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公开(公告)号：US20160251255A1
公开(公告)日：2016-09-01
申请号：US15040502
申请日：2016-02-10
Applicant: CORNING INCORPORATED
Inventor： Timothy Michael Gross , John Christopher Mauro , Yihong Mauro , Rohit Rai , Adama Tandia , Zhongzhi Tang
CPC classification number: C03C3/097 , B32B17/06 , C03C21/002
Abstract: Alkali aluminosilicate glasses that exhibit fast ion exchange performance and having low softening points that enable the glasses to be formed into non-planar, three-dimensional shapes. The glasses contain less than about 1 mol % of boron oxide and, in some embodiments, are substantially free of B2O3. Furthermore, these glasses have excess amounts of alkali oxides relative to both Al2O3 and P2O5, in order to improve melting behavior and ion exchange performance while still achieving sufficiently low softening points to allow for formability.
Abstract translation: 表现出快速离子交换性能并具有低软化点的碱性硅铝酸盐玻璃，使玻璃能够形成非平面的三维形状。 该玻璃含有少于约1mol％的氧化硼，并且在一些实施方案中基本上不含B 2 O 3。 此外，这些玻璃相对于Al 2 O 3和P 2 O 5都具有过量的碱金属氧化物，以便改善熔融行为和离子交换性能，同时仍然获得足够低的软化点以允许成形性。
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112.发明授权公开(公告)号：US09321679B2
公开(公告)日：2016-04-26
申请号：US14602300
申请日：2015-01-22
Applicant: Corning Incorporated
Inventor： Theresa Chang , Polly Wanda Chu , Adam James Ellison , Timothy Michael Gross , Guangli Hu , Nicholas James Smith
IPC: B32B17/00 , C03C21/00 , H05K1/02 , H05K1/03 , C03C15/00 , B32B17/10 , C03C17/32 , G06F1/16 , G02F1/1333 , H04M1/02
CPC classification number: G06F1/1652 , B32B7/12 , B32B17/06 , B32B17/064 , B32B17/10137 , B32B27/36 , B32B37/12 , B32B37/16 , B32B2255/00 , B32B2307/536 , B32B2307/546 , B32B2307/5825 , B32B2315/08 , B32B2367/00 , B32B2457/00 , B32B2457/20 , C03C3/091 , C03C15/00 , C03C17/32 , C03C21/002 , G02F1/133305 , H04M1/0268 , H05K1/028 , H05K1/0306 , H05K3/46 , Y10T428/24942 , Y10T428/26 , Y10T428/266
Abstract: A glass element having a thickness from 25 μm to 125 μm, a first primary surface, a second primary surface, and a compressive stress region extending from the first primary surface to a first depth, the region defined by a compressive stress σI of at least about 100 MPa at the first primary surface. Further, the glass element has a stress profile such that it does not fail when it is held at a bend radius from about 1 mm to about 20 mm for at least 60 minutes at about 25° C. and about 50% relative humidity. Still further, the glass element has a puncture resistance of greater than about 1.5 kgf when the first primary surface of the glass element is loaded with a tungsten carbide ball having a diameter of 1.5 mm.
Abstract translation: 一种玻璃元件，其厚度为25μm至125μm，第一主表面，第二主表面和从第一主表面延伸到第一深度的压应力区域，该区域由压缩应力和 在第一主表面处至少约100MPa。 此外，玻璃元件具有应力分布，使得当其在约25℃和约50％相对湿度下保持在约1mm至约20mm的弯曲半径至少60分钟时，其不会失效。 此外，当玻璃元件的第一主表面装载有直径为1.5mm的碳化钨球时，玻璃元件具有大于约1.5kgf的穿刺电阻。
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公开(公告)号：US09290407B2
公开(公告)日：2016-03-22
申请号：US14082847
申请日：2013-11-18
Applicant: Corning Incorporated
Inventor： Kristen L. Barefoot , Matthew John Dejneka , Sinue Gomez , Timothy Michael Gross , Nagaraja Shashidhar
CPC classification number: C03C3/091 , C03B33/0222 , C03B33/04 , C03B33/091 , C03C3/097 , C03C21/002 , Y02P40/57 , Y10T225/12 , Y10T428/24777 , Y10T428/315
Abstract: A glass and an enclosure, including windows, cover plates, and substrates for mobile electronic devices comprising the glass. The glass has a crack initiation threshold that is sufficient to withstand direct impact, has a retained strength following abrasion that is greater than soda lime and alkali aluminosilicate glasses, and is resistant to damage when scratched. The enclosure includes cover plates, windows, screens, and casings for mobile electronic devices and information terminal devices.
