公开(公告)号：US09211526B2

公开(公告)日：2015-12-15

申请号：US13880746

申请日：2011-08-26

Applicant: Gerhard Auer ,  Frank Hipler

Inventor： Gerhard Auer ,  Frank Hipler

IPC: B01J23/30 ,  B01D53/86 ,  B01D53/94 ,  B01J21/06 ,  B01J23/22 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  C01G31/02 ,  C01G41/02

CPC classification number: B01J23/30 ,  B01D53/8628 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20776 ,  B01D2255/9207 ,  B01J21/063 ,  B01J23/22 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0009 ,  B01J37/009 ,  B01J37/0201 ,  C01G31/02 ,  C01G41/02 ,  C01P2002/50 ,  C01P2006/12

Abstract: A composition includes titanium dioxide-containing digestion residue from titanium dioxide production, and at least one further component which is catalytically active. Dimensionally stable, catalytically active solids which are obtained from this composition can be used as catalyst, for example for minimizing nitrogen oxides.

Abstract translation: 组合物包括来自二氧化钛生产的含二氧化钛的消化残余物和至少一种其它催化活性成分。 从该组合物获得的尺寸稳定的催化活性固体可用作催化剂，例如用于使氮氧化物最小化。

公开(公告)号：US09206361B2

公开(公告)日：2015-12-08

申请号：US13330910

申请日：2011-12-20

Applicant: Julie Chabot ,  Bruce E. Reynolds ,  Erin Maris ,  Shuwu Yang

Inventor： Julie Chabot ,  Bruce E. Reynolds ,  Erin Maris ,  Shuwu Yang

IPC: C10G47/26 ,  C10G49/02 ,  B01J37/20 ,  B01J35/00 ,  B01J23/883 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  C10G49/12

CPC classification number: C10G49/02 ,  B01J23/883 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1052 ,  B01J35/1066 ,  B01J35/1076 ,  B01J37/0036 ,  B01J37/0201 ,  B01J37/20 ,  C10G49/12 ,  C10G2300/208 ,  C10G2300/4056 ,  C10G2300/70 ,  C10G2300/708 ,  C10G2300/802

Abstract: A method to upgrade heavy oil feedstock using an ebullated bed reactor and a novel catalyst system is provided. The ebullated bed reactor system includes two different catalyst with different characteristics: an expanded catalyst zone containing particulate catalyst having a particle size of greater than 0.65 mm; and a slurry catalyst having an average particle size ranging from 1 to 300 μm. The slurry catalyst is provided to the ebullated bed system containing the heavy oil feedstock, and entrained in the upflowing hydrocarbon liquid passing through the ebullated bed reaction zone. The slurry catalyst reduces the formation of sediment and coke precursors in the ebullating bed reactor system. The slurry catalyst is prepared from rework materials, which form a slurry catalyst in-situ upon mixing with the heavy oil feedstock.

Abstract translation: 提供了一种使用沸腾床反应器和新型催化剂体系升级重油原料的方法。 沸腾床反应器系统包括具有不同特性的两种不同的催化剂：包含粒度大于0.65mm的颗粒催化剂的膨胀催化剂区; 和平均粒度为1〜300μm的浆料催化剂。 将浆料催化剂提供给含有重油原料的沸腾床系统，并夹带在通过沸腾床反应区的向上流动的烃液中。 浆料催化剂减少沸腾床反应器系统中沉淀物和焦炭前体的形成。 浆料催化剂由返工材料制备，其在与重油原料混合时原位形成浆料催化剂。

公开(公告)号：US09205409B2

公开(公告)日：2015-12-08

申请号：US14115823

申请日：2012-04-25

Applicant: Cornelia Carolina Eloff ,  Jan Van De Loosdrecht ,  Jacobus Lucas Visagie ,  Hendrik Van Rensburg

Inventor： Cornelia Carolina Eloff ,  Jan Van De Loosdrecht ,  Jacobus Lucas Visagie ,  Hendrik Van Rensburg

