公开(公告)号：US20060100387A1

公开(公告)日：2006-05-11

申请号：US11299676

申请日：2005-12-13

Applicant: Hideyuki Takahashi ,  Bunji Uchino

Inventor： Hideyuki Takahashi ,  Bunji Uchino

IPC: C08F8/14

CPC classification number: C09D201/06 ,  C09D7/65 ,  C09D133/066 ,  C09D133/26 ,  C09D201/005 ,  Y10T428/31551

Abstract: The invention provides stain-proofing agents capable of forming coating films excellent in rain streak stain resistance and durability thereof, coating compositions comprising the stain-proofing agents, and articles coated therewith. A stain-proofing agent comprising a polymer which contains at least one repeating unit having at least two hydroxyl groups, wherein the content (by mass) of the repeating unit is more than 10%. A stain-proofing agent comprising a polymer which contains at least two repeating units having hydroxymethyl groups, wherein the content (by mass) of the repeating unit is more than 30%. A coating composition comprising such a stain-proofing agent and a coating resin such as a fluororesin.

Abstract translation: 本发明提供能够形成耐雨渍性和耐久性优异的涂膜的抗污染剂，包含防污剂的涂料组合物和涂覆的制品。 一种防污剂，其含有含有至少一个具有至少两个羟基的重复单元的聚合物，其中重复单元的含量（质量比）大于10％。 一种防污剂，其包含含有至少两个具有羟甲基的重复单元的聚合物，其中重复单元的含量（质量比）大于30％。 包含这种防污剂和涂料树脂如氟树脂的涂料组合物。

公开(公告)号：US20050245661A1

公开(公告)日：2005-11-03

申请号：US10512157

申请日：2003-04-10

Applicant: Naoki Kodama ,  Kunio Takahashi ,  Shidzuka Yamazawa

Inventor： Naoki Kodama ,  Kunio Takahashi ,  Shidzuka Yamazawa

IPC: C08G18/62 ,  C08G18/70 ,  C09D5/02 ,  C09D175/04 ,  C09D201/06 ,  C08K3/20

CPC classification number: C09D5/02 ,  C08G18/6254 ,  C08G18/706 ,  C09D175/04 ,  C09D201/06

Abstract: The present invention has for its object to provide an emulsion polymer resin composition adapted to give a coating film having an excellent appearance in terms of gloss, image sharpness, and apparent thickness, be satisfactory in curability and storage stability, contribute to cost reduction, express satisfactory coating film properties such as hardness, high impact resistance, scratch resistance, acid rain resistance, and weather resistance, and be conducive to a reduced VOC level, a curable composition comprising the above emulsion polymer resin composition and a crosslinking agent, and a cured coating film formed from the above curable composition. The present invention is an emulsion polymer resin composition which contains a hydroxyl group and a functional group reactive with the hydroxyl group within the same particle and has a weight average molecular weight of not less than 10000 but not more than 500000.

Abstract translation: 本发明的目的是提供一种乳液聚合物树脂组合物，其适用于在光泽度，图像清晰度和表观厚度方面具有优异外观的涂膜，令人满意的固化性和储存稳定性，有助于降低成本，快速 包含上述乳液聚合物树脂组合物和交联剂的可固化组合物和硬化剂的固化性组合物，包括硬度，耐冲击性，耐擦伤性，耐酸雨性和耐候性等令人满意的涂膜性能，并且有助于降低VOC水平 由上述可固化组合物形成的涂膜。 本发明是一种乳液聚合物树脂组合物，其含有羟基和与该相同粒子内的羟基具有反应性的官能团，其重均分子量不小于10000，但不大于500000。

公开(公告)号：US06783857B2

公开(公告)日：2004-08-31

申请号：US10181750

申请日：2002-07-19

Applicant: Arihiro Anada ,  Shoji Okamoto ,  Kenjin Shiba ,  Hayami Onishi

Inventor： Arihiro Anada ,  Shoji Okamoto ,  Kenjin Shiba ,  Hayami Onishi

IPC: B32B2730

CPC classification number: C08J7/047 ,  C08J2429/00 ,  C09D201/06 ,  Y10T428/1341 ,  Y10T428/1379 ,  Y10T428/31504 ,  Y10T428/31507 ,  Y10T428/31743 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31928 ,  Y10T428/31935

