Low-emissions diesel fuel blend
    12.
    发明授权
    Low-emissions diesel fuel blend 有权
    低排放柴油混合物

    公开(公告)号:US07285140B2

    公开(公告)日:2007-10-23

    申请号:US10357027

    申请日:2003-02-03

    Abstract: A low-emissions diesel fuel comprises a catalyzed blend of fatty acid esters, preferably derived from soybean oil and/or tallow and aviation kerosene. The catalyzed blend is effective in lowering regulated emission pollutants, among which are NOx, particulates, hydrocarbons and carbon monoxide. The catalyst will comprise fuel-soluble platinum and/or cerium or iron. The cerium or iron are typically employed at concentrations of from 2 to 25 ppm and the platinum from 0.05 to 2 ppm, with preferred levels of cerium or iron being from 5 to 10 ppm, e.g., 7.5 ppm, and the platinum being employed at a level of from 0.1 to 0.5 ppm, e.g., 0.15 ppm. A preferred ratio of cerium and/or iron to platinum is from 75:1 to 10:1. The jet fuel component will typically be employed at a volume ratio to the fatty acid esters of from about 2:1 to about 5:1, e.g., about 4:1. The full range of blends extends from 50:1 to 1:50 with some benefit. The jet fuel component of the blend preferably contains grade 55, 50-300 ppm detergent, 25 to about 500 ppm lubricity additive and 0.1-1 ppm platinum COD and 5-20 ppm cerium oleate or octoate. In addition to the fuel blend, a method is provided for reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined.

    Abstract translation: 低排放柴油包括脂肪酸酯的催化混合物,优选衍生自大豆油和/或牛脂和航空煤油。 催化的共混物有效地降低了调节的排放污染物,其中包括无机颗粒,碳氢化合物和一氧化碳。 催化剂将包括燃料可溶的铂和/或铈或铁。 通常使用铈或铁的浓度为2至25ppm,铂为0.05至2ppm,优选的铈或铁的含量为5至10ppm,例如7.5ppm,铂用于 水平为0.1至0.5ppm,例如0.15ppm。 铈和/或铁与铂的优选比例为75:1至10:1。 通常,喷气燃料组分的使用量与脂肪酸酯的体积比为约2:1至约5:1,例如约4:1。 混合物的范围从50:1增加到1:50,具有一定的优势。 共混物的喷气燃料组分优选含有55级,50-300ppm洗涤剂,25-约500ppm润滑性添加剂和0.1-1ppm铂COD和5-20ppm油酸铈或辛酸铈。 除了燃料混合物之外,还提供了一种用于减少来自柴油发动机的污染物排放的方法,包括以定义的燃料运行发动机。

    LOW-EMISSIONS DIESEL FUEL BLEND
    13.
    发明申请
    LOW-EMISSIONS DIESEL FUEL BLEND 有权
    低排放柴油燃料混合

    公开(公告)号:US20070209272A1

    公开(公告)日:2007-09-13

    申请号:US10357027

    申请日:2003-02-03

    Inventor: James Valentine

    Abstract: A low-emissions diesel fuel comprises a catalyzed blend of fatty acid esters, preferably derived from soybean oil and/or tallow and aviation kerosene. The catalyzed blend is effective in lowering regulated emission pollutants, among which are NOx, particulates, hydrocarbons and carbon monoxide. The catalyst will comprise fuel-soluble platinum and/or cerium or iron. The cerium or iron are typically employed at concentrations of from 2 to 25 ppm and the platinum from 0.05 to 2 ppm, with preferred levels of cerium or iron being from 5 to 10 ppm, e.g., 7.5 ppm, and the platinum being employed at a level of from 0.1 to 0.5 ppm, e.g., 0.15 ppm. A preferred ratio of cerium and/or iron to platinum is from 75:1 to 10:1. The jet fuel component will typically be employed at a volume ratio to the fatty acid esters of from about 2:1 to about 5:1, e.g., about 4:1. The full range of blends extends from 50:1 to 1:50 with some benefit. The jet fuel component of the blend preferably contains grade 55, 50-300 ppm detergent, 25 to about 500 ppm lubricity additive and 0.1-1 ppm platinum COD and 5-20 ppm cerium oleate or octoate. In addition to the fuel blend, a method is provided for reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined.