IPC: B01J23/00 ,  B01J23/75 ,  C10G2/00 ,  C01G45/00 ,  C10G3/00 ,  B01J37/08 ,  B01J23/89 ,  B01J35/00 ,  B01J35/10 ,  B01J37/16 ,  B01J21/12

CPC classification number: B01J23/75 ,  B01J21/04 ,  B01J21/12 ,  B01J23/8913 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/0244 ,  B01J37/08 ,  B01J37/088 ,  B01J37/16 ,  B01J37/18 ,  C01G45/00 ,  C10G2/332 ,  C10G3/50 ,  C10G45/00 ,  Y02P30/20

Abstract: A process for preparing a cobalt-containing hydrocarbon synthesis catalyst precursor includes calcining a loaded catalyst support comprising a catalyst support supporting a cobalt compound. The calcination includes subjecting the loaded catalyst support to heat treatment by heating the loaded catalyst support to a temperature, T, of at least 220° C. at a heating rate below 10° C./minute, and effecting gas flow at a space velocity of at least 9 m3n/kg cobalt compound/hour over the loaded catalyst support during at least part of the heating. The cobalt-containing hydrocarbon synthesis catalyst precursor is thereby produced.

Abstract translation: 制备含钴烃合成催化剂前体的方法包括煅烧负载的催化剂载体，其包含负载钴化合物的催化剂载体。 煅烧包括使负载的催化剂载体进行热处理，通过将负载的催化剂载体加热到至少220℃的温度T，加热速率低于10℃/分钟，并以空速进行气体流动 在至少部分加热期间，在负载的催化剂载体上至少为9m 3 / kg钴化合物/小时。 由此制造含钴烃合成催化剂前体。

公开(公告)号：US09199223B2

公开(公告)日：2015-12-01

申请号：US14631333

申请日：2015-02-25

Applicant: BASF SE

Inventor： Tobias Rosendahl ,  Torsten Mäurer ,  Cornelia K. Dobner ,  Andreas Lehr ,  Johanna Wanka

IPC: B01J23/50 ,  B01J21/04 ,  C07D301/10 ,  B01J27/02 ,  B01J23/68 ,  B01J35/10 ,  B01J37/02 ,  C07F1/00 ,  B01J21/02 ,  B01J35/00 ,  B01J37/08

CPC classification number: B01J27/02 ,  B01J21/02 ,  B01J21/04 ,  B01J23/50 ,  B01J23/688 ,  B01J35/0006 ,  B01J35/1009 ,  B01J35/1066 ,  B01J35/1076 ,  B01J35/108 ,  B01J37/0201 ,  B01J37/0213 ,  B01J37/088 ,  C07D301/10 ,  C07F1/005

Abstract: Process for producing a supported silver catalyst, which comprises (a) reacting oxalic acid with an alkali metal base in a solvent, preferably water, to the second equivalence point of oxalic acid to give alkali metal oxalate; (b) reacting the alkali metal oxalate obtained according to (a) with silver salt in a solvent, preferably water, to give silver oxalate; (c) forming a complexation of the silver oxalate obtained according to (b) with a diamine compound in a solvent, preferably water, to give a diamine-silver oxalate complex.

公开(公告)号：US20150336856A1

公开(公告)日：2015-11-26

申请号：US14718264

申请日：2015-05-21

Applicant: INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

Inventor： Young-Woong SUH ,  Hyung-Su JANG ,  Kyung-Bok BAE

IPC: C07C1/20

CPC classification number: C07C1/20 ,  B01J23/06 ,  B01J23/28 ,  B01J23/75 ,  B01J29/072 ,  B01J29/076 ,  B01J29/40 ,  B01J37/0201 ,  B01J37/031 ,  B01J2229/12 ,  B01J2229/38 ,  C07C2529/40 ,  C07C2529/46 ,  C07C2529/48 ,  C10G3/46 ,  C10G3/49 ,  C10G3/52 ,  C10G2300/1011 ,  C10G2400/30 ,  Y02E50/13 ,  Y02P30/20