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公开(公告)号：US20150368150A1
公开(公告)日：2015-12-24
申请号：US14842122
申请日：2015-09-01
Applicant: CORNING INCORPORATED
Inventor： Timothy Michael Gross
CPC classification number: C03C3/097 , C03C3/04 , C03C3/062 , C03C3/064 , C03C3/083 , C03C3/085 , C03C3/087 , C03C3/091 , C03C3/093 , C03C4/02 , C03C4/18 , C03C14/006 , C03C21/00 , C03C21/002 , C03C2204/00 , Y10T428/265 , Y10T428/315
Abstract: Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % P2O5 and, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf.
Abstract translation: 提供了耐冲击和能够快速离子交换的损伤的碱性硅铝酸盐玻璃。 玻璃包含至少4摩尔％的P2O5，并且当离子交换时，其维氏压痕裂纹起始载荷为至少约7kgf。
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115.发明申请公开(公告)号：US20150210588A1
公开(公告)日：2015-07-30
申请号：US14601698
申请日：2015-01-21
Applicant: Corning Incorporated
Inventor： Theresa Chang , Polly Wanda Chu , Patrick Joseph Cimo , Michael Patrick Donovan , Adam James Ellison , Timothy Michael Gross , Guangli Hu , Gautam Narendra Kudva , Nicholas James Smith , Butchi Reddy Vaddi , Natesan Venkataraman
CPC classification number: G06F1/1652 , B32B7/12 , B32B17/06 , B32B17/064 , B32B17/10137 , B32B27/36 , B32B37/12 , B32B37/16 , B32B2255/00 , B32B2307/536 , B32B2307/546 , B32B2307/5825 , B32B2315/08 , B32B2367/00 , B32B2457/00 , B32B2457/20 , C03C3/091 , C03C15/00 , C03C17/32 , C03C21/002 , G02F1/133305 , H04M1/0268 , H05K1/028 , H05K1/0306 , H05K3/46 , Y10T428/24942 , Y10T428/26 , Y10T428/266
Abstract: A glass element having a thickness from 25 μm to 125 μm, a first primary surface, a second primary surface, and a compressive stress region extending from the first primary surface to a first depth, the region defined by a compressive stress σI of at least about 100 MPa at the first primary surface. Further, the glass element has a stress profile such that when the glass element is bent to a target bend radius of from 1 mm to 20 mm, with the center of curvature on the side of the second primary surface so as to induce a bending stress σB at the first primary surface, σI+σB
Abstract translation: 一种玻璃元件，其厚度为25μm至125μm，第一主表面，第二主表面和从第一主表面延伸到第一深度的压应力区域，该区域由压缩应力和 在第一主表面处至少约100MPa。 此外，玻璃元件具有应力分布，使得当玻璃元件弯曲到目标弯曲半径为1mm至20mm时，具有在第二主表面侧的曲率中心以引起弯曲应力 ＆sgr; B在第一个主表面，＆sgr; I +＆sgr; B <0。 此外，当玻璃元件的第一主表面装载有直径为1.5mm的碳化钨球时，玻璃元件具有≥1.5kgf的耐刺穿性。
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Patent Agency Ranking
公开(公告)号：US20150147576A1
公开(公告)日：2015-05-28
申请号：US14548650
申请日：2014-11-20
Applicant: CORNING INCORPORATED
Inventor： Dana Craig Bookbinder , Nicholas Francis Borrelli , Matthew John Dejneka , Timothy Michael Gross
CPC classification number: C03C21/005 , A01N59/00 , A01N59/16 , C03C3/097 , C03C4/00 , C03C17/30 , C03C21/002 , C03C2204/02 , Y10T428/315 , Y10T428/31612
Abstract: A strengthened antimicrobial glass including greater from about 50.0 mol. % to about 65.0 mol. % SiO2, about 14.0 mol. % to about 22.0 mol. % Al2O3, about 14.0 mol. % to about 22.0 mol. % R2O, wherein R is an alkali metal, and about 4.0 mol. % to 10.0 mol. % P2O5. The glass may have a compressive stress layer having a thickness of greater than or equal to about 20 μm to less than or equal to about 60 μm and having a compressive stress of greater than or equal to about 700 MPa. The glass may have an antimicrobial activity greater than or equal to about 1.0 log kill at about 23° C. and about 40.0% relative humidity. A method for making the glass may include obtaining a glass article, strengthening the glass article by contact with a first ion-exchange liquid, and contacting the glass article with second ion-exchange liquid comprising an antimicrobial agent.
