公开(公告)号：US07166753B2

公开(公告)日：2007-01-23

申请号：US10510972

申请日：2003-04-09

Applicant: Koichi Nakahara ,  Kenzo Nagami ,  Okitsugu Kajimoto ,  Kazuya Kobiro

Inventor： Koichi Nakahara ,  Kenzo Nagami ,  Okitsugu Kajimoto ,  Kazuya Kobiro

IPC: C07C45/29

CPC classification number: B01J3/006 ,  B01J3/008 ,  C01B3/32 ,  C01B2203/0216 ,  C01B2203/0805 ,  C01B2203/1217 ,  C01B2203/1229 ,  C07C45/002 ,  Y02P20/544 ,  C07C49/786 ,  C07C49/403 ,  C07C49/08 ,  C07C47/06

Abstract: A process for producing a carbonyl compound involves allowing water to undergo phase transition to a supercritical or subcritical state in the presence of an alcohol compound so as to produce/generate water-derived hydrogen and at the same time convert the alcohol compound into a corresponding carbonyl compound. Specifically, the process is carried out by introducing the alcohol in a reaction tube along with water and heating and/or pressurizing the mixture of the alcohol and the water to bring the water into a subcritical or supercritical state. In this manner, water-derived hydrogen is produced and the alcohol is converted to a corresponding carbonyl compound. The process is preferably carried out in an oxygen-free environment.

Abstract translation: 制备羰基化合物的方法包括使水在醇化合物的存在下进行相转变为超临界或亚临界状态，以产生/产生水源氢，同时将醇化合物转化为相应的羰基 复合。 具体地，该方法通过将醇与水一起引入反应管中并加热和/或加压醇和水的混合物以使水进入亚临界或超临界状态来进行。 以这种方式，产生水衍生的氢，并将醇转化为相应的羰基化合物。 该方法优选在无氧环境中进行。

公开(公告)号：US07147828B2

公开(公告)日：2006-12-12

申请号：US10239542

申请日：2002-01-23

Applicant: Noritaka Sato ,  Tsutomu Noguchi

Inventor： Noritaka Sato ,  Tsutomu Noguchi

IPC: B01J3/00 ,  B01J19/00

CPC classification number: B01J3/008 ,  B01J19/0006 ,  B01J19/0013 ,  B01J2219/00135 ,  B01J2219/00162 ,  B01J2219/002 ,  B01J2219/00211 ,  B01J2219/00231

Abstract: A reactor comprising a reacting vessel 31 that contains a fluid including high temperature and high pressure water under target reaction temperature and reaction pressure condition and performs a reaction treatment to a reactant by the fluid, a first pipe 25 connected to the reacting vessel 31 to supply the reactant to the reacting vessel 31, and a first partition means 50 for partitioning between first pipe 25 and the reacting vessel 31 so as to prevent a leakage of any one of the fluid, the reactant, and a reaction product from the reacting vessel 31 side to the first pipe 25 side. The first partition means 50 is comprised of for example a valve 51, a shaft 52, a weight 53, a supporting member 54, and a pipe 55, and normally, due to the weight 53, the valve 51 closes an opening of a bottom end of the pipe 55. That is, it isolates the pipe 55 and the inside of the reacting vessel 31. At this time, although the valve 51 does not completely seal up the inside of the reacting vessel 31, it has the ability to prevent a large amount of hot water HW in the reacting vessel 31 from leaking into the pipe 25 due to a convection current thereof.

Abstract translation: 一种反应器，包括在目标反应温度和反应压力条件下包含高温高压水的流体的反应容器31，并且通过流体对反应物进行反应处理;连接到反应容器31的第一管25， 反应容器31的反应物和第一分隔装置50，用于分隔第一管25和反应容器31之间，以防止任何一种流体，反应物和反应产物从反应容器31中泄漏 一侧到第一管25侧。 第一分隔装置50包括例如阀51，轴52，重物53，支撑构件54和管55，并且通常由于重量53，阀51关闭底部的开口 管55的端部。 也就是说，它隔离管55和反应容器31的内部。 此时，虽然阀51没有完全密封反应容器31的内部，但是它具有防止反应容器31中的大量热水HW由于对流而泄漏到管25中的能力 其中。