Abstract: Provided is a method for producing bio-aromatic compounds from glycerol. The method uses a primary alcohol, secondary alcohol or a combination thereof as a mixing medium in converting glycerol into an aromatic compound, and thus overcomes the high viscosity of glycerol and improves the problem of rapid catalytic deactivation, thereby increasing the yield of aromatic compounds and improving the stability of catalyst. In addition, the method for producing bio-aromatic compounds uses a zeolite-based catalyst that is a kind of solid acid catalysts, and suggests optimum reaction conditions, and thus imparts a high added value to glycerol produced as a byproduct in a biodiesel production process and increases the cost-efficiency of process.

Abstract translation: 提供从甘油生产生物芳族化合物的方法。 该方法使用伯醇，仲醇或其组合作为将甘油转化为芳香族化合物的混合介质，从而克服了甘油的高粘度，改善了快速催化失活的问题，从而提高了芳族化合物的收率， 提高催化剂的稳定性。 此外，生物芳香族化合物的制造方法使用作为一种固体酸催化剂的沸石型催化剂，提出了最佳的反应条件，因此赋予生物柴油生产工序中副产物甘油高附加值 并提高过程的成本效益。

公开(公告)号：US20150335063A1

公开(公告)日：2015-11-26

申请号：US14817604

申请日：2015-08-04

Applicant: PHILIP MORRIS USA INC.

Inventor： Sarojini DEEVI ,  Kent B. KOLLER

IPC: A24B15/28 ,  A24D3/16

CPC classification number: A24B15/286 ,  A24B15/28 ,  A24B15/282 ,  A24B15/287 ,  A24D3/16 ,  B01J37/0201 ,  B01J37/0213 ,  B01J37/03 ,  B01J37/035

Abstract: Cut filler compositions, cigarette paper, cigarette filters, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of a catalyst capable converting carbon monoxide to carbon dioxide. The catalyst comprises nanoscale metal and/or metal oxide particles supported on high surface area support particles. The catalyst can be prepared by combining a metal precursor solution with high surface area support particles to form a mixture, or by combining a metal precursor solution with a colloidal solution to form a mixture, and then heat treating the mixture.

Abstract translation: 提供了切割填料组合物，卷烟纸，香烟过滤嘴，香烟，制造香烟的方法和吸烟方法，其涉及使用能够将一氧化碳转化为二氧化碳的催化剂。 催化剂包含负载在高表面积载体颗粒上的纳米金属和/或金属氧化物颗粒。 催化剂可以通过将金属前体溶液与高表面积载体颗粒结合以形成混合物，或者通过将金属前体溶液与胶体溶液组合以形成混合物，然后热处理该混合物来制备。

公开(公告)号：US20150328625A1

公开(公告)日：2015-11-19

申请号：US14808519

申请日：2015-07-24

Applicant: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  TOTAL MARKETING SERVICES

Inventor： Sander VAN DONK ,  Maxime LACROIX ,  Régine KENMOGNE-GATCHUISSI ,  François FAJULA ,  Métin BULUT ,  Jean-Pierre DATH ,  Krijn Pieter DE JONG ,  Petra Elisabeth DE JONGH ,  Jovana ZECEVIC ,  Adrianus Nicolaas Cornelis VAN LAAK

IPC: B01J29/08 ,  B01J37/04 ,  C10G47/18 ,  B01J37/06 ,  B01J37/08 ,  B01J37/02 ,  C01B39/24 ,  B01J37/00

CPC classification number: B01J29/084 ,  B01J29/126 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/108 ,  B01J37/009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/38 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C10G47/18

Abstract: The invention relates to a Y-type zeolite having a modified faujasite structure, the intracrystalline structure of which includes at least one network of micropores, at least one network of small mesopores having an average diameter ranging from 2 to 5 nm, and at least one network of large mesopores having an average diameter range from 10 to 50 nm. The invention also relates to particles including such zeolites and to the use thereof in a method for processing crude oil, particularly as a hydrocracking catalyst.

