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    Functionalized Copolymers of Terminally Functionalized Perfluoro (Alkyl Vinyl Ether) Reactor Wall for Photochemical Reactions, Process for Increasing Fluorine Content in Hydrocaebons and Halohydrocarbons and Olefin Production
    13.
    发明申请
    Functionalized Copolymers of Terminally Functionalized Perfluoro (Alkyl Vinyl Ether) Reactor Wall for Photochemical Reactions, Process for Increasing Fluorine Content in Hydrocaebons and Halohydrocarbons and Olefin Production 审中-公开
    用于光化学反应的末端官能化全氟（烷基乙烯醚）反应器壁的官能化共聚物，增加氢化碳和卤代烃中的氟含量和烯烃生产的方法

    公开(公告)号：US20070265368A1

    公开(公告)日：2007-11-15

    申请号：US11792639

    申请日：2005-12-19

    Applicant: Velliyur Nott Mallikarjuna Rao ,  Allen Sievert

    Inventor： Velliyur Nott Mallikarjuna Rao ,  Allen Sievert

    IPC: C07C17/00 ,  C08J3/28

    CPC classification number: B01J19/127 ,  B01J8/08 ,  B01J19/123 ,  B01J19/24 ,  B01J19/2415 ,  B01J19/243 ,  B01J23/26 ,  B01J37/088 ,  B01J2219/00822 ,  B01J2219/00831 ,  B01J2219/00833 ,  B01J2219/00835 ,  B01J2219/00936 ,  B01J2219/00943 ,  B01J2219/0204 ,  C07C17/10 ,  C07C17/206 ,  C07C17/25 ,  C07C19/08 ,  C07C19/10 ,  C07C19/12 ,  C07C21/18 ,  C07C21/185

    Abstract: A photochemical reaction apparatus including a reactor and a light source situated so that light from the light source is directed through a portion of the reactor wall is disclosed. The apparatus is characterized by the portion of the reaction wall comprising a functionalized copolymer of a terminally functionalized perfluoro(alkyl vinyl ether). Also described is a photochemical reaction process using said reactor. The functional group of the copolymer of the apparatus and the process is selected from —SO2F, —SO2CI, —SO3H, —CO2R (where R is H or C1-C3 alkyl), —PO3H2, and salts thereof. A process for increasing the flourine content of at least one compound selected from hydrocarbons and halohydrocarbons, comprising: (a) photochlorinating said at least one compound, and (b) reacting the halogenated hydrocarbon in (a) with HF. A process for producing an olefinic compound, comprising: (a) photochlorinating at least one compound selected from hydrocarbons and halohydrocarbons containing at least two carbon atoms and at least two hydrogen atoms to produce a halogenated hydrocarbon containing a hydrogen substituent and a chlorine substituent on adjacent carbon atoms; and (b) subjecting the halogenated hydrocarbon produced in (a) to dehydrohalogenation.

    Abstract translation: 公开了一种光化学反应装置，其包括反应器和光源，其位于使得来自光源的光被引导通过反应器壁的一部分。 该装置的特征在于反应壁的一部分包含末端官能化的全氟（烷基乙烯基醚）的官能化共聚物。 还描述了使用所述反应器的光化学反应过程。 该装置和方法的共聚物的官能团选自-SO 2 F，-SO 2 Cl，-SO 3 H ，-CO 2 R（其中R为H或C 1 -C 3烷基），-PO 3 H 2 H 2，及其盐。 一种提高至少一种选自烃和卤代烃的化合物的含量的方法，包括：（a）将所述至少一种化合物进行光氯化，和（b）使（a）中的卤代烃与HF反应。 一种制备烯烃化合物的方法，包括：（a）将至少一种选自含有至少两个碳原子和至少两个氢原子的烃和卤代烃的化合物进行光氯化以产生在邻近的含氢取代基和氯取代基的卤代烃 碳原子 和（b）使（a）中制备的卤代烃脱卤化氢。

    Method for carrying out homogeneously catalyzed reactions
    14.
    发明授权
    Method for carrying out homogeneously catalyzed reactions 有权
    进行均相催化反应的方法

    公开(公告)号：US06392062B1

    公开(公告)日：2002-05-21

    申请号：US09711133

    申请日：2000-11-14

    Applicant: Thomas Haas

    Inventor： Thomas Haas

    IPC: C07D49300

    CPC classification number: C07B61/00 ,  B01J8/008 ,  B01J8/02 ,  B01J8/08 ,  B01J2208/00212 ,  B01J2208/00371 ,  B01J2208/024 ,  C07C29/60

    Abstract: The conversion rate of a homogeneously catalyzed reaction in which an educt is converted into a reaction product with addition or cleavage of a reaction partner or under isomerization in a liquid phase that contains an effective amount in dissolved form of a catalyst suitable for the reaction can be significantly increased in that the liquid phase containing the educt and homogeneous catalyst and, to the extent required, reaction partners [2nd] to be attached are brought into contact with a stationary or moved bed consisting of porous particles, especially particles with a pore volume of 0.1 to 3 ml/g. The liquid phase is preferably conducted in a trickle bed operation over a stationary fixed bed.