公开(公告)号：US20060252951A1

公开(公告)日：2006-11-09

申请号：US11275564

申请日：2006-01-17

Applicant: Walter Leitner ,  Nils Theyssen ,  Zhenshan Hou ,  Konstantin Kottsieper ,  Maurizio Solinas ,  Daniela Giunta

Inventor： Walter Leitner ,  Nils Theyssen ,  Zhenshan Hou ,  Konstantin Kottsieper ,  Maurizio Solinas ,  Daniela Giunta

IPC: C07F15/00 ,  C07C5/29 ,  C07C2/02

CPC classification number: C07C6/04 ,  B01J3/008 ,  B01J2219/0004 ,  B01J2219/00047 ,  C07B37/10 ,  C07C2531/22 ,  Y02P20/544 ,  C07C13/20

Abstract: The present invention relates to a process for carrying out olefin ring-closing metathesis (RCM) wherein compressed carbon dioxide (gaseous, liquid or supercritical) acts as solvent for the liquid or solid reactant and the products obtained therefrom, while additionally one or more ionic liquids are introduced as the 2nd phase in which homogeneous olefin metathesis catalysts are immobilised.

Abstract translation: 本发明涉及一种用于进行烯烃闭合复分解（RCM）的方法，其中压缩二氧化碳（气态，液体或超临界）用作液体或固体反应物的溶剂及其获得的产物，另外还有一种或多种离子 引入液体作为其中固定有均相烯烃复分解催化剂的第二相。

公开(公告)号：US20060185244A1

公开(公告)日：2006-08-24

申请号：US10502633

申请日：2004-02-04

Applicant: Ki Park ,  Hiroshi Tomiyasu

Inventor： Ki Park ,  Hiroshi Tomiyasu

IPC: C10J3/46

CPC classification number: B01J3/008 ,  C10J3/00 ,  C10J2300/093 ,  C10J2300/0946 ,  C10J2300/0979 ,  C10J2300/0983 ,  C10L3/08 ,  Y02P20/52 ,  Y02P20/544

Abstract: A novel process of producing gas fuel is provided, in which low quality fuel such as coal and various kinds of plastics and resins (polymeric compounds) collected as flame retardant waste are decomposed to gas in supercritical water, so that the resultant gas is effectively utilized as fuel. That is, polymeric compounds and aromatic/condensed-aromatic hydrocarbons are decomposed in supercritical water with ruthenium oxide (IV) as a catalyst. The resultant gas components through the decomposition are collected as gas fuel.

Abstract translation: 提供一种生产气体燃料的新型方法，其中将低质量燃料如煤和作为阻燃废物收集的各种塑料和树脂（聚合物）分解成超临界水中的气体，从而有效利用所得气体 作为燃料。 也就是说，聚合物和芳族/缩合芳香烃在超临界水中以氧化钌（IV）为催化剂分解。 通过分解产生的气体组分作为气体燃料收集。

公开(公告)号：US07074548B2

公开(公告)日：2006-07-11

申请号：US10376253

申请日：2003-03-03

Applicant: Takeshi Kijima ,  Eiji Natori ,  Mitsuhiro Suzuki

Inventor： Takeshi Kijima ,  Eiji Natori ,  Mitsuhiro Suzuki

IPC: B05D3/00 ,  B05D3/06

CPC classification number: C23C18/1216 ,  B01J3/008 ,  B01J19/0013 ,  B01J19/123 ,  B01J19/125 ,  B01J19/1887 ,  B01J2219/00058 ,  B05D1/025 ,  B05D2401/90 ,  C23C18/12 ,  C23C18/1283 ,  C23C18/1287 ,  C23C18/14 ,  Y02P20/544

Abstract: A method of forming a thin-film including a capability to remove contaminants from the formed thin-film and/or a substrate on which the thin-film is formed using alcohol. The method includes allowing a substrate holder to support a substract. A first mixture is produced by mixing a condensation polymer containing an element of metal oxide compound and alcohol. Then second mixture is produced by mixing supercritical fluid or liquid carbon dioxide and the first mixture. A thin film is formed by applying the second mixture on a surface of the substrate. After forming the thin-film, the substrate is cleaned by applying alcohol to upper and lower surfaces, preferably the whole upper and lower surfaces, of the substract. The thin-film is crystallized by heating, and the crystallizing may include applying oxygen in a crystallizing chamber. Soft X-rays may be applied to the substrate, during the forming of the thin-film on the surface of the substrate.