Abstract translation: 本发明涉及具有改性的八面沸石结构的Y型沸石，其结晶结构包括至少一个微孔网络，至少一个平均直径范围为2-5nm的小介孔网络，以及至少一个 具有平均直径范围为10至50nm的大介孔的网络。 本发明还涉及包括这种沸石的颗粒以及其在用于加工原油，特别是加氢裂化催化剂的方法中的用途。

公开(公告)号：US09181160B2

公开(公告)日：2015-11-10

申请号：US14368381

申请日：2012-12-25

Applicant: KAO CORPORATION

Inventor： Tsubasa Arai ,  Shinji Kotachi ,  Yoshiharu Ataka

IPC: C07C41/00 ,  C07C41/20 ,  C11B9/00 ,  B01J37/08 ,  B01J21/18 ,  B01J23/44 ,  B01J23/46 ,  B01J23/89 ,  B01J37/02

CPC classification number: C07C41/20 ,  B01J21/18 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/892 ,  B01J37/0201 ,  B01J37/084 ,  C07C2601/14 ,  C11B9/0034 ,  C07C43/196

Abstract: The present invention relates to [1] a method of producing 1-(2-t-butylcyclohexyloxy)-2-butanol including a step of hydrogenating 1-(2-t-butylphenyloxy)-2-butanol under a condition at a hydrogen pressure of from 1 to 5 MPa in the presence of a palladium catalyst (A) supported on peat-derived active carbon and a metal catalyst (B) containing one or more kinds of members selected from ruthenium, rhodium, platinum, and nickel; and [2] a perfume composition containing 1-(2-t-butylcyclohexyloxy)-2-butanol obtained by the foregoing method. According to the present invention, 1-(2-t-butylcyclohexyloxy)-2-butanol having a woody or amber-like fragrance as a perfume material and excellent fragrance notes can be obtained in a high purity because of a small remaining amount of a reaction intermediate and in a high yield.

Abstract translation: 本发明涉及[1]一种生产1-（2-叔丁基环己氧基）-2-丁醇的方法，包括在氢气压力条件下氢化1-（2-叔丁基苯氧基）-2-丁醇的步骤 在负载在泥炭源活性炭上的钯催化剂（A）和含有一种或多种选自钌，铑，铂和镍的成分的金属催化剂（B）的存在下，为1〜5MPa， 和[2]含有通过上述方法得到的1-（2-叔丁基环己基氧基）-2-丁醇的香料组合物。 根据本发明，可以以高纯度获得具有木质或琥珀色香料作为香料的1-（2-叔丁基环己基氧基）-2-丁醇和优异的香味，因为剩余量少 反应中间体和高产率。

公开(公告)号：US09180439B2

公开(公告)日：2015-11-10

申请号：US12811219

申请日：2009-01-23

Applicant: Nikolai Nesterenko ,  Walter Vermeiren ,  Sander Van Donk ,  Delphine Minoux

Inventor： Nikolai Nesterenko ,  Walter Vermeiren ,  Sander Van Donk ,  Delphine Minoux

IPC: B01J29/06 ,  B01J27/16 ,  B01J29/40 ,  B01J37/28 ,  C07C1/20 ,  B01J37/02

CPC classification number: C07C1/20 ,  B01J27/16 ,  B01J29/06 ,  B01J29/061 ,  B01J29/40 ,  B01J29/405 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/024 ,  B01J37/28 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  C07C4/06 ,  C07C2523/02 ,  C07C2527/14 ,  C07C2529/06 ,  C07C2529/40 ,  C07C2529/82 ,  C07C2529/85 ,  C08F110/02 ,  C10G2400/20 ,  Y02P30/42 ,  C07C11/02

