Fuel oils based on middle distillates and copolymers of ethylene and unsaturated carboxylic esters
    14.
    发明授权
    Fuel oils based on middle distillates and copolymers of ethylene and unsaturated carboxylic esters 失效
    基于中间馏分的燃料油和乙烯和不饱和羧酸酯的共聚物

    公开(公告)号:US06846338B2

    公开(公告)日:2005-01-25

    申请号:US09788261

    申请日:2001-02-19

    CPC classification number: C10L1/1955 C10L1/1963 C10L1/1973 C10L1/2364

    Abstract: A fuel oil comprising: A) a mineral oil having a cloud point of less than −8° C., a boiling range (90-20%) of less than 120° C. and a difference between CFPP and PP of less than 10° C., and B) one or more copolymers, wherein the copolymers comprise: a) bivalent structural unit (B1), wherein (B1) is a bivalent structural unit of formula (1) —CH2—CH2—  (1) and b) one or more bivalent structural units (B2), wherein (B2) is either a bivalent structural unit of formula (2) —CH2—CR1R2—  (2)  in which R1 is hydrogen or methyl, R2 is COOR3, OR3 or OCOR3, and R3 is an alkyl radical having at least 4 and at most 30 carbon atoms, or (B2) is a bivalent structural unit of formula (2a)  in which R3 is an alkyl radical having at least 4 and at most 30 carbon atoms.

    Abstract translation: 一种燃油,包括:A)浊点小于-8℃的矿物油,小于120℃的沸程(90-20%)和CFPP与PP之间的差异小于10 其中所述共聚物包括:a)二价结构单元(B1),其中(B1)是式(1)的二价结构单元,和b)一个或多个二价结构单元(B2) 其中(B2)是式(2)的二价结构单元,其中R 1是氢或甲基,R 2是COOR 3,OR 3或OCOR 3,R 3是 是具有至少4个且至多30个碳原子的烷基,或(B2)是式(2a)的二价结构单元,其中R 3是具有至少4个且至多30个碳原子的烷基。

    Additives for improving the cold flow properties and the storage stability of crude oil
    16.
    发明授权
    Additives for improving the cold flow properties and the storage stability of crude oil 失效
    用于改善冷流特性和原油储存稳定性的添加剂

    公开(公告)号:US06821933B2

    公开(公告)日:2004-11-23

    申请号:US10311057

    申请日:2002-12-13

    Abstract: The invention relates to additives for improving the flowability of mineral oils, containing: A) 1-40 wt. % of at least one copolymer, which is oil-soluble and improves the cold flow properties of mineral oil, selected from A1) copolymers consisting of 80 to 96.5 mol % ethylene and 3.5-20 mol % vinyl esters of carboxylic acids with 1-20 C atoms and/or (meth)acrylic acid esters of alcohols with 1-8 C atoms, and A2) homopolymers or copolymers of esters, containing C10-C30 alkyl radicals, of ethylenically unsaturated carboxylic acids with up to 20 mol % of other olefinically unsaturated compounds, B) 20-80 wt. % of at least one poly-alpha-olefin with a molecular weight of 250-5000, derived from monoolefins with 3-5 C atoms, and C) 5-70 wt. % of at least one organic acid selected from C1) alkylphenol-aldehyde resins of formula (1), wherein R1 and R2 independently designate H or alkyl radicals with 1-30 C atoms, but both radicals do not at the same time signify H, n represents an integer of 3-50, and R3 represents H or an alkyl radical with 1-4 C atoms, and C2) aliphatic and/or aromatic sulfonic acids of formula R18—SO3H, wherein R18 stands for C6-C40-alkyl, C6-C40-alkenyl, or an alk(en)yl aryl radical which has 1, 2, 3 or 4 aromatic rings and 1, 2, 3 or 4 alkyl or aryl radicals with respectively 6-40 C-atoms.

    Abstract translation: 本发明涉及用于改善矿物油的流动性的添加剂,其含有:A)1-40wt。 %的至少一种共聚物,其是油溶性的并且改善矿物油的冷流动性质,选自A1)由80至96.5mol%乙烯和3.5-20mol%羧酸乙烯基酯与1-20 C原子和/或具有1-8个C原子的醇的(甲基)丙烯酸酯,和A2)烯键式不饱和羧酸与含有至多20摩尔%其它烯属不饱和羧酸的C 10 -C 30烷基酯的均聚物或共聚物 不饱和化合物,B)20-80wt。 %的至少一种分子量为250-5000的聚-α-烯烃,衍生自具有3-5个C原子的单烯烃,和C)5-70wt。 %的至少一种选自式(1)的C1)烷基酚醛树脂的有机酸,其中R 1和R 2独立地表示H或具有1-30个C原子的烷基,但两个基团不在 同时表示H,n表示3-50的整数,R 3表示H或具有1-4个C原子的烷基,以及C2)式R 18的脂族和/或芳族磺酸 - SO 3 H,其中R 18代表C 6 -C 40 - 烷基,C 6 -C 40 - 烯基或具有1,2,3或4个芳环和1,2,3或4个烷基的烷基(烯)基芳基, 或具有6-40个C原子的芳基。