Abstract: Using a gas barrier resin composition including 83 to 15% by mass of a compound (A) having two or more hydroxyl groups in a molecule thereof and 17 to 85% by mass of a compound (B) in which at least one carboxyl group is bound to each of three or more consecutive carbon atoms in a molecule thereof, wherein the compound (B) is any one of a compound in which no anhydrous structure is made among the carboxyl groups and a compound in which at least one anhydrous structure is made among the carboxyl groups, or using a gas barrier coating agent including the compound (A), the compound (B) and a solvent, the present invention provides a gas barrier molded material, which has high gas barrier property in that it has less reduction of gas barrier property even in a high humidity atmosphere, has excellent transparency, does not generate poisonous gas when it is subjected to an incineration treatment, is friendly to the natural environment because of the non-use of organic solvents, and has good productivity.

Abstract translation: 使用包含83〜15质量％的分子中具有两个以上羟基的化合物（A）和17〜85质量％的化合物（B）的阻气性树脂组合物，其中至少一个羧基为 在其分子中连接三个或更多个连续碳原子中的每一个，其中化合物（B）是其中在羧基中不形成无水结构的化合物和至少一种无水结构的化合物中的任何一种 在羧基中，或者使用包含化合物（A），化合物（B）和溶剂的气体阻隔涂层剂，本发明提供阻气性模塑材料，其具有较高的阻气性，因为它具有较少的降低 即使在高湿度气氛下也具有阻气性，具有优异的透明性，在进行焚烧处理时不产生有毒气体，因为不使用有机溶剂而对自然环境友好，并且具有良好的 生产率。

公开(公告)号：US06756420B2

公开(公告)日：2004-06-29

申请号：US10266593

申请日：2002-10-09

Applicant: Tetsuo Ogawa ,  Hisashi Isaka

Inventor： Tetsuo Ogawa ,  Hisashi Isaka

IPC: C08F250

CPC classification number: C09D201/06 ,  B05D1/02 ,  B05D3/061 ,  B05D3/067 ,  B05D7/536 ,  B05D7/576 ,  C08G18/341 ,  C08G18/4291 ,  C08G18/6254 ,  C08G18/792 ,  C08G18/8077 ,  C09D175/06 ,  G03F7/032 ,  G03F7/038 ,  C08L2666/16

Abstract: This invention provides a high-solids coating composition which comprises (A) a compound which has at least one radically polymerizable unsaturated group per molecule, (B) a hydroxyl group-containing ester compound which is obtained by ester-forming addition reaction between 2,2-dimethylolalkanoic acid having 6 to 8 carbon atoms and alkanoic acid monoglycidylester, and which has an acid value of 20 mgKOH/g or less, (C) a curing agent which is reactive with the above-mentioned hydroxyl group-containing ester compound (B), and (D) a photopolymerization initiator, and also provides a process to form a coating film by spray coating of said coating composition, which process is characterized by irradiating flying paint particles which have been sprayed and/or paint which has been applied onto a substrate with active energy ray so as to make the coating composition partially react, and by subsequently heating the coating composition.

Abstract translation: 本发明提供了一种高固含量涂料组合物，其包含（A）每分子具有至少一个可自由基聚合的不饱和基团的化合物，（B）含羟基的酯化合物，其通过酯化形成加成反应获得， 具有6至8个碳原子的2-二羟甲基链烷酸和链烷酸单缩水甘油酯，其酸值为20mgKOH / g以下，（C）与上述含羟基酯化合物反应的固化剂（ B）和（D）光聚合引发剂，并且还提供通过所述涂料组合物的喷涂形成涂膜的方法，该方法的特征在于照射已经喷涂的飞溅涂料颗粒和/或涂布的涂料 到具有活性能量射线的基底上，以使涂料组合物部分反应，随后加热涂料组合物。

公开(公告)号：US06730740B1

公开(公告)日：2004-05-04

申请号：US09405923

申请日：1999-09-24

Applicant: Dirk Emiel Paula Mestach ,  Maarten Johannes Jacobus Weber ,  Genevieve Delaunoit ,  Wincenty Lambertus Stanislaw Pilaszek

Inventor： Dirk Emiel Paula Mestach ,  Maarten Johannes Jacobus Weber ,  Genevieve Delaunoit ,  Wincenty Lambertus Stanislaw Pilaszek

IPC: C08L3300

CPC classification number: C09D201/06 ,  C08L101/06

Abstract: The invention pertains to an aqueous cross-linkable polymer composition comprising: W a) a water-soluble first polymer comprising acid groups, which is at least partially neutralized with a volatile base; b) a dispersion of a substantially water-insoluble second polymer, which comprises carbonyl-functional groups, which may be produced by emulsion polymerization in the presence of an aqueous solution of the first polymer; c) a cross-linking agent which can react by condensation with the carbonyl-functional groups of the second polymer; and d) a water-soluble, amine-functional third polymer.