Abstract: The invention covers a process for obtaining an alkaline earth or rare earth metal-P-modified molecular sieve (M-P-modified molecular sieve) comprising the following steps: a). selecting at least one molecular sieve selected from one of: a P-modified molecular sieve which contains at least 0.3 wt % of P obtained by dealuminating a molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P a molecular sieve which is modified with P during step b) by dealuminating the molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P thereby introducing at least 0.3 wt % of P b). contacting said molecular sieve with an alkaline earth or rare earth metal-containing compound (M-containing compound) to introduce at least 0.05 wt % of the alkaline earth or rare earth metal to the molecular sieve. The invention also covers a catalyst composite comprising: a). at least 10 wt % of a M-P-modified molecular sieve comprising at least 0.05% by weight of an alkaline earth or rare earth metal (M) and at least 0.3 wt % of P, b). optionally metal phosphate, c). optionally matrix material, and d). optionally binder. The catalyst of the invention can also be used in a process for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted in the XTO reactor with the catalyst composite according to the invention under conditions effective to convert the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent). The catalyst composite of the invention can also be used in addition or alternatively in an OCP process.

Abstract translation: 本发明涉及一种获得碱土金属或稀土金属-P改性分子筛（M-P改性分子筛）的方法，包括以下步骤：a）。 选择至少一种分子筛，其选自以下之一中的一种分子筛：P-改性分子筛，其含有至少0.3重量％的通过在蒸汽步骤中脱模分子筛获得的P，然后使用含有源的 P是在步骤b）期间用P改性的分子筛，通过在蒸汽步骤中脱分解分子筛，然后使用含有P源的酸溶液进行浸出步骤，从而引入至少0.3重量％的P b）。 使所述分子筛与含碱土金属或稀土金属的化合物（含M化合物）接触，以将至少0.05重量％的碱土金属或稀土金属引入分子筛中。 本发明还涉及一种催化剂复合材料，其包含：a）。 至少10重量％的M-P改性分子筛包含至少0.05重量％的碱土金属或稀土金属（M）和至少0.3重量％的P，b）。 任选的金属磷酸盐，c）。 任选的基质材料，和d）。 可选粘合剂。 本发明的催化剂也可以用于从含氧，含卤素或含硫有机原料制备烯烃产物的方法，其中所述含氧卤化物或含硫有机原料接触 在具有将含氧，含卤素或含硫有机原料转化为烯烃产物（XTO反应器流出物）的条件下，具有根据本发明的催化剂复合材料的XTO反应器。 本发明的催化剂复合材料也可以在OCP方法中加入或替代地使用。

公开(公告)号：US09180433B2

公开(公告)日：2015-11-10

申请号：US14206587

申请日：2014-03-12

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Haiyou Wang ,  Hsueh Sung Tung

IPC: B01J23/58 ,  C07C17/25 ,  C07C17/087 ,  C07C17/20 ,  B01J21/10 ,  B01J37/02 ,  B01J23/44

CPC classification number: B01J23/58 ,  B01J21/10 ,  B01J23/44 ,  B01J23/96 ,  B01J37/0201 ,  B01J38/02 ,  B01J38/10 ,  B01J38/12 ,  B01J38/18 ,  C07C17/087 ,  C07C17/206 ,  C07C17/25 ,  Y02P20/582 ,  Y02P20/584 ,  C07C21/18 ,  C07C19/10

Abstract: The present invention relates to a provides a catalyst comprising (a) a solid support comprising an alkaline earth metal oxide, fluoride, or oxyfluoride, and (b) at least one elemental metal disposed on or within said support, preferably wherein said elemental metal is present in an amount from about 0.01 to about 10 weight percent based upon the total weight of the metal and support. It also relates to the use of the catalyst for the dehydrochlorination of a hydrochlorofluorocarbon.

Abstract translation: 本发明涉及一种催化剂，其包括（a）包含碱土金属氧化物，氟化物或氟氧化物的固体载体，和（b）设置在所述载体上或其内的至少一种元素金属，优选其中所述元素金属为 以基于金属和载体的总重量计约0.01至约10重量％的量存在。 它还涉及催化剂用于氢氯氟烃的脱氯化氢的用途。