Abstract translation: 一种形成薄膜的方法，该薄膜包括从形成的薄膜和/或使用酒精形成薄膜的基板去除污染物的能力。 该方法包括允许衬底保持器支撑减法。 通过混合含有金属氧化物和醇的元素的缩聚物来制备第一混合物。 然后通过混合超临界流体或液体二氧化碳和第一混合物产生第二混合物。 通过将第二混合物施加到基板的表面上来形成薄膜。 在形成薄膜之后，通过将酒精施加到底部的上表面和下表面，优选整个上表面和下表面来清洁基底。 薄膜通过加热结晶，结晶可以包括在结晶室中施加氧气。 在衬底表面形成薄膜期间，可以将软X射线施加到衬底上。

公开(公告)号：US20060115411A1

公开(公告)日：2006-06-01

申请号：US10519142

申请日：2003-06-25

Applicant: Henrik Jensen ,  Erik Sogaard

Inventor： Henrik Jensen ,  Erik Sogaard

IPC: C01G23/047

CPC classification number: B82Y30/00 ,  B01J3/008 ,  B01J2208/00061 ,  B01J2208/0007 ,  B01J2208/00548 ,  C01B13/32 ,  C01F7/36 ,  C01G1/02 ,  C01G23/053 ,  C01P2002/02 ,  C01P2002/04 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2002/78 ,  C01P2004/64 ,  C01P2006/12 ,  Y02P20/544 ,  Y10T428/2982

Abstract: The invention relates to a method of manufacturing a product having a sub-micron primary particle such as metal oxide, metal oxidhydroxide or metal hydroxide product, said method comprising the steps of: introducing a solid reactor filling material in a reactor, introducing a metal-containing precursor in said reactor, introducing a co-solvent into the said reactor, introducing a supercritical solvent in the said reactor. By these steps a contact between the metal-containing precursor and the co-solvent is established, thus resulting in the formation of said product in the proximity of the said solid reactor filling material. The present invention offers the astonishing possibility of producing anatase phase of TiO2 at temperatures as low as between 50° C. and 100° C. and at concurrent pressures of 100-200 bar. The invention also relates to a product such as anatase TiO2 produced by the method and also relates to an apparatus utilising the method.

Abstract translation: 本发明涉及一种制造具有亚微米一次粒子如金属氧化物，金属氧化物氢氧化物或金属氢氧化物产品的产品的方法，所述方法包括以下步骤：在反应器中引入固体反应器填充材料， 在所述反应器中含有前体，将共溶剂引入所述​​反应器中，在所述反应器中引入超临界溶剂。 通过这些步骤，建立含金属前体和共溶剂之间的接触，从而导致在所述固体反应器填充材料附近形成所述产物。 本发明提供了在低至50℃至100℃的温度和100-200巴的同时压力下产生TiO 2的锐钛矿相的令人惊奇的可能性。 本发明还涉及通过该方法制备的诸如锐钛矿TiO 2的产品，并且还涉及利用该方法的装置。

公开(公告)号：US20050179170A1

公开(公告)日：2005-08-18

申请号：US11085154

申请日：2005-03-22

Applicant: Kenneth Wynne ,  Younosuke Ohsaka ,  Suresh Shenoy ,  Sadashige Irie ,  Takako Ohsaka

Inventor： Kenneth Wynne ,  Younosuke Ohsaka ,  Suresh Shenoy ,  Sadashige Irie ,  Takako Ohsaka

IPC: B01J3/00 ,  C08F2/00 ,  C08J9/12 ,  C08K3/20 ,  H05B6/00

CPC classification number: C08J9/122 ,  B01J3/008 ,  C08J2201/032 ,  C08J2203/06 ,  C08J2203/08 ,  C08J2327/12 ,  C08K3/20 ,  Y02P20/544 ,  C08L27/12

Abstract: Fluoropolymer materials containing tetrafluoroethylene monomers, such as PTFE, are significantly swollen by supercritical carbon dioxide at high temperatures and pressures. The swollen fluoropolymer is processable by molding, extrusion, and other techniques. In addition, the fluoropolymer may be sintered at significantly lower temperatures compared to a nonswollen fluoropolymer material. The melting temperature of fluorinated polymers containing tetrafluoroethylene and triflouroethylene monomers which are swollen with supercritical carbon dioxide is significantly reduced, thereby permitting manufacturing operations such as extruding and molding to be performed at lower temperatures and with reduced risk of decomposition.