    Abstract translation: 低排放柴油包括脂肪酸酯的催化混合物,优选衍生自大豆油和/或牛脂和航空煤油。 催化的共混物有效地降低了调节的排放污染物,其中包括无机颗粒,碳氢化合物和一氧化碳。 催化剂将包括燃料可溶的铂和/或铈或铁。 通常使用铈或铁的浓度为2至25ppm,铂为0.05至2ppm,优选的铈或铁的含量为5至10ppm,例如7.5ppm,铂用于 水平为0.1至0.5ppm,例如0.15ppm。 铈和/或铁与铂的优选比率为75:1至10:1。 通常,喷气燃料组分的使用量与脂肪酸酯的体积比为约2:1至约5:1,例如约4:1。 混合物的范围从50:1增加到1:50,具有一定的优势。 共混物的喷气燃料组分优选含有55级,50-300ppm洗涤剂,25-约500ppm润滑性添加剂和0.1-1ppm铂COD和5-20ppm油酸铈或辛酸铈。 除了燃料混合物之外,还提供了一种用于减少来自柴油发动机的污染物排放的方法,包括以定义的燃料运行发动机。

    Low-emissions diesel fuel
    17.
    发明授权
    Low-emissions diesel fuel 失效
    低排放柴油

    公开(公告)号:US07063729B2

    公开(公告)日:2006-06-20

    申请号:US10290798

    申请日:2002-11-08

    Abstract: A low-emissions diesel fuel comprises fungible aviation kerosene grade 55, 50–300 ppm detergent, 25–500 ppm lubricity additive and a bimetallic, fuel soluble platinum and cerium fuel borne catalyst (e.g., 0.1–2.0 ppm platinum COD and 5–20 ppm cerium oleate). The fuel can be used as is or in the form of an emulsion. A method of reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined. Retarding engine timing can further reduce NOx and the use of a diesel particulate filter and/or diesel oxidation catalyst can provide further reductions in carbon monoxide, unburned hydrocarbons and particulates.

    Abstract translation: 低排放柴油包括可替换航空煤油55级,50-300ppm洗涤剂,25-500ppm润滑添加剂和双金属,燃料可溶性铂和铈燃料催化剂(例如,0.1-2.0ppm铂COD和5-20 ppm油酸铈)。 燃料可以原样使用或以乳液的形式使用。 一种减少来自柴油发动机的污染物排放的方法,包括以定义的燃料运行发动机。 阻止发动机正时可以进一步减少NOx,并且使用柴油微粒过滤器和/或柴油氧化催化剂可以进一步减少一氧化碳,未燃碳氢化合物和颗粒物。

    Drag reduction using fatty acids
    18.
    发明申请
    Drag reduction using fatty acids 失效
    使用脂肪酸减阻

    公开(公告)号:US20020183214A1

    公开(公告)日:2002-12-05

    申请号:US09944837

    申请日:2001-08-30

    Abstract: Non-polymeric fatty acid drag reducing agents are described herein. These additives are useful to reduce drag in hydrocarbon fluids and multiphase fluids of hydrocarbon(s) and water. No injection probes or other special equipment is expected to be required to introduce the drag reducing agent into the liquid stream, nor is grinding (cryogenic or otherwise) of the additive necessary to form a suitable drag reducing agent. The drag reducing additives of the invention are not subject to shear degradation and do not cause undesirable changes in the emulsion or fluid quality of the fluid being treated, or undesirable foaming. The drag reducing additives include fatty acids, alkoxylated derivatives of fatty acids, organic and inorganic salts of fatty acids and alkoxylated derivatives thereof, and esters of fatty acids and alkoxylated derivatives thereof, and mixtures thereof.