    Abstract translation: 通过添加或裂解反应伴侣或在含有溶解形式的适合于该反应的催化剂的有效量的液相中异构化将衍生物转化为反应产物的均匀催化反应的转化率可以是 显着增加，其中含有离子和均相催化剂的液相，并且在所要求的程度上使待连接的反应配体[2]与由多孔颗粒组成的静止或移动的床接触，特别是孔体积为 0.1〜3ml / g。 液相优选在静止固定床上的滴流床操作中进行。

    Moving bed gas/solids contact apparatus
    15.
    发明授权
    Moving bed gas/solids contact apparatus 失效
    移动床气/固体接触装置

    公开(公告)号：US5165900A

    公开(公告)日：1992-11-24

    申请号：US606914

    申请日：1990-10-13

    Applicant: Frank J. Miksitz

    Inventor： Frank J. Miksitz

    IPC: B01D46/34 ,  B01J8/08

    CPC classification number: B01J8/08 ,  B01D46/34

    Abstract: Gas/solids contact apparatus includes a tower-like, vertical vessel divided by internal wall structures into three axially-extending, concentric spaces. An inner space, typically of generally circular cross section and extending along the axis of the vessel, receives the gas which is to be contacted with particulate solids. An intermediate space, which may have a variety of configurations, surrounds the inner space and, during operation the contactor, contains a downwardly moving bed of solids. An outer space, typically of annular configuration, surrounds the intermediate space and serves to collect gas which flows from the inner space, generally horizontally through the moving bed of solids and then into the outer space for discharge through a gas outlet. In a preferred embodiment the moving bed of solids is contained by louvered walls, and these walls are constructed as modules which can be arranged to provide contactors having different gas and solids handling capacities.

    Abstract translation: 气体/固体接触装置包括由内部壁结构分成三个轴向延伸的同心空间的塔状立式容器。 通常为大致圆形横截面且沿着容器的轴线延伸的内部空间接收与微粒固体接触的气体。 可以具有各种构造的中间空间围绕内部空间，并且在操作期间，接触器包含向下移动的固体床。 通常为环形构造的外部空间包围中间空间，用于收集从内部空间流出的气体，该气体通常水平地穿过移动的固体床，然后进入外部空间，以通过气体出口排出。 在优选实施例中，固体的移动床由百叶窗壁容纳，并且这些壁被构造为可以布置成提供具有不同气体和固体处理能力的接触器的模块。

    Multiple arc plasma device with continuous gas jet
    16.
    发明授权
    Multiple arc plasma device with continuous gas jet 失效
    具有连续气体喷射的多弧等离子体装置

    公开(公告)号：US4818837A

    公开(公告)日：1989-04-04

    申请号：US88610

    申请日：1987-08-24

    Applicant: Emil Pfender

    Inventor： Emil Pfender

    IPC: B01J8/08 ,  B01J12/00 ,  B01J19/08 ,  B05B7/22 ,  C23C4/12 ,  H01J37/32 ,  H05H1/32 ,  H05H1/36 ,  H05H1/42 ,  H05H1/44 ,  B23K9/00

    CPC classification number: H01J37/32 ,  B01J12/002 ,  B01J19/088 ,  B01J8/08 ,  B05B7/226 ,  C23C4/131 ,  H05H1/32 ,  H05H1/36 ,  H05H1/42 ,  H05H1/44 ,  B01J2219/0894

    Abstract: A multiple cathode DC arc plasma generator arrangement is used in connection with a single anode for thermal arc plasma processing of materials. A nozzle is provided to introduce a gas in approximately the center of the multiple cathodes, towards the anode. The nozzle injects the gas into the center of the plasma column generated between the cathodes and anode to stabilize such arc and affect the self-induced electrode jets. This provides control of the heat transfer to the anode and permits feeding of particulate matter into the core of the plasma column to enhance inflight processing (melting and/or chemical reaction) of the matter. A set of gas nozzles positioned radially about the anode may be employed for feeding of particulate matter at the anode surface.

    Abstract translation: 多阴极直流电弧等离子体发生器装置与用于材料的热电弧等离子体处理的单个阳极结合使用。 提供喷嘴以将多个阴极的大致中心的气体引向阳极。 喷嘴将气体注入在阴极和阳极之间产生的等离子体柱的中心，以稳定这种电弧并影响自身引发的电极射流。 这提供了对阳极的热传递的控制，并且允许将颗粒物质进料到等离子体柱的芯中，以增强物质的机加工（熔化和/或化学反应）。 可以使用围绕阳极径向设置的一组气体喷嘴用于在阳极表面处供给颗粒物质。

    Method of utilizing a plasma column
    17.
    发明授权
    Method of utilizing a plasma column 失效
    利用等离子体柱的方法