Abstract translation: 增强的抗微生物玻璃包括大约50.0mol。 ％至约65.0mol。 ％SiO 2，约14.0mol。 ％至约22.0mol。 ％Al 2 O 3，约14.0mol。 ％至约22.0mol。 ％R 2 O，其中R是碱金属，和约4.0mol。 ％至10.0mol。 ％P2O5。 玻璃可以具有大于或等于约20μm至小于或等于约60μm的压缩应力层，并且具有大于或等于约700MPa的压缩应力。 在约23℃和约40.0％相对湿度下，玻璃可具有大于或等于约1.0log的杀菌活性。 制造玻璃的方法可以包括获得玻璃制品，通过与第一离子交换液体接触来加强玻璃制品，并使玻璃制品与包含抗微生物剂的第二离子交换液体接触。
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117.发明申请公开(公告)号：US20150064474A1
公开(公告)日：2015-03-05
申请号：US14469688
申请日：2014-08-27
Applicant: CORNING INCORPORATED
Inventor： Matthew John Dejneka , Qiang Fu , Timothy Michael Gross , Xiaoju Guo , Sumalee Likitvanichkul , John Christopher Mauro
CPC classification number: C03C10/0009 , C03B32/02 , C03C3/091 , C03C3/097 , C03C3/112 , C03C4/005 , C03C4/02 , C03C10/00 , C03C21/002 , C03C2204/00 , Y10T428/315
Abstract: Glass-ceramics and precursor glasses that are crystallizable to glass-ceramics are disclosed. The glass-ceramics of one or more embodiments include rutile, anatase, armalcolite or a combination thereof as the predominant crystalline phase. Such glasses and glass-ceramics may include compositions of, in mole %: SiO2 in the range from about 45 to about 75; Al2O3 in the range from about 4 to about 25; P2O5 in the range from about 0 to about 10; MgO in the range from about 0 to about 8; R2O in the range from about 0 to about 33; ZnO in the range from about 0 to about 8; ZrO2 in the range from about 0 to about 4; B2O3 in the range from about 0 to about 12, and one or more nucleating agents in the range from about 0.5 to about 12. In some glass-ceramic articles, the total crystalline phase includes up to 20% by weight of the glass-ceramic article.