    Abstract translation: 本文描述了非聚合脂肪酸减阻剂。 这些添加剂可用于减少烃流体和烃类和水的多相流体中的阻力。 预计不需要注射探针或其他特殊设备将减阻剂引入液体流中,也不需要研磨(低温或其他)添加剂,以形成合适的减阻剂。 本发明的减阻添加剂不会受到剪切降解,并且不会引起所处理的流体的乳液或流体质量的不期望的变化或不期望的起泡。 减阻添加剂包括脂肪酸,脂肪酸的烷氧基化衍生物,脂肪酸的有机和无机盐及其烷氧基化衍生物,脂肪酸及其烷氧基化衍生物的酯,及其混合物。

    Heavy oils having improved properties and an additive therefor
    19.
    发明授权
    Heavy oils having improved properties and an additive therefor 失效
    具有改进性能的重油和其添加剂

    公开(公告)号:US06488724B1

    公开(公告)日:2002-12-03

    申请号:US08957834

    申请日:1997-10-27

    Abstract: The additive described essentially comprises a selected alkoxylated fatty amine or fatty amine derivative and a special metal salt compound, preferably a metal soap. This additive for heavy oils effects a good emulsification or dispersion of asphaltenes and other higher-molecular weight compounds and, in addition, inter alia, increased storage stability, improved pumpability due to decreased viscosity of the oil and longer service lives of the filter systems. In addition, it also effects enhanced combustion of the heavy oils. The effective amount of additive in these oils is 2 to 2000 ppm. The oils described are suitable, in particular, as furnace fuel for industrial plants and power stations and as engine fuel for marine engines.

    Abstract translation: 所描述的添加剂基本上包括选择的烷氧基化脂肪胺或脂肪胺衍生物和特殊金属盐化合物,优选金属皂。 这种重油添加剂可以使沥青质和其他高分子量化合物具有良好的乳化或分散性,此外,尤其是由于油的粘度降低和过滤系统的使用寿命延长,储存稳定性提高,泵送性提高。 此外,它还会影响重油的燃烧。 这些油中的添加剂的有效量为2〜2000ppm。 所描述的油特别适用于工业设备和发电站的炉燃料以及船用发动机的发动机燃料。

    Process for the selective noncatalytic reduction of the emission of
pollutants from oil-fired boiler plants
    20.
    发明授权
    Process for the selective noncatalytic reduction of the emission of pollutants from oil-fired boiler plants 失效
    从燃油锅炉厂排放污染物的选择性非生物降解方法

    公开(公告)号:US5118282A

    公开(公告)日:1992-06-02

    申请号:US583100

    申请日:1990-09-17

    Abstract: In this process for the selective noncatalytic reduction of the emission of pollutants from oil-fired boiler plants, chemical compounds which affect the combustion process are admixed, in solutions miscible with the liquid fuel, in metered amounts to the liquid fuel or to the combustion air, among these compounds being salts of organic acids, such as naphthenates, octoates, tallates, salts of sulfonic acids, saturated or unsaturated fatty acids, such as oleic acid, and tall oil, with metals from the group of K, Ba, Mg, Ca, Ce, Mn, Fe; rare earth metals; organometallic compounds, such as carbonyl compounds, mixed cyclopentadienylcarbonyl compounds, or aromatic complexes of the transition metals Fe or Mn. For the purpose of minimizing the NO.sub.x values in the waste gas and the dust load with economical consumption of chemicals, a reducing agent is introduced in metered quantities into the firebox (burner chamber) via a boiler metering system with the use of the liquid or also gaseous carrier stream as an aqueous solution of urea or also urea precursors, such as ammonia or ammonium carbonate, which can also contain further ingredients, such as alkanols, alkanecarboxylic acids, alkanals, or alkanones.

    Abstract translation: 在这种选择性非催化还原燃油锅炉设备污染物排放的过程中,影响燃烧过程的化合物与液体燃料混溶,溶液量与液体燃料或燃烧空气混合 在这些化合物中,作为有机酸的盐,例如环烷酸盐,辛酸盐,妥尔酸盐,磺酸盐,饱和或不饱和脂肪酸如油酸和妥尔油,与K,Ba,Mg, Ca,Ce,Mn,Fe; 稀土金属; 有机金属化合物,如羰基化合物,混合环戊二烯基羰基化合物,或过渡金属Fe或Mn的芳族络合物。 为了最大限度地减少废气中的NOx值和粉尘负荷,经济地消耗化学品,将还原剂通过使用液体的锅炉计量系统引入火炉(燃烧室) 作为尿素水溶液的气态载体物流或者还可以含有其它成分如链烷醇,链烷羧酸,链烷烃或链烷烃的尿素前体,如氨或碳酸铵。

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