公开(公告)号：US20050154237A1

公开(公告)日：2005-07-14

申请号：US10510972

申请日：2003-04-09

Applicant: Koichi Nakahara ,  Kenzo Nagami ,  Okitsugu Kajimoto ,  Kazuya Kobiro

Inventor： Koichi Nakahara ,  Kenzo Nagami ,  Okitsugu Kajimoto ,  Kazuya Kobiro

IPC: B01J3/00 ,  C01B3/32 ,  C07C45/00 ,  C07C45/29

CPC classification number: B01J3/006 ,  B01J3/008 ,  C01B3/32 ,  C01B2203/0216 ,  C01B2203/0805 ,  C01B2203/1217 ,  C01B2203/1229 ,  C07C45/002 ,  Y02P20/544 ,  C07C49/786 ,  C07C49/403 ,  C07C49/08 ,  C07C47/06

Abstract: A process for producing a carbonyl compound involves allowing water to undergo phase transition to a supercritical or subcritical state in the presence of an alcohol compound so as to produce/generate water-derived hydrogen and at the same time convert the alcohol compound into a corresponding carbonyl compound. Specifically, the process is carried out by introducing the alcohol in a reaction tube along with water and heating and/or pressurizing the mixture of the alcohol and the water to bring the water into a subcritical or supercritical state. In this manner, water-derived hydrogen is produced and the alcohol is converted to a corresponding carbonyl compound. The process is preferably carried out in an oxygen-free environment.

Abstract translation: 制备羰基化合物的方法包括使水在醇化合物的存在下进行相转变为超临界或亚临界状态，以产生/产生水源氢，同时将醇化合物转化为相应的羰基 复合。 具体地，该方法通过将醇与水一起引入反应管中并加热和/或加压醇和水的混合物以使水进入亚临界或超临界状态来进行。 以这种方式，产生水衍生的氢，并将醇转化为相应的羰基化合物。 该方法优选在无氧环境中进行。

公开(公告)号：US20050152820A1

公开(公告)日：2005-07-14

申请号：US11010139

申请日：2004-12-10

Applicant: Mark D'Evelyn ,  Kristi Narang ,  Robert Giddings ,  Steven Tysoe ,  John Lucek ,  Suresh Vagarali ,  Robert Leonelli ,  Joel Dysart

Inventor： Mark D'Evelyn ,  Kristi Narang ,  Robert Giddings ,  Steven Tysoe ,  John Lucek ,  Suresh Vagarali ,  Robert Leonelli ,  Joel Dysart

IPC: A61K9/64 ,  B01D9/00 ,  B01J3/00 ,  B01J3/06 ,  B01J19/02 ,  B65D1/40 ,  B65D3/22 ,  B65D6/14 ,  C30B9/00 ,  C30B29/40

CPC classification number: B01J3/008 ,  B01J3/062 ,  B01J19/02 ,  B01J2203/0665 ,  B01J2219/00777 ,  B01J2219/0236 ,  B01J2219/024 ,  C30B7/10 ,  C30B9/00 ,  C30B29/40 ,  C30B29/406 ,  Y02P20/544 ,  Y10T117/10 ,  Y10T117/1004 ,  Y10T117/1024 ,  Y10T117/108 ,  Y10T117/1092

Abstract: A capsule for containing at least one reactant and a supercritical fluid in a substantially air-free environment under high pressure, high temperature processing conditions. The capsule includes a closed end, at least one wall adjoining the closed end and extending from the closed end; and a sealed end adjoining the at least one wall opposite the closed end. The at least one wall, closed end, and sealed end define a chamber therein for containing the reactant and a solvent that becomes a supercritical fluid at high temperatures and high pressures. The capsule is formed from a deformable material and is fluid impermeable and chemically inert with respect to the reactant and the supercritical fluid under processing conditions, which are generally above 5 kbar and 550° C. and, preferably, at pressures between 5 kbar and 80 kbar and temperatures between 550° C. and about 1500° C. The invention also includes methods of filling the capsule with the solvent and sealing the capsule, as well as an apparatus for sealing the capsule.