Abstract translation: 公开了可玻璃陶瓷结晶的玻璃陶瓷和前体玻璃。 一个或多个实施方案的玻璃陶瓷包括作为主要结晶相的金红石，锐钛矿，二钙铝石或其组合。 这种玻璃和玻璃陶瓷可以包括摩尔％的组分：SiO 2在约45至约75的范围内; 在约4至约25的范围内的Al 2 O 3; 在约0至约10的范围内的P 2 O 5; 在约0至约8的范围内的MgO; R 2 O在约0至约33的范围内; 在约0至约8的范围内的ZnO; 在约0至约4的范围内的ZrO 2; B 2 O 3在约0至约12的范围内，以及一种或多种成核剂在约0.5至约12的范围内。在一些玻璃陶瓷制品中，总结晶相包含至多20重量％的玻璃 - 陶瓷 文章。
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118.发明申请公开(公告)号：US20150037586A1
公开(公告)日：2015-02-05
申请号：US14331753
申请日：2014-07-15
Applicant: CORNING INCORPORATED
Inventor： Timothy Michael Gross
CPC classification number: C03C3/097 , C03C3/087 , C03C4/18 , C03C21/002 , C03C2204/00 , Y10T428/315
Abstract: A glass article is provided having from greater than or equal to about 40 mol % to less than or equal to about 68 mol % SiO2, less than or equal to about 11 mol % Al2O3, an R2O:R′O molar ratio of from greater than or equal to about 1:1 to less than or equal to about 2:1, and an MgO:CaO molar ratio of from greater than or equal to about 0.6:1 to less than or equal to about 1.8:1. The class article may also include a compressive stress layer on at least one surface thereof, the compressive stress layer having a compressive stress that is greater than or equal to about 800 MPa, and a depth that is greater than or equal to about 20 μm.
Abstract translation: 提供玻璃制品，其具有大于或等于约40摩尔％至小于或等于约68摩尔％的SiO 2，小于或等于约11摩尔％的Al 2 O 3，R2O:R'O摩尔比从较大 大于或等于约1：1至小于或等于2：1，MgO：CaO摩尔比为大于或等于0.6：1至小于或等于约1.8：1。 类物品还可以在其至少一个表面上包括压缩应力层，压应力层具有大于或等于约800MPa的压缩应力，以及大于或等于约20μm的深度。
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公开(公告)号：US12291484B2
公开(公告)日：2025-05-06
申请号：US18093416
申请日：2023-01-05
Applicant: CORNING INCORPORATED
Inventor： Timothy Michael Gross , Xiaoju Guo , Peter Joseph Lezzi , Alexandra Lai Ching Kao Andrews Mitchell , Rostislav Vatchev Roussev
Abstract: A glass composition includes from 55.0 mol % to 75.0 mol % SiO2; from 8.0 mol % to 20.0 mol % Al2O3; from 3.0 mol % to 15.0 mol % Li2O; from 5.0 mol % to 15.0 mol % Na2O; and less than or equal to 1.5 mol % K2O. The glass composition has the following relationships: Al2O3+Li2O is greater than 22.5 mol %, R2O+RO is greater than or equal to 18.0 mol %, R2O/Al2O3 is greater than or equal to 1.06, SiO2+Al2O3+B2O3+P2O5 is greater than or equal to 78.0 mol %, and (SiO2+Al2O3+B2O3+P2O5)/Li2O is greater than or equal to 8.0. The glass composition may be used in a glass article or a consumer electronic product.
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120.发明申请公开(公告)号：US20240400434A1
公开(公告)日：2024-12-05
申请号：US18800607
申请日：2024-08-12
Applicant: CORNING INCORPORATED
Inventor： Heather Debra Boek , Timothy Michael Gross , Jin Su Kim , Jesse Kohl , HungCheng Lu , Yu Xiao , Liying Zhang , Lu Zhang
Abstract: Methods for manufacturing glass articles having a target effective coefficient of thermal expansion CTETeff averaged over a temperature range comprise selecting a glass core composition having an average core glass coefficient of thermal expansion CTEcore that is greater than the target effective CTETeff and a glass clad composition having an average clad glass coefficient of thermal expansion CTEclad that is less than the target effective CTETeff; and manufacturing a glass laminate comprising a glass core layer formed from the glass core composition and two or more glass cladding layers fused to the glass core layer, each of the two or more glass cladding layers formed from the glass clad composition such that a ratio of a thickness of the glass core layer to a total thickness of the two or more glass cladding layers is selected to produce the glass laminate having an effective coefficient of thermal expansion CTEeff that is within ±0.5 ppm/° C. of the target effective CTETeff.
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