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公开(公告)号:US10557092B2
公开(公告)日:2020-02-11
申请号:US15643893
申请日:2017-07-07
Applicant: ExxonMobil Research and Engineering Company
Inventor: Jason T. Calla , Will G. Fisher, Jr. , Eric D. Joseck , Seth D. Fortney
Abstract: Systems and methods are provided for production of base stocks with a viscosity index of at least 120 and/or a sulfur content of 300 wppm or less and/or a kinematic viscosity at 100° C. of 3.0 cSt to 8.0 cSt by hydroconversion of a raffinate from aromatic extraction of a feed. The base stocks can further have a reduced content of 3+ ring naphthenes, such as 4.0 wt % or less, or 1.0 wt % or less. The base stocks can be produced by performing an elevated amount of feed conversion relative to 370° C. during hydroconversion of the raffinate, and optionally additional conversion during catalytic dewaxing of the hydroconverted raffinate. The base stocks can optionally be blended with additional base stocks and/or lubricant additives for production of lubricant compositions.
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公开(公告)号:US10544239B2
公开(公告)日:2020-01-28
申请号:US14966015
申请日:2015-12-11
Applicant: ExxonMobil Research and Engineering Company
Inventor: Quanchang Li , David Charles Calabro , Mobae Amin Afeworki , Simon Christopher Weston , Matcheld Maria Wilfried Mertens , Tilman Wolfram Beutel , Wenyih Frank Lai , Paul Podsiadlo , Jean Willem Lodewijk Beeckman
IPC: C10G45/52 , B01D15/00 , C08F10/02 , B01J31/06 , B01J35/10 , C08G77/58 , C08G77/50 , B01J20/08 , B01J20/28 , B01J37/03 , B01J20/06 , B01J20/10 , B01J20/26 , B01J20/286 , B01J20/30 , B01J20/32 , B01D53/22 , B01J23/42 , B01J31/12 , C01B37/00 , C01B39/00 , C08G77/60 , C08F2/00 , C08F2/10 , C08F2/42 , C10G25/00 , C10G35/06 , C10G45/00 , C10G45/04 , C10G45/34 , C10G45/44 , C10G45/46 , C10G45/60 , C10G45/64 , C10G47/02 , C10G50/00 , C10M177/00 , C10K1/32 , B01J29/03 , B01D53/04 , B01D53/047 , B01D53/02 , B01J23/44 , C10M101/02 , C07F7/00 , C08F4/659 , C08F4/6592
Abstract: Organosilica materials, which are a polymer of at least one independent monomer of Formula [Z1OZ2OSiCH2]3 (I), wherein each Z1 and Z2 independently represent a hydrogen atom, a C1-C4 alkyl group or a bond to a silicon atom of another monomer and at least one other trivalent metal oxide monomer are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for catalysis etc., are also provided herein.
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公开(公告)号:US20200002625A1
公开(公告)日:2020-01-02
申请号:US16567218
申请日:2019-09-11
Applicant: ExxonMobil Research and Engineering Company
Inventor: Benjamin S. Umansky , Keith K. Aldous , James W. Gleeson , Edward J. Blok , Richard A. Demmin
Abstract: Systems and methods are provided for producing upgraded raffinate and extract products from lubricant boiling range feeds and/or other feeds having a boiling range of 400° F. (204° C.) to 1500° F. (816° C.) or more. The upgraded raffinate and/or extract products can have a reduced or minimized concentration of sulfur, nitrogen, metals, or a combination thereof. The reduced or minimized concentration of sulfur, nitrogen, and/or metals can be achieved by hydrotreating a suitable feed under hydrotreatment conditions corresponding to relatively low levels of feed conversion. Optionally, the feed can also dewaxed, such as by catalytic dewaxing or by solvent dewaxing. Because excessive aromatic saturation is not desired, the pressure for hydrotreatment (and optional dewaxing) can be 500 psig (˜3.4 MPa) to 1200 psig (˜8.2 MPa).
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公开(公告)号:US10518257B2
公开(公告)日:2019-12-31
申请号:US15969062
申请日:2018-05-02
Applicant: ExxonMobil Research and Engineering Company
Inventor: Joseph M. Falkowski , Mobae Afeworki , Simon C. Weston
Abstract: A novel metal organic framework, EMM-33, is described having the structure of UiO-67 and comprising bisphosphonate linking ligands. EMM-33 has acid activity and is useful as a catalyst in olefin isomerization. Also disclosed is a process of making metal organic frameworks, such as EMM-33, by heterogeneous ligand exchange, in which linking ligands having a first bonding functionality in a host metal organic framework are exchanged with linking ligands having a second different bonding functionality in the framework.
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公开(公告)号:US10513475B2
公开(公告)日:2019-12-24
申请号:US15839974
申请日:2017-12-13
Applicant: ExxonMobil Research and Engineering Company
Inventor: Sophie Liu , Jihad M. Dakka , Partha Nandi , Sara Yacob , Quddus A. Nizami , Chuansheng Bai
IPC: C07C2/86 , C07C2/62 , C07C29/50 , C07C1/24 , C07C31/12 , C07C31/125 , B01J29/70 , C07C5/02 , C07C29/132 , C07C2/12 , C07C5/03 , C07C5/27 , C07C407/00 , C10G45/58 , C10G50/00 , C10G69/12 , C10G3/00 , B01J29/80 , B01J29/50
Abstract: Methods and systems for converting hydrocarbons including exposing a portion of a hydroperoxide-containing feed including tert-butyl hydroperoxide to a solid deperoxidation catalyst under decomposition conditions to form an oxidation effluent comprising tert-butyl alcohol, wherein the solid deperoxidation catalyst comprises a manganese oxide octahedral molecular sieve, are provided herein. Further methods and systems for converting the oxidation effluent to an alkylation product are also provided herein.