Abstract translation: 本发明涉及一种水可交联聚合物组合物，其包含：Wa）包含酸基的水溶性第一聚合物，其至少部分用挥发性碱中和; b）基本上不溶于水的第二聚合物的分散体，其中 包括羰基官能团，其可以在第一聚合物的水溶液存在下通过乳液聚合制备; c）交联剂，其可以与第二聚合物的羰基官能团缩合反应; andd）水溶性胺官能第三聚合物。

公开(公告)号：US06562893B2

公开(公告)日：2003-05-13

申请号：US10112511

申请日：2002-03-28

Applicant: Robert John Barsotti ,  Isidor Hazan ,  Bruce Lyle Neff

Inventor： Robert John Barsotti ,  Isidor Hazan ,  Bruce Lyle Neff

IPC: C09D20106

CPC classification number: C09D201/06 ,  C08G18/423 ,  C08G18/718 ,  C08G18/792 ,  C09D175/06 ,  Y10T428/31511 ,  Y10T428/31547 ,  Y10T428/31551 ,  Y10T428/31663 ,  Y10T428/31786 ,  Y10T428/31855

Abstract: A curable coating composition comprising functionalized oligomer components i and ii which cross-link at cure to form a three-dimensional network having chains of substantially uniform, controllable molecular weight between cross-links; oligomers i and ii having weight average molecular weights not exceeding about 3,000, a polydispersity for (i) not exceeding about 1.5, and functionalities that react with one another to cross-link i and ii at cure to yield coatings with an excellent balance of hardness and mar resistance.

公开(公告)号：US06562463B2

公开(公告)日：2003-05-13

申请号：US09169262

申请日：1998-10-09

Applicant: Martin Melchiors ,  Wieland Hovestadt ,  Jochen Brück ,  Theodor Engbert ,  Hans-Josef Buysch

Inventor： Martin Melchiors ,  Wieland Hovestadt ,  Jochen Brück ,  Theodor Engbert ,  Hans-Josef Buysch

IPC: B32B2730

CPC classification number: C09D167/00 ,  C08G18/225 ,  C08G18/244 ,  C08G18/283 ,  C08G18/4063 ,  C09D169/00 ,  C09D175/06 ,  C09D201/06 ,  Y10T428/31504 ,  Y10T428/31507 ,  Y10T428/31511 ,  Y10T428/31551 ,  Y10T428/31786 ,  Y10T428/31931 ,  Y10T428/31935 ,  C08L75/04 ,  C08L2666/34

Abstract: This invention relates to a new one-component stoving composition, which can be baked at low temperatures without the release of volatile compounds and which also has satisfactory stability when stored at room temperature. The invention also relates to the use of the one-component stoving composition.

公开(公告)号：US20030049435A1

公开(公告)日：2003-03-13

申请号：US09860944

申请日：2001-05-18

Applicant: 3M Innovative Properties Company

Inventor： Louis C. Haddad ,  James I. Hembre ,  Jerald K. Rasmussen ,  Daniel Sarpong

IPC: B32B005/16

CPC classification number: B82Y30/00 ,  B01J2219/00315 ,  B01J2219/00317 ,  B01J2219/00497 ,  B01J2219/00511 ,  B01J2219/00527 ,  B01J2219/00585 ,  B01J2219/00596 ,  B01J2219/00605 ,  B01J2219/0061 ,  B01J2219/00612 ,  B01J2219/00621 ,  B01J2219/00626 ,  B01J2219/00637 ,  B01J2219/00641 ,  B01J2219/00644 ,  B01J2219/00659 ,  B01J2219/00677 ,  B01J2219/00725 ,  C07B2200/11 ,  C08F8/32 ,  C08F8/42 ,  C08F220/54 ,  C08F2800/20 ,  C08F2810/20 ,  C08F2810/50 ,  C08J3/075 ,  C08J3/244 ,  C08J3/246 ,  C08J7/047 ,  C08K5/17 ,  C08K5/544 ,  C09D133/26 ,  C09D139/04 ,  C09D157/10 ,  C09D201/06 ,  C12N11/08 ,  C40B40/10 ,  C40B60/14 ,  Y10T428/256 ,  Y10T428/29 ,  Y10T428/2907 ,  Y10T428/2913 ,  Y10T428/2924 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/2998 ,  Y10T428/31504 ,  Y10T428/31663 ,  Y10T428/31855 ,  Y10T428/31935 ,  C08L33/26 ,  C08L2666/36 ,  C08F220/56 ,  C08F226/06