    公开(公告)号：US4725447A

    公开(公告)日：1988-02-16

    申请号：US817759

    申请日：1986-01-06

    Applicant: Emil Pfender

    Inventor： Emil Pfender

    IPC: B01J8/08 ,  B01J12/00 ,  B01J19/08 ,  B05B7/22 ,  C23C4/12 ,  H01J37/32 ,  H05H1/32 ,  H05H1/36 ,  H05H1/42 ,  H05H1/44 ,  B05D3/06

    CPC classification number: H05H1/44 ,  B01J12/002 ,  B01J19/088 ,  B01J8/08 ,  B05B7/226 ,  C23C4/131 ,  H01J37/32 ,  H05H1/32 ,  H05H1/36 ,  H05H1/42 ,  B01J2219/0894

    Abstract: A multiple cathode DC arc plasma generator arrangement is used in connection with a single anode for thermal arc plasma processing of materials. A nozzle is provided to introduce a gas in approximately the center of the multiple cathodes, towards the anode. The nozzle injects the gas into the center of the plasma column generated between the cathodes and anode to stabilize such arc and affect the self-induced electrode jets. This provides control of the heat transfer to the anode and permits feeding of particulate matter into the core of the plasma column to enhance inflight processing (melting and/or chemical reaction) of the matter. A set of gas nozzles positioned radially about the anode may be employed for feeding of particulate matter at the anode surface.

    Abstract translation: 多阴极直流电弧等离子体发生器装置与用于材料的热电弧等离子体处理的单个阳极结合使用。 提供喷嘴以将多个阴极的大致中心的气体引向阳极。 喷嘴将气体注入在阴极和阳极之间产生的等离子体柱的中心，以稳定这种电弧并影响自身引发的电极射流。 这提供了对阳极的热传递的控制，并且允许将颗粒物质进料到等离子体柱的芯中，以增强物质的机加工（熔化和/或化学反应）。 可以使用围绕阳极径向设置的一组气体喷嘴用于在阳极表面处供给颗粒物质。

    Fluid solid contact process and apparatus
    18.
    发明授权
    Fluid solid contact process and apparatus 失效
    流体固体接触方法和装置

    公开(公告)号：US4035292A

    公开(公告)日：1977-07-12

    申请号：US576872

    申请日：1975-05-12

    Applicant: Alexander Himsley

    Inventor： Alexander Himsley

    IPC: B01D15/00 ,  B01J8/08 ,  B01J8/12 ,  B01J47/10 ,  C02F1/28 ,  C22B3/02 ,  C22B60/02 ,  C01G43/00

    CPC classification number: C22B3/02 ,  B01D15/00 ,  B01J47/10 ,  B01J8/08 ,  B01J8/125 ,  C02F1/28 ,  C22B3/42 ,  C22B60/0265 ,  Y02P10/234

    Abstract: An improved process for continuous counter-current contact between a fluid to be treated and solid particles wherein the fluid flows through a column containing a plurality of contacting chambers each of which contains solid particles and in which intermittent transfer of the particles in a direction opposite to that of the fluid from each chamber to the chamber immediately adjacent is effected while maintaining a continuous flow of the fluid through the column.

    Abstract translation: 一种用于待处理流体和固体颗粒之间的连续逆流接触的改进方法，其中流体流过包含多个接触室的塔，每个接触室均含有固体颗粒，并且其中颗粒沿与...相反的方向间歇转移 在保持流体通过柱的连续流动的同时实现从每个室到紧邻的室的流体的流体。

    Reaction apparatus
    19.
    发明授权
    Reaction apparatus 失效
    反应装置

    公开(公告)号：US3948609A

    公开(公告)日：1976-04-06

    申请号：US429829

    申请日：1974-01-02

    Applicant: Nazim Museib Ogly Guseinov ,  Vageb Safarovich Aliev

    Inventor： Nazim Museib Ogly Guseinov ,  Vageb Safarovich Aliev

    IPC: B01J8/08 ,  B01J8/12 ,  B01J8/18

    CPC classification number: B01J8/08

    Abstract: In the reaction contrivance disclosed which serves the purpose of oxidizing hydrocarbons over a catalyst, with the catalyst being disposed in a casing of the contrivance. Next to an inlet into a reactor disposed in the casing, is a mixing chamber fitted rigidly, and linked with the casing of the contrivance. A separator is arranged at the outlet of the reactor. The mixing chamber provides a means of forming a reaction mixture of the reactants and the catalyst drawn from the casing and into the reactor. By virtue of this arrangement the entire surface of catalyst is in contact with the reactants and the yield of final product increases.

    Abstract translation: 在所公开的用于在催化剂上氧化烃的目的的反应设备中，催化剂被置于设计的外壳中。 在设置在壳体中的反应器的入口旁边，是刚性地配合并与设计的壳体连接的混合室。 在反应器的出口处布置有分离器。 混合室提供了形成反应物和催化剂从壳体中抽出并进入反应器的反应混合物的方法。 由于这种布置，催化剂的整个表面与反应物接触，并且最终产物的收率增加。

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