Paraffin hydrocarbon isomerization process
    112.
    发明授权
    Paraffin hydrocarbon isomerization process 失效
    巴拉芬烃异构化方法

    公开(公告)号:US3803263A

    公开(公告)日:1974-04-09

    申请号:US30903972

    申请日:1972-11-24

    Inventor: SCHNEIDER A MOORE R

    CPC classification number: C07C5/2727 C07C9/00

    Abstract: PARAFFINS RANGING FROM C6 TO AND INCLUDING SOLID PARAFFINS ARE ISOMERIZED BY CONTACTING THE PARAFFINIC FEED IN LIQUID PHASE, PREFERABLY AT 10-80*C. WITH AN ADMIXTURE OF ALCL3 AND A PARTIALLY DEHYDRATED ADSORBENT COMPRISING ALUMINA, SILICA OR ALUMINSOLICATE HAVING CERTAIN PORE SIZE AND SURFACE AREA CHARACTERISTICS, IN THE PRESENCE OF AN ADAMANTANOID SUPRESSOR SELECTTED FROM ADAMANTANE, ALKHYLADAMANTANES, DIAMANTANE AND MONOALKYLDIAMANTANES. THESE ADAMANTANOID SUPPRESSORS HAVE BEEN FOUND TO BE HIGHLY EFFECTIVE IN SUPPRESSING UNDERSIRABLE SIDE REACTIONS WHILE ALLOWING THE ISOMERIZATION REACTION TO PROCEED. PREFERABLY A MINOR AMOUNT OF HCL OR SATURATED HALOHYDROCARBON IS ALSO PRESENT AS A PROMOTER, THE COMBINATION OF ALCL3, THE ADSORBENT AND THE HCL OR HALOHYDROCARBON PROMOTER RESULTS IN A HIGHLY ACTIVE ISOMERIZATION CATALYST.

    Haloadamantanes
    114.
    发明授权
    Haloadamantanes 失效
    胭脂红素

    公开(公告)号:US3784615A

    公开(公告)日:1974-01-08

    申请号:US3784615D

    申请日:1971-09-20

    Inventor: MOORE R

    CPC classification number: C07C17/10 C07C23/38

    Abstract: HALOGENATED DERIVATIVES CONTAINING ADAMANTANE NUCLEUS ARE PRODUCED BY ADMIXING, IN THE PRESENCE OF STRONG SULFURIC ACID, ADAMANTANE OR ALKYL-SUBSTITUTED ADAMANTANT WITH A SELECTED HALO-YIELDING SALT OF AN ALKALI OR ALKALINE EARTH METAL, OR A CORRESPONDING HYDROGEN HALIDE.

    Polysulfone polymers from adamantane bisphenols
    116.
    发明授权
    Polysulfone polymers from adamantane bisphenols 失效
    来自ADAMANTANE BISPHENOLS的聚苯乙烯聚合物

    公开(公告)号:US3738960A

    公开(公告)日:1973-06-12

    申请号:US3738960D

    申请日:1971-12-30

    Inventor: THOMPSON R DULING I

    CPC classification number: C08G75/23

    Abstract: NOVEL SOLID POLYSULFONES HAVING THE STRUCTURE:

    -((1,4-PHENYLENE)-(1-R1,5-R2-ADAMANTAN-7,3-YLENE)-(1,4-

    PHENYLENE)-O-(1,4-PHENYLENE)-SO2-(1,4-PHENYLENE)-O)N-

    WHERE R1 AND R2 ARE HYDROGEN OR HYDROCARBLY RADICALS HAVING 1 TO 20 CARBON ATOMS AND N REPRESENTS THE NUMBER OF SUCH REPEATING UNITS WHICH ARE PRODUCED. THESE THERMOPLASTIC RESINS HAVE EXCEPTIONAL OXIDATION STABILITY, CHEMICAL INTERTNESS AND HIGH HEAT DISTORTION TEMPERATURES AND ARE USEFUL IN THE MANUFACTURE OF MOLDED AND EXTRUDED PRODUCTS.

    Inhibition of ether decomposition during distillation by quinoline addition
    117.
    发明授权
    Inhibition of ether decomposition during distillation by quinoline addition 失效
    通过喹啉添加剂在蒸馏中抑制醚分解

    公开(公告)号:US3729385A

    公开(公告)日:1973-04-24

    申请号:US3729385D

    申请日:1971-07-29

    Inventor: TUMOLO A

    CPC classification number: C07C41/06 C07C41/42 C07C41/46 C07C43/04

    Abstract: Propylene trimer methyl ether is of interest as a non-air polluting solvent; however, in the production of the ether, there is a major proportion of unreacted propylene trimer from which the ether must be separated. Distilling the propylene trimer methyl ether out of the ether-trimer mixture results in up to 30 percent degradation of the ether. By adding 0.1-10 weight percent quinoline to the distillation mixture, however, reduces degradation loss to less than 5 percent.

    Abstract translation: 丙烯三聚甲醚作为非空气污染溶剂是有意义的; 然而,在醚的生产中,存在主要比例的未反应的丙烯三聚体,其中乙醚必须从其中分离出来。 将丙烯三聚体甲醚从乙醚 - 三聚体混合物中蒸馏,导致乙醚降解高达30%。 然而,通过向蒸馏混合物中加入0.1-10重量%的喹啉,将降解损失降低到小于5%。

    Oxidative dehydrogenation of multicyclic hydrocarbons
    119.
    发明授权
    Oxidative dehydrogenation of multicyclic hydrocarbons 失效
    多环烯烃的氧化脱氢

    公开(公告)号:US3671599A

    公开(公告)日:1972-06-20

    申请号:US3671599D

    申请日:1971-03-24

    Inventor: MOORE ROBERT E

    CPC classification number: C07C5/333 C07C5/50 C07C13/573 Y10S585/942 C07C13/28

    Abstract: Conjugated dienes of polycyclic naphthenes having three to 11 rings of five to six carbon atoms each of which at least three are adjacent fused rings are produced by contacting the polycyclic naphthenes with a strong acid and a monool or diol of an adamantane hydrocarbon having zero to four alkyl groups with at least one alkyl group at a non bridgehead position when the number of alkyl groups is four at a reaction temperature between the freezing point of the acid and 50* C., and recovering a polycyclic conjugated diene from the reaction mixture.

    Abstract translation: 通过使多环烷烃与具有0至4个的金刚烷烃的强酸和一元醇或二醇接触来制备具有3至11个具有5至6个碳原子的环的多环烷烃的共轭二烯,其中至少3个是相邻的稠环 当烷基的数量在酸的凝固点和50℃之间的反应温度下为四时,并从反应混合物中回收多环共轭二烯时,在非桥头位置具有至少一个烷基的烷基。

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