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公开(公告)号:US20190383784A1
公开(公告)日:2019-12-19
申请号:US16430832
申请日:2019-06-04
Applicant: ExxonMobil Research and Engineering Company
Inventor: Joseph W. Krynicki , Neeraj S. Thirumalai , Lujian Peng
IPC: G01N33/207
Abstract: A pipeline inspection assembly includes a test pipe including at least one weld and one or more synthetic weld flaws, and a pipeline inspection device mountable to the test pipe and movable relative thereto. The pipeline inspection device includes a detection device operable to detect the one or more synthetic weld flaws as the pipeline inspection device moves along a length of the test pipe. A performance of the pipeline inspection device is assessed based on a comparison of a detected characteristic of the one or more synthetic weld flaws and a known characteristic of the one or more synthetic weld flaws.
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107.
公开(公告)号:US20190382664A1
公开(公告)日:2019-12-19
申请号:US16425255
申请日:2019-05-29
Applicant: ExxonMobil Research and Engineering Company
Inventor: Stuart E. Smith , Eric B. Sirota , Stephen H. Brown
IPC: C10C3/08
Abstract: Methods are provided for reducing or minimizing the temperature dependence of a pitch feed or fraction for use in carbon fiber production, such as a mesophase pitch feed or fraction or an isotropic pitch feed or fraction. A pitch sample can be characterized to determine a characteristic temperature and a characteristic viscosity for the sample. One or more solvent extraction processes can also be performed on the pitch and/or the extract and raffinate fractions formed by the solvent extraction(s). The resulting raffinate and extract fractions are then used to form a modified pitch fraction with a T0 value that is lower than the T0 value of the original pitch. The modified pitch fraction can optionally also have a different ηinf value relative to the original pitch.
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公开(公告)号:US20190367824A1
公开(公告)日:2019-12-05
申请号:US16540123
申请日:2019-08-14
Applicant: ExxonMobil Research and Engineering Company
IPC: C10G69/02 , C10M101/02
Abstract: Disclosed are Group III base stocks comprising greater than or equal to about 90 wt. % saturated hydrocarbons (saturates); a viscosity index from 120 to 145; a unique ratio of molecules with multi-ring naphthenes to single ring naphthenes (2R+N/1RN); a unique ratio of branched carbons to straight chain carbons (BC/SC); a unique ratio of branched carbons to terminal carbons (BC/TC); and unique MRV behavior as a function of base stock naphthene ratio (2R+N/1RN). A method for preparing the base stocks is also disclosed. Also disclosed is a lubricating oil having the base stock as a major component, and an additive as a minor component.
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109.
公开(公告)号:US20190352694A1
公开(公告)日:2019-11-21
申请号:US16407446
申请日:2019-05-09
Applicant: ExxonMobil Research and Engineering Company
Inventor: Giovanni Pilloni , Zarath M. Summers
Abstract: A method for identifying in situ presence of a hydrocarbon reservoir or of a pipeline leakage is disclosed. The method can include obtaining a sample from an area of interest, such as a sediment sample or water column sample near a hydrocarbon seep or near an offshore pipeline; analyzing the sample to detect nucleic acid, protein or metabolite signatures that are indicative of cold-shock response; identifying the relative abundance of the cold-shock signatures present in the sample in comparison to the surrounding environment.
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公开(公告)号:US20190338203A1
公开(公告)日:2019-11-07
申请号:US16512601
申请日:2019-07-16
Applicant: ExxonMobil Research and Engineering Company
Inventor: Benjamin S. UMANSKY , Himanshu GUPTA , John D. NELSON , Cindy J. HUGHART , Jane C. CHENG , Steven W. LEVINE , Stephen H. BROWN , Todd P. MARUT , David C. DANKWORTH , Stuart L. SOLED , Thomas F. DEGNAN, JR. , Robert J. FALKINER , Mohsen N. HARANDI , Juan D. HENAO , Lei ZHANG , Chuansheng BAI , Richard C. DOUGHERTY
IPC: C10G65/12 , B01J23/882 , C10G67/14 , C10G45/16 , C10G31/09 , C10G45/08 , B01J27/19 , B01J35/10 , C10G47/04 , B01J23/885
Abstract: Systems and methods are provided for hydroconversion of a heavy oil feed under slurry hydroprocessing conditions and/or solvent assisted hydroprocessing conditions. The systems and methods for slurry hydroconversion can include the use of a configuration that can allow for improved separation of catalyst particles from the slurry hydroprocessing effluent. In addition to allowing for improved catalyst recycle, an amount of fines in the slurry hydroconversion effluent can be reduced or minimized. This can facilitate further processing or handling of any “pitch” generated during the slurry hydroconversion. The systems and methods for solvent assisted hydroprocessing can include processing of a heavy oil feed in conjunction with a high solvency dispersive power crude.
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