Abstract translation: 一种用于在高压，高温处理条件下在基本无空气环境中含有至少一种反应物和超临界流体的胶囊。 所述胶囊包括封闭端，邻近所述封闭端并从所述封闭端延伸的至少一个壁; 以及与所述封闭端相对的所述至少一个壁相邻的密封端。 至少一个壁，封闭端和密封端在其中限定一个室，用于容纳反应物和在高温和高压下成为超临界流体的溶剂。 胶囊由可变形材料形成，并且在加工条件下相对于反应物和超临界流体是流体不可渗透和化学惰性的，其通常高于5kbar和550℃，并且优选在5kbar和80kPa之间的压力 kbar和550℃至约1500℃之间的温度。本发明还包括用溶剂填充胶囊并密封胶囊的方法以及用于密封胶囊的装置。

公开(公告)号：US20050038289A1

公开(公告)日：2005-02-17

申请号：US10484457

申请日：2002-07-23

Applicant: Richard Gordon ,  Tessa Early ,  Andrew Holmes

Inventor： Richard Gordon ,  Tessa Early ,  Andrew Holmes

IPC: B01J3/00 ,  B01J23/44 ,  B01J31/04 ,  B01J31/06 ,  B01J31/16 ,  B01J31/18 ,  B01J31/24 ,  C07B37/04 ,  C07C1/32 ,  C07C41/30 ,  C07C51/09 ,  C07C67/343 ,  C07C205/06 ,  C07C205/56 ,  C07C51/10 ,  C07C51/14

CPC classification number: C07C41/30 ,  B01J3/008 ,  B01J23/44 ,  B01J31/06 ,  B01J31/1658 ,  B01J31/1805 ,  B01J31/2404 ,  B01J2219/00094 ,  B01J2231/4205 ,  B01J2231/4255 ,  B01J2231/4261 ,  B01J2231/4266 ,  B01J2531/824 ,  B01J2531/922 ,  C07B37/04 ,  C07B2200/11 ,  C07C1/321 ,  C07C51/09 ,  C07C67/343 ,  C07C201/12 ,  C07C2521/18 ,  C07C2523/44 ,  C07C15/00 ,  C07C59/84 ,  C07C63/331 ,  C07C57/44 ,  C07C69/732 ,  C07C69/65 ,  C07C69/734 ,  C07C69/738 ,  C07C69/618 ,  C07C205/06 ,  C07C205/56 ,  C07C43/205

Abstract: A palladium-catalysed carbon-carbon bond forming reaction in compressed carbon dioxide is provided wherein at least one of the reagents used in said reaction is bounded to a solid polymer support. In a second aspect, a palladium-catalysed carbon-carbon bond forming reaction in compressed carbon dioxide is provided wherein said reaction is performed in the presence of a tetra-alkylammonium acetate. In a third aspect, a palladium-catalysed carbon-carbon bond forming reaction in compressed carbon dioxide is provided wherein said palladium catalyst does not have any fluorinated phosphine ligands but does have at least one phosphine ligand that has at least one substituent that is selected from tert-alkyl groups, cycloalkyl groups and optionally substituted phenyl groups or 1′-diphenylphosphino-biphenyl. In a fourth aspect, there is provided a palladium-catalysed Suzuki or Heck reaction in compressed carbon dioxide wherein both of the substrates being combined in said reactions are boronic acids.

Abstract translation: 提供了在压缩二氧化碳中形成钯催化的碳 - 碳键反应，其中所述反应中使用的至少一种试剂与固体聚合物载体结合。 在第二方面，提供了在压缩二氧化碳中形成钯催化的碳 - 碳键反应，其中所述反应在四烷基乙酸铵存在下进行。 在第三方面，提供了在压缩二氧化碳中形成钯催化的碳 - 碳键反应，其中所述钯催化剂不具有任何氟化膦配体，但是具有至少一个具有至少一个选自以下的取代基的膦配体： 叔烷基，环烷基和任选取代的苯基或1'-二苯基膦基 - 联苯。 在第四方面，提供了在压缩二氧化碳中的钯催化的Suzuki或Heck反应，其中在所述反应中组合的两种底物都是硼酸。