反应器中。
Abstract:
A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.
Abstract:
Olefins are reacted with carbon monoxide and hydrogen to produce aldehydes to the near exclusion of alcohols in the presence of a solid phase catalyst consisting essentially of one or more sulfided Group VIII metals.
Abstract:
Toxic substances contained in exhaust gases, especially nitrogen oxides contained in exhaust gases from automobiles, can be effectively eliminated, even in the presence of oxygen, by contacting such exhaust gases with a catalyst composition comprising iron or iron oxide, silver or silver oxide, at least a member selected from the group consisting of copper, beryllium, zinc, lead, indium, lanthanum, cerium and oxides of these metals, and a carrier. Especially good results can be obtained by employing a catalyst composition obtained by treating a composition comprising iron or iron oxide, silver or silver oxide, copper or copper oxide and a carrier with hydrogen sulfide, or by employing a catalyst composition comprising sulfides of iron, silver and copper supported on a carrier.
Abstract:
A SELECTIVE PROCESS FOR THE CONTINUOUS DEHYDROGENATION OF NONAROMATIC C3-C5 HYDROCARBONS TO DERIVATIVES HAVING A HIGHER DEGREE OF UNSATURATION COMPRISING PASSING A MIX TURE OF THE HYDROCARBON, STEAM AND H2S THROUGH A SULFIDED METAL CATALYST AT A CONVERSION BELOW ABOUT 70%.
Abstract:
A process for dehydrogenating an alkane to form an olefin by passing it over a catalyst comprising nickel or cobalt sulfide and cerium oxide alone or in combination with barium oxide, preferably on an alumina support, at a temperature of from about 550* to 625* C. and recovering the olefin.