Method for selectively producing carbon nanostructures
    13.
    发明申请
    Method for selectively producing carbon nanostructures 审中-公开
    选择性生产碳纳米结构的方法

    公开(公告)号:US20040005269A1

    公开(公告)日:2004-01-08

    申请号:US10437512

    申请日:2003-05-14

    Abstract: A method for producing carbon nanostructures using a chemical vapor deposition process. A carbon source and a mixture catalyst are used wherein the mixture catalyst includes at least one element, from a group A including Fe, Co and Ni, and at least one supporting element, from a group B including lanthanides. The lanthanide elements can be used to lower the melting point of the catalyst by forming alloys so that the carbon nanostructures can be grown at lower temperatures. Further, the lanthanide elements also enhance catalyst activity of Ni, Co or Fe by changing the catalyst surface electronic properties. Also, the lanthanide elements also scavenger excess carbon so that carbon nanostructures can be grown without contamination.

    Abstract translation: 一种使用化学气相沉积工艺生产碳纳米结构的方法。 使用碳源和混合催化剂,其中混合物催化剂包括至少一种元素,包括来自包括镧系元素的组B的至少一种元素,包括Fe,Co和Ni以及至少一种支撑元素。 镧系元素可用于通过形成合金来降低催化剂的熔点,使得碳纳米结构可以在较低温度下生长。 此外,镧系元素还通过改变催化剂表面电子性能来提高Ni,Co或Fe的催化剂活性。 此外,镧系元素还可以清除过量的碳,使得碳纳米结构可以无污染地生长。

    Calcining apparatus and process of use
    14.
    发明申请
    Calcining apparatus and process of use 审中-公开
    煅烧装置及使用过程

    公开(公告)号:US20030215379A1

    公开(公告)日:2003-11-20

    申请号:US10394596

    申请日:2003-03-21

    CPC classification number: C01D7/00 C01D7/35

    Abstract: Disclosed is an apparatus for the calcination of materials using low temperature heating and indirect heating for calcination. Also disclosed are a variety of processes for calcination of materials which have-reduced emissions of pollutants compared to conventional processes.

    Abstract translation: 公开了一种使用低温加热和间接加热煅烧材料的装置。 还公开了与常规方法相比具有减少的污染物排放的材料的各种煅烧方法。

    Heat transfer enhancing inserts for tubular catalyst bed reactors
    15.
    发明申请
    Heat transfer enhancing inserts for tubular catalyst bed reactors 审中-公开
    用于管式催化床反应器的传热增强插入件

    公开(公告)号:US20030180201A1

    公开(公告)日:2003-09-25

    申请号:US10389187

    申请日:2003-03-14

    Abstract: A tubular reactor with a catalyst bed and inserts placed within the tubes redirecting the flow from the center to the wall of the tube. The redirected flow increases the amount of heat transfer through the system by moving the reactants from the low heat transfer zone at the center of the tube to the high heat transfer zone at the wall of the tube. In one embodiment, the tubular reactor comprises a tubular reactor having a series of tubes, within the tubes are a plurality of flow obstructing inserts and a catalyst bed. The inserts may comprise a plurality of inclined, conical, or spiral plates. The plates may be affixed to the wall of the tube and may depend on the catalyst bed for structural support.

    Abstract translation: 具有催化剂床的管式反应器和放置在管内的插入件将流体从中心重新导向管的壁。 重新引导的流量通过将反应物从管中心的低传热区域移动到管壁处的高传热区域来增加通过系统的热传递量。 在一个实施例中,管式反应器包括具有一系列管的管式反应器,管内是多个阻流插入件和催化剂床。 插入件可以包括多个倾斜的,锥形的或螺旋的板。 板可以固定到管的壁上,并且可以取决于用于结构支撑的催化剂床。

    Reactive distillation
    16.
    发明申请
    Reactive distillation 审中-公开
    反应蒸馏

    公开(公告)号:US20030124038A1

    公开(公告)日:2003-07-03

    申请号:US10348801

    申请日:2003-01-21

    Abstract: The reactive distillation is carried out in a column (1) with a packing (2) which is at least partly designed as a catalyst carrier (23). Fluids (3, 4) which form two phases of different densities flow through the packing. An internal volume flow (300) is set for the denser fluid (3), the value of which lies in an interval (I) about a distinguished value (a), with this value being associated with a dwell time distribution (32) of the denser fluid: For the distinguished value the variance (s) of the dwell time distributionnullas a function of the internal volume flownulltakes on a minimum; and at the boundaries of the named interval the internal volume flow does not differ from the distinguished value by more than 30%, preferably by more than 10%.