    Multifunctional additive for fuel oils
    17.
    发明授权
    Multifunctional additive for fuel oils 有权
    燃油多功能添加剂

    公开(公告)号:US06652610B2

    公开(公告)日:2003-11-25

    申请号:US09760319

    申请日:2001-01-11

    Abstract: The invention relates to additives for improving cold-flow and lubricating properties of fuel oils, comprising A) 5-95% by weight of at least one oil-soluble amphiphile of the formula  in which R1 is an alkyl, alkenyl, hydroxyalkyl or aromatic radical having 1 to 50 carbon atoms, X is NH, NR3, O or S, y is 1, 2, 3 or 4, R2 is hydrogen or an alkyl radical carrying hydroxyl groups and having 2 to 10 carbon atoms and R3 is an alkyl radical carrying nitrogen and/or hydroxyl groups and having 2 to 10 carbon atoms or C1-C20-alkyl, and B) 5 to 95% by weight of a terpolymer containing from 10 to 35 mol % of structural units derived from the vinyl ester of a carboxylic acid having 2 to 4 carbon atoms, from 1 to 15 mol % of structural units derived from the vinyl ester of a neocarboxylic acid having 8 to 15 carbon atoms, and structural units of ethylene to 100 mol %, having a melt viscosity, measured at 140° C., of from 20 to 10,000 mPas.

    Abstract translation: 本发明涉及用于改善燃料油的冷流和润滑性能的添加剂,包括A)5-95重量%的至少一种油溶性两性物质,其中R 1是烷基,烯基,羟基烷基或芳族 具有1至50个碳原子的基团,X是NH,NR 3,O或S,y是1,2,3或4,R 2是氢或带有羟基并具有2至10个碳原子的烷基 原子和R 3是带有氮和/或羟基并且具有2-10个碳原子或C 1 -C 20烷基的烷基,B)5至95重量%的含有10至35摩尔% 衍生自碳原子数为2〜4的羧酸的乙烯基酯的结构单元,1〜15摩尔%的来自碳原子数为8〜15的新羧酸的乙烯基酯的结构单元,乙烯的结构单元为100〜 mol,在140℃下测得的熔体粘度为20至10,000mPa·s。

    Multifunctional additive for fuel oils
    19.
    发明授权
    Multifunctional additive for fuel oils 失效
    燃油多功能添加剂

    公开(公告)号:US06475250B2

    公开(公告)日:2002-11-05

    申请号:US09760318

    申请日:2001-01-11

    Abstract: The invention relates to additives for improving cold-flow and lubricating properties of fuel oils, comprising A) 5-95% by weight of at least one oil-soluble amphiphile of the formulae in which R1 is an alkyl, alkenyl, hydroxyalkyl or aromatic radical having 1 to 50 carbon atoms, X is NH, NR3, O or S, y is 1, 2, 3 or 4, R2 is an alkyl radical carrying hydroxyl groups and having 2 to 10 carbon atoms and R3 is an alkyl radical carrying nitrogen and/or hydroxyl groups and having 2 to 10 carbon atoms or a C1-C20-alkyl radical, and B) 5 to 95% by weight of a terpolymer of ethylene, the vinyl ester of one or more aliphatic, linear or branched monocarboxylic acids which contain 2 to 20 carbon atoms in the molecule and a C5-C7-olefin containing from 9 to 18 mol % of vinyl ester and from 0.5 to 5 mol % of olefin (based in each case on the terpolymer), having a melt viscosity, measured at 140° C., of from 20 to 10,000 mPas.

    Abstract translation: 本发明涉及用于改善燃料油的冷流和润滑性能的添加剂,包括A)5-95重量%的至少一种油溶性二醇,其中R1是具有1个烷基,烯基,羟基烷基或芳族基团的烷基,链烯基,羟基烷基或芳族基团 至50个碳原子,X是NH,NR 3,O或S,y是1,2,3或4,R 2是带有羟基且具有2至10个碳原子的烷基,R 3是带有氮和/ 或羟基并且具有2至10个碳原子或C 1 -C 20烷基,和B)5至95重量%的乙烯三元共聚物,一种或多种脂族,直链或支链单羧酸的乙烯基酯,其含有2 至20个碳原子和含有9至18摩尔%乙烯基酯和0.5至5摩尔%烯烃(基于每种情况下在三元共聚物上)的C5-C7-烯烃,其熔体粘度在 140℃,为20至10,000mPas。

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