Abstract: Surface coatings including azlactone-functional hydrogels and articles with the coatings disposed thereon are disclosed. Methods of making the coating and controlling the gellation time of the hydrogels are also disclosed.

Abstract translation: 公开了包括吖内酯官能水凝胶和其上涂覆有涂层的制品的表面涂层。 还公开了制备涂层和控制水凝胶的凝胶化时间的方法。

公开(公告)号：US06432484B1

公开(公告)日：2002-08-13

申请号：US09744101

申请日：2001-01-16

Applicant: Patrick Henry Corcoran ,  Carl Brent Douglas ,  Eric Diaz Felton ,  Josef Huybrechts ,  Gary Delmar Jaycox ,  Patricia Mary Ellen Sormani ,  Marko Strukelj ,  Lech Wilczek

Inventor： Patrick Henry Corcoran ,  Carl Brent Douglas ,  Eric Diaz Felton ,  Josef Huybrechts ,  Gary Delmar Jaycox ,  Patricia Mary Ellen Sormani ,  Marko Strukelj ,  Lech Wilczek

IPC: B05D700

CPC classification number: C09D201/06 ,  C09D201/005 ,  C08L2666/28

Abstract: The invention is directed to a two-pack high solids low VOC ambient curable coating composition, which includes cross linking and binder components. The crosslinking component includes a polyamine, a polyketimine, or a combination thereof. The polyamine is provided on an average with at least two amine functionalities per polymer chain and the polyketimine is provided on an average with at least two ketimine functionalities per polymer chain. A reactive diluent in the binder component includes a macromolecule substantially free from acrylate functionalities and having at least two acetoacetate functionalities per the macromolecule. If desired, the coating composition includes a binder polymer. The coating composition of the invention is particularly suited in automotive refinish coatings.

Abstract translation: 本发明涉及包含交联和粘合剂组分的双组分高固含量低VOC环境可固化涂料组合物。 交联组分包括多胺，聚酮亚胺或其组合。 每个聚合物链平均提供至少两个胺官能团的多胺，并且每个聚合物链平均提供至少两个酮亚胺官能度的聚酮亚胺。 粘合剂组分中的反应性稀释剂包括基本上不含丙烯酸酯官能团并且每个大分子具有至少两个乙酰乙酸酯官能团的大分子。 如果需要，涂料组合物包括粘合剂聚合物。 本发明的涂料组合物特别适用于汽车修补漆。

公开(公告)号：US06201056B1

公开(公告)日：2001-03-13

申请号：US09434733

申请日：1999-11-05

Applicant: Dong-Wei Zhu

Inventor： Dong-Wei Zhu

IPC: C08K336

CPC classification number: C09D201/02 ,  C09D133/16 ,  C09D143/04 ,  C09D201/06 ,  C08L2666/02

Abstract: Coatings prepared from water-based compositions comprise an aqueous solution, emulsion, or dispersion of (a) a water-soluble or water-dispersible polymer or oligomer having at least one anionic moiety which is capable of reacting with an oxazoline or oxazine moiety; (b) a water-soluble or water-dispersible polymer or oligomer having at least one oxazoline or oxazine moiety; and (c) colloidal silica; at least one of the components (a) and (b) further comprising at least one fluoroaliphatic moiety. The coatings have low surface energy and high abrasion resistance.

Abstract translation: 由水基组合物制备的涂料包含（a）具有至少一个能够与恶唑啉或恶嗪部分反应的阴离子部分的水溶性或水分散性聚合物或低聚物的水溶液，乳液或分散体; （b）具有至少一个恶唑啉或恶嗪部分的水溶性或水分散性聚合物或低聚物; 和（c）胶体二氧化硅; 组分（a）和（b）中的至少一种还包含至少一个氟脂族部分。 涂层具有低表面能和高耐磨性。