    Abstract translation: 反应蒸馏在具有至少部分设计为催化剂载体(23)的填料(2)的塔(1)中进行。 形成两个不同密度的相的流体(3,4)流过填料。 对于较稠密的流体(3)设置内部体积流(300),其中该值位于围绕识别值(a)的间隔(I)中,该值与停留时间分布(32)相关联 更稠密的流体:对于不同的值,驻留时间分布的方差(作为内部体积流量的函数)占最小值; 并且在所述间隔的边界处,内部体积流量与识别值没有差异超过30%,优选大于10%。

    Method of decomposing thermosetting resin, apparatus and heat control program
    18.
    发明申请
    Method of decomposing thermosetting resin, apparatus and heat control program 失效
    分解热固性树脂的方法,设备和热控程序

    公开(公告)号:US20020170474A1

    公开(公告)日:2002-11-21

    申请号:US09964581

    申请日:2001-09-28

    Abstract: A method of decomposing a thermosetting resin by a decomposer comprising the steps of: pre-heating the thermosetting resin up to a pre-heating temperature T0; kneading the pre-heated thermosetting resin together with a decomposer, and concurrently heating a mixture comprising the thermosetting resin and the decomposer up to a kneading temperature T1, thereby allowing a reaction to take place between the decomposer and the thermosetting resin to obtain a kneaded matter wherein the decomposer becomes consumed; and heating the kneaded matter to a maximum temperature T2 to thereby decompose the thermosetting resin; wherein the preheating temperature T0 is not higher than the boiling temperature of the decomposer; the kneading temperature T1 is not lower than the pre-heating temperature T0 but is lower than the thermal decomposition temperature of the thermosetting resin; the maximum temperature T2 is lower than the decomposition temperature of the thermosetting resin; and the pre-heating of the thermosetting resin is performed under the following conditions of temperature T0 and time t: 100null C.nullT0

    Abstract translation: 一种通过分解器分解热固性树脂的方法,包括以下步骤:将热固性树脂预热至预热温度T0; 将预热热固性树脂与分解器一起捏合,同时将包含热固性树脂和分解剂的混合物加热至捏合温度T1,从而使分解器和热固性树脂之间发生反应,得到捏合物 其中所述分解器消耗; 并将捏合物加热至最高温度T2,从而分解热固性树脂; 其中预热温度T0不高于分解器的沸腾温度; 捏合温度T1不低于预热温度T0,但低于热固性树脂的热分解温度; 最高温度T2低于热固性树脂的分解温度; 并且在温度T0和时间t的以下条件下进行热固性树脂的预热:在线配方> 100℃。<= T0 <260℃。 / in-line-formula> <段落lvl =“0”> 0.5分钟<= t <= 7分钟。

    Catalytic separator plate reactor and method of catalytic reforming of fuel to hydrogen
    19.
    发明申请
    Catalytic separator plate reactor and method of catalytic reforming of fuel to hydrogen 审中-公开
    催化分离板反应器和燃料对氢气的催化重整方法

    公开(公告)号:US20020168308A1

    公开(公告)日:2002-11-14

    申请号:US09972142

    申请日:2001-10-05

    Abstract: Modular, stackable, flow-through plate or channel reactor units for continuous, low temperature, catalytic reactions of two separate process reaction streams; typically the first is an exothermic combustion process and the second, an endothermic reforming process. Each reactor unit comprises two separate sets of flow channels or slot-type reaction zones formed in flow plates located between spaced, thin metal, highly heat-conductive metal foil or platelet separator walls, adjacent reactors in a stack including a common, medially located, bicatalytic separator plate, i.e., a separator plate having on opposed surfaces the same or different catalysts selected for the particular reaction taking place in the adjacent reactor zone. Each flow plate has a relieved medial area defining the reaction zone, the side walls of which are the catalyst coated separator platelets. A separator platelet thus separates two adjacent reaction zones, one on each side and functions to transfer heat from the combustion occurring at the catalyst surface in the combustion zone directly to the reforming catalyst coated on the opposed surface. The reaction zones may include structures such as grooved plates or packed spheres to direct the feedstock gases to the catalyst coated on the platelet surfaces. Support frames, gaskets, manifolding, insulating spacers, end plates and assembly hardware and methods are also disclosed. Multiple modular reactor units or cells may be stacked to provide a reactor of any desired throughput capacity and portability. The invention also comprises methods for the catalytic reforming of hydrocarbon fuels for the production of synthesis gas or hydrogen employing the bicatalytic reactor of the invention.

    Abstract translation: 模块化,可堆叠,流通板或通道反应器单元,用于两个单独的过程反应流的连续,低温,催化反应; 通常第一个是放热燃烧过程,第二个是吸热重整过程。 每个反应器单元包括形成在位于间隔开的薄金属,高导热金属箔或血小板分离器壁之间的流动板中的两组单独的流动通道或狭槽型反应区,所述叠层包括共同的,位于中间的, 双分离分离器板,即在相对表面上具有相同或不同的催化剂的隔板,所述催化剂选择用于在相邻的反应器区域中发生的特定反应。 每个流动板具有限定反应区的缓和的内侧区域,其侧壁是催化剂涂覆的分离器血小板。 因此,分离器血小板分离两个相邻的反应区,每侧有一个反应区,用于将燃烧区中催化剂表面处发生的燃烧的热量直接传递到涂覆在相对表面上的重整催化剂。 反应区可以包括诸如开槽板或填充球体的结构,以将原料气体引导到涂覆在血小板表面上的催化剂。 还公开了支撑框架,垫片,歧管,绝缘垫片,端板和组装硬件和方法。 多个模块化反应器单元或单元可以被堆叠以提供任何期望的吞吐能力和便携性的反应器。 本发明还包括使用本发明的双催化反应器用于生产合成气或氢气的烃燃料的催化重整